Article(id=1322943598827799409, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942545734546372, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200763, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1602259200000, receivedDateStr=2020-10-10, revisedDate=1603382400000, revisedDateStr=2020-10-23, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343933063, onlineDateStr=2026-10-30, pubDate=1618848000000, pubDateStr=2021-04-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343933063, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343933063, creator=13701087609, updateTime=1793343933063, updator=13701087609, issue=Issue{id=1322942545734546372, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='4', pageStart='605', pageEnd='806', issueExtLink='null', onlineDate='null', pubDate='1618848000000', pubDateStr='2021-04-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343681986, creator='13701087609', updateTime=1793345524324, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322950273110508350, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942545734546372, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322950273110508351, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942545734546372, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=799, endPage=806, ext={EN=ArticleExt(id=1322943600018981746, articleId=1322943598827799409, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Self-propagating High-temperature Synthesis of TiC-SiC Coated Graphite Flakes and Its Effect on Properties of Al2O3-C Refractories, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

TiC/SiC coated natural flake graphite was used as a new carbon source of low carbon Al2O3-C refractories which was prepared by self-propagating high-temperature synthesis (SHS) using Ti, Si and GF as raw materials. The phase composition of the products was characterized by X-ray diffraction and the microstructure as well as the element distribution were studied via a scanning electron microscopy coupled with an energy dispersive spectroscopy. The effects of the amount of graphite on the reaction were studied. The results show that the maximum amount of GF added is 38.6% (mass fraction) under a self-sustained combustion wave, and a continuous, complete TiC-SiC coating layer with a uniform thickness (about 360 nm) is synthesized on the GF surface. The effects of the amount of the coated graphite on the properties of low carbon Al2O3-C refractories were invetigated. The results revel that the Al2O3-C refractory shows the optimal properties when 3% (mass fraction) coated graphite is used: the lowest apparent porosity (12.9%), the highest cold modulus of rupture (20.7 MPa), and the thickness of oxide decarburization layer and the erosion depth of slag are reduced by 41.8% and 57.1%, respectively.

, authors=Xing CHEN, Yun REN, Jiyuan LUO, Xiaochuan CHONG, Donghai DING, Guoqing XIAO, authorsList=Xing CHEN, Yun REN, Jiyuan LUO, Xiaochuan CHONG, Donghai DING, Guoqing XIAO, authorCompany=null, correspAuthors=Yun REN, authorNote=

CHEN Xing (1995-), male, Master candidate. E-mail:

, correspAuthorsNote=
REN Yun (1967-), female, Associate Professor. E-mail:
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以Ti、Si和天然鳞片石墨(GF)为原料,通过自蔓延高温合成法(SHS)在GF表面制备TiC/SiC复合包覆层并用作低碳Al2O3-C耐火材料的新型碳源;利用X射线衍射、扫描电子显微镜和能谱仪对产物物相组成和显微结构进行表征。结果表明:在燃烧波自维持下,GF的最大添加量为38.6%(质量分数),GF表面形成了连续、完整且厚度均匀(约为360 nm)的TiC-SiC包覆层。当用3%(质量分数)的包覆石墨代替GF时,Al2O3-C耐火材料显气孔率最低(12.9%),抗折强度最高(20.7 MPa),氧化脱碳层厚度和熔渣侵蚀深度分别降低41.8%和57.1%,综合性能最佳。

, authors=陈兴, 任耘, 骆吉源, 种小川, 丁冬海, 肖国庆, authorsList=陈兴, 任耘, 骆吉源, 种小川, 丁冬海, 肖国庆, authorCompany=null, correspAuthors=任耘, authorNote=

陈兴(1995—),男,硕士研究生。

, correspAuthorsNote=
任耘(1967—),女,副教授。
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陈兴(1995—),男,硕士研究生。

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陈兴(1995—),男,硕士研究生。

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自蔓延高温合成TiC-SiC包覆鳞片石墨及其对Al2O3-C耐火材料性能的影响
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陈兴 , 任耘 , 骆吉源 , 种小川 , 丁冬海 , 肖国庆
硅酸盐学报 | 2021,49(4): 799-806
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硅酸盐学报 | 2021 , 49 (4) : 799 -806
自蔓延高温合成TiC-SiC包覆鳞片石墨及其对Al2O3-C耐火材料性能的影响
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陈兴 , 任耘 , 骆吉源, 种小川, 丁冬海, 肖国庆
作者信息
  • 西安建筑科技大学材料科学与工程学院,西安 710055
通讯作者:
任耘(1967—),女,副教授。
作者简介:

