Article(id=1322943454799601946, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942780003201932, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20210181, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1615737600000, receivedDateStr=2021-03-15, revisedDate=1618070400000, revisedDateStr=2021-04-11, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343898725, onlineDateStr=2026-10-30, pubDate=1632067200000, pubDateStr=2021-09-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343898725, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343898725, creator=13701087609, updateTime=1793343898725, updator=13701087609, issue=Issue{id=1322942780003201932, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='9', pageStart='1785', pageEnd='2044', issueExtLink='null', onlineDate='null', pubDate='1632067200000', pubDateStr='2021-09-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343737841, creator='13701087609', updateTime=1793345873558, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322951737916665918, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942780003201932, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322951737916665919, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942780003201932, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1846, endPage=1852, ext={EN=ArticleExt(id=1322943456343105820, articleId=1322943454799601946, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Control Mechanism and Effect of Oxygen-inhibition Layer of Ceramic Stereolithography on Orming Precision, columnId=1322942810562900072, journalTitle=Journal of the Chinese Ceramic Society, columnName=Additive Manufacturing of Ceramics—Research Article, runingTitle=null, highlight=null, articleAbstract=

There is an "oxygen inhibition layer" forming when light-curing 3D printing with radicals resin material, leading to continuous printing and surface quality improvement. Since the mechanism of controlling the structural precision of printing parts is unclear, it is thus difficult to control the precision of printing porous parts with complex shape. This paper used a self-made free radical bioceramic slurry to produce porous bioceramic scaffolds through stereolithography, investigated the three-stage curing interval in the lithography process and the principle of controlling the molding accuracy of the oxygen barrier layer. and proposed a reasonable control oxygen-inhibition layer method for adjusting the printing process parameters. It is indicated that the oxygen-inhibition layer can improve the molding accuracy of ceramic parts, and affect its mechanical properties. According to the established mechanism of the thickness of the oxygen-inhibition layer on the forming accuracy and mechanical properties of the porous structure of the bio-bone ceramic scaffold, the high-precision manufacturing basic theory and method for the multifunctional ceramic printing technique and the application of ceramic base bone substitutes were proposed.

, authors=Qin LIAN1, 2, Yonghui WANG1, 2, Dichen LI1, 2, Xiaoning HE3, authorsList=Qin LIAN, Yonghui WANG, Dichen LI, Xiaoning HE, authorCompany=null, correspAuthors=null, authorNote=

LIAN Qin(1971-), female, Professor. E-mail:

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利用自由基树脂材料进行光固化3D打印时出现的“氧阻聚层”,为其连续制造和表面质量的提升提供了可能,但因对打印件的结构精度的调控机理不清,打印具有复杂外形的多孔结构件难以控制其成型精度。利用自制自由基生物陶瓷浆料经光固化3D打印制造多孔生物骨陶瓷支架,研究并提出了光固化过程中的3阶段的固化区间和氧阻聚层调控成型精度原理;建立了寻找合理的氧阻聚调控打印工艺参数的方法;发现了氧阻聚层不仅能够提升陶瓷制件的成型精度,也会影响其力学性能。由此建立起的氧阻聚层厚度对生物骨陶瓷支架的多孔结构成型精度和力学性能的作用机制,为多功能陶瓷打印技术及其陶瓷基骨替代物应用提供了高精度制造基础理论与方法。

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连芩(1971—),女,教授。

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氧阻聚层调控原理及其对陶瓷光固化成型精度的影响
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连芩 1, 2 , 王永辉 1, 2 , 李涤尘 1, 2 , 何晓宁 3
硅酸盐学报 | 陶瓷增材制造专题-研究论文 2021,49(9): 1846-1852
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硅酸盐学报 |陶瓷增材制造专题-研究论文 2021 , 49 (9) : 1846 -1852
氧阻聚层调控原理及其对陶瓷光固化成型精度的影响
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连芩1, 2 , 王永辉1, 2, 李涤尘1, 2, 何晓宁3
作者信息
  • 1.西安交通大学,机械制造系统工程国家重点实验室,西安 710054
  • 2.国家药品监督管理局医用增材制造器械研究与评价重点实验室,西安 710054
  • 3.西安电子科技大学,宽带隙半导体技术国家重点学科实验室,西安 710071
作者简介:

连芩(1971—),女,教授。

Control Mechanism and Effect of Oxygen-inhibition Layer of Ceramic Stereolithography on Orming Precision
Qin LIAN1, 2 , Yonghui WANG1, 2, Dichen LI1, 2, Xiaoning HE3
Affiliations
  • 1.State Key Laboratory of Mechanical Manufacturing Systems Engineering, Xi'an Jiaotong University, Xi'an 710054, China
  • 2.Key Laboratory of Research and Evaluation of Medical Additive Manufacturing Devices, National Medical Products Administration, Xi'an 710054, China
  • 3.State Key Laboratory of Broadband Gap Semiconductor Technