Article(id=1322943574496641849, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942545734546372, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200506, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1594137600000, receivedDateStr=2020-07-08, revisedDate=1596211200000, revisedDateStr=2020-08-01, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343927262, onlineDateStr=2026-10-30, pubDate=1618848000000, pubDateStr=2021-04-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343927262, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343927262, creator=13701087609, updateTime=1793343927262, updator=13701087609, issue=Issue{id=1322942545734546372, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='4', pageStart='605', pageEnd='806', issueExtLink='null', onlineDate='null', pubDate='1618848000000', pubDateStr='2021-04-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343681986, creator='13701087609', updateTime=1793345524324, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322950273110508350, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942545734546372, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322950273110508351, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942545734546372, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=639, endPage=647, ext={EN=ArticleExt(id=1322943575310336826, articleId=1322943574496641849, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Effect of K/Ce Ions Co-doping on Structure and Electrical Properties of Na0.5Bi2.5Ta2O9 Ceramics, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

A lead-free piezoelectric ceramic (NaBi)0.5-x(KCe)xBi2Ta2O9(NBTO-x, 0≤x≤0.15) was prepared by a solid-state reaction method. The influence of K/Ce ions co-doping content on the structure and electrical properties of NBTO ceramic was investigated. Based on the results by X-ray diffraction, a bismuth layered structure compound with m=2 is formed in all the ceramic samples. The Curie temperature TC of the samples decreases gradually with the increase of K/Ce ions co-doping content. The piezoelectric properties of the samples are improved due to K/Ce ions co-doping, The piezoelectric constant d33 initially increases and then decreases with the increase of K/Ce ions co-doping content. The ceramic with x of 0.075 exhibits the optimal properties, i.e., d33 of 19.0 pC/N, the Curie temperature TC of 735℃, dielectric loss tanδ of 0.137%, and volume density ρ of 9.113 g·cm-3. The piezoelectric constant d33 of NBTO (x of 0.075) ceramic has a good temperature stability, and the d33 of NBTO ceramic annealed at 600℃ for 2 h is still as high as 17.8 pC/N, which is 93.7% of the original value (i.e., d33=19.0 pC/N).

, authors=Jingdong XU, Xiangping JIANG, Chao CHEN, Xiaokun HUANG, Xin NIE, Liwei HUANG, authorsList=Jingdong XU, Xiangping JIANG, Chao CHEN, Xiaokun HUANG, Xin NIE, Liwei HUANG, authorCompany=null, correspAuthors=Xiangping JIANG, authorNote=

XU Jingdong (1994-), male, Master candidate. E-mail:

, correspAuthorsNote=
JIANG Xiangping (1964-), male, Ph.D., Professor. E-mail:
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采用传统固相法制备(NaBi)0.5-x(KCe)xBi2Ta2O9(NBTO-x,0≤x≤0.15)无铅压电陶瓷,研究K/Ce离子含量对NBTO陶瓷结构和电学性能的影响。结果表明:所有陶瓷样品均生成了m=2的铋层状结构化合物,且未发现其他明显杂峰;随着K/Ce离子含量的增加,样品的Curie温度TC逐渐降低;K/Ce离子掺杂提高了样品的压电性能,压电常数d33随掺杂量提高呈现出先升高后降低趋势,当x=0.075时,样品的综合性能达到最佳:d33=19.0 pC/N,Curie温度TC=735℃,介电损耗tanδ=0.137%,体积密度ρ=9.113 g·cm-3;NBTO(x=0.075)陶瓷在600℃退火2 h,其d33仍高达17.8 pC/N,约为初始值(d33=19.0 pC/N)的93.7%,表现出良好的温度稳定性。

, authors=许经东, 江向平, 陈超, 黄枭坤, 聂鑫, 黄立伟, authorsList=许经东, 江向平, 陈超, 黄枭坤, 聂鑫, 黄立伟, authorCompany=null, correspAuthors=江向平, authorNote=

许经东(1994—),男,硕士研究生。

, correspAuthorsNote=
江向平(1964—),博士,教授。
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K/Ce离子共掺对Na0.5Bi2.5Ta2O9陶瓷的结构与电学性能影响
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许经东 , 江向平 , 陈超 , 黄枭坤 , 聂鑫 , 黄立伟
硅酸盐学报 | 2021,49(4): 639-647
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硅酸盐学报 | 2021 , 49 (4) : 639 -647
K/Ce离子共掺对Na0.5Bi2.5Ta2O9陶瓷的结构与电学性能影响
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许经东 , 江向平 , 陈超, 黄枭坤, 聂鑫, 黄立伟
作者信息
  • 景德镇陶瓷大学材料科学与工程学院,江西省先进陶瓷材料重点实验室,江西 景德镇 333403
通讯作者:
江向平(1964—),博士,教授。
作者简介:

许经东(1994—),男,硕士研究生。

Effect of K/Ce Ions Co-doping on Structure and Electrical Properties of Na0.5Bi2.5Ta2O9 Ceramics
Jingdong XU , Xiangping JIANG , Chao CHEN, Xiaokun HUANG, Xin NIE, Liwei HUANG
Affiliations
  • Jiangxi Key Laboratory of Advanced Ceramic Materials, School of Material Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen 333403, Jiangxi, China
  • Corresponding Author:
    JIANG Xiangping (1964-), male, Ph.D., Professor. E-mail:

    XU Jingdong (1994-), male, Master candidate. E-mail:

出版时间: 2021-04-20 doi: 10.14062/j.issn.0454-5648.20200506
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采用传统固相法制备(NaBi)0.5-x(KCe)xBi2Ta2O9(NBTO-x,0≤x≤0.15)无铅压电陶瓷,研究K/Ce离子含量对NBTO陶瓷结构和电学性能的影响。结果表明:所有陶瓷样品均生成了m=2的铋层状结构化合物,且未发现其他明显杂峰;随着K/Ce离子含量的增加,样品的Curie温度TC逐渐降低;K/Ce离子掺杂提高了样品的压电性能,压电常数d33随掺杂量提高呈现出先升高后降低趋势,当x=0.075时,样品的综合性能达到最佳:d33=19.0 pC/N,Curie温度TC=735℃,介电损耗tanδ=0.137%,体积密度ρ=9.113 g·cm-3;NBTO(x=0.075)陶瓷在600℃退火2 h,其d33仍高达17.8 pC/N,约为初始值(d33=19.0 pC/N)的93.7%,表现出良好的温度稳定性。

铋层状  /  高温压电陶瓷  /  电学性能

A lead-free piezoelectric ceramic (NaBi)0.5-x(KCe)xBi2Ta2O9(NBTO-x, 0≤x≤0.15) was prepared by a solid-state reaction method. The influence of K/Ce ions co-doping content on the structure and electrical properties of NBTO ceramic was investigated. Based on the results by X-ray diffraction, a bismuth layered structure compound with m=2 is formed in all the ceramic samples. The Curie temperature TC of the samples decreases gradually with the increase of K/Ce ions co-doping content. The piezoelectric properties of the samples are improved due to K/Ce ions co-doping, The piezoelectric constant d33 initially increases and then decreases with the increase of K/Ce ions co-doping content. The ceramic with x of 0.075 exhibits the optimal properties, i.e., d33 of 19.0 pC/N, the Curie temperature TC of 735℃, dielectric loss tanδ of 0.137%, and volume density ρ of 9.113 g·cm-3. The piezoelectric constant d33 of NBTO (x of 0.075) ceramic has a good temperature stability, and the d33 of NBTO ceramic annealed at 600℃ for 2 h is still as high as 17.8 pC/N, which is 93.7% of the original value (i.e., d33=19.0 pC/N).

bismuth layer-structured  /  high temperature piezoelectric ceramics  /  electrical property
许经东, 江向平, 陈超, 黄枭坤, 聂鑫, 黄立伟. K/Ce离子共掺对Na0.5Bi2.5Ta2O9陶瓷的结构与电学性能影响. 硅酸盐学报, 2021 , 49 (4) : 639 -647 . DOI: 10.14062/j.issn.0454-5648.20200506
Jingdong XU, Xiangping JIANG, Chao CHEN, Xiaokun HUANG, Xin NIE, Liwei HUANG. Effect of K/Ce Ions Co-doping on Structure and Electrical Properties of Na0.5Bi2.5Ta2O9 Ceramics[J]. Journal of the Chinese Ceramic Society, 2021 , 49 (4) : 639 -647 . DOI: 10.14062/j.issn.0454-5648.20200506
  • 国家自然科学基金(51762024; 51862016)
  • 江西省自然科学基金(20192BAB206008; 20192BAB212002)
  • 江西省教育厅科技项目(GJJ190712; GJJ180718; GJJ180739)
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2021年第49卷第4期
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doi: 10.14062/j.issn.0454-5648.20200506
  • 接收时间:2020-07-08
  • 首发时间:2026-10-30
  • 出版时间:2021-04-20
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  • 收稿日期:2020-07-08
  • 修回日期:2020-08-01
基金
国家自然科学基金(51762024; 51862016)
江西省自然科学基金(20192BAB206008; 20192BAB212002)
江西省教育厅科技项目(GJJ190712; GJJ180718; GJJ180739)
作者信息
    景德镇陶瓷大学材料科学与工程学院,江西省先进陶瓷材料重点实验室,江西 景德镇 333403

通讯作者:

江向平(1964—),博士,教授。
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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