陈兴(1995—),男,硕士研究生。

Self-propagating High-temperature Synthesis of TiC-SiC Coated Graphite Flakes and Its Effect on Properties of Al2O3-C Refractories
Xing CHEN , Yun REN , Jiyuan LUO, Xiaochuan CHONG, Donghai DING, Guoqing XIAO
Affiliations
  • College of Materials Science and Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China
  • Corresponding Author:
    REN Yun (1967-), female, Associate Professor. E-mail:

    CHEN Xing (1995-), male, Master candidate. E-mail:

出版时间: 2021-04-20 doi: 10.14062/j.issn.0454-5648.20200763
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以Ti、Si和天然鳞片石墨(GF)为原料,通过自蔓延高温合成法(SHS)在GF表面制备TiC/SiC复合包覆层并用作低碳Al2O3-C耐火材料的新型碳源;利用X射线衍射、扫描电子显微镜和能谱仪对产物物相组成和显微结构进行表征。结果表明:在燃烧波自维持下,GF的最大添加量为38.6%(质量分数),GF表面形成了连续、完整且厚度均匀(约为360 nm)的TiC-SiC包覆层。当用3%(质量分数)的包覆石墨代替GF时,Al2O3-C耐火材料显气孔率最低(12.9%),抗折强度最高(20.7 MPa),氧化脱碳层厚度和熔渣侵蚀深度分别降低41.8%和57.1%,综合性能最佳。

自蔓延高温合成  /  碳化钛碳化硅包覆层  /  低碳铝碳耐火材料  /  鳞片石墨  /  显气孔率

TiC/SiC coated natural flake graphite was used as a new carbon source of low carbon Al2O3-C refractories which was prepared by self-propagating high-temperature synthesis (SHS) using Ti, Si and GF as raw materials. The phase composition of the products was characterized by X-ray diffraction and the microstructure as well as the element distribution were studied via a scanning electron microscopy coupled with an energy dispersive spectroscopy. The effects of the amount of graphite on the reaction were studied. The results show that the maximum amount of GF added is 38.6% (mass fraction) under a self-sustained combustion wave, and a continuous, complete TiC-SiC coating layer with a uniform thickness (about 360 nm) is synthesized on the GF surface. The effects of the amount of the coated graphite on the properties of low carbon Al2O3-C refractories were invetigated. The results revel that the Al2O3-C refractory shows the optimal properties when 3% (mass fraction) coated graphite is used: the lowest apparent porosity (12.9%), the highest cold modulus of rupture (20.7 MPa), and the thickness of oxide decarburization layer and the erosion depth of slag are reduced by 41.8% and 57.1%, respectively.

self-propagating high-temperature synthesis  /  titanium carbide silicon carbide coating  /  low carbon aluminum carbon refractories  /  graphite flakes  /  apparent porosity
陈兴, 任耘, 骆吉源, 种小川, 丁冬海, 肖国庆. 自蔓延高温合成TiC-SiC包覆鳞片石墨及其对Al2O3-C耐火材料性能的影响. 硅酸盐学报, 2021 , 49 (4) : 799 -806 . DOI: 10.14062/j.issn.0454-5648.20200763
Xing CHEN, Yun REN, Jiyuan LUO, Xiaochuan CHONG, Donghai DING, Guoqing XIAO. Self-propagating High-temperature Synthesis of TiC-SiC Coated Graphite Flakes and Its Effect on Properties of Al2O3-C Refractories[J]. Journal of the Chinese Ceramic Society, 2021 , 49 (4) : 799 -806 . DOI: 10.14062/j.issn.0454-5648.20200763
  • 国家自然科学基金(51572212; 51772236)
  • 陕西省重点研发项目(2018ZDXM-GY-128)
  • 陕西省教育厅协同创新项目(Z20200170)
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2021年第49卷第4期
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doi: 10.14062/j.issn.0454-5648.20200763
  • 接收时间:2020-10-10
  • 首发时间:2026-10-30
  • 出版时间:2021-04-20
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  • 收稿日期:2020-10-10
  • 修回日期:2020-10-23
基金
国家自然科学基金(51572212; 51772236)
陕西省重点研发项目(2018ZDXM-GY-128)
陕西省教育厅协同创新项目(Z20200170)
作者信息
    西安建筑科技大学材料科学与工程学院,西安 710055

通讯作者:

任耘(1967—),女,副教授。
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2种不同金属材料的力学参数
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属
Genus
种数
Number of
species
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Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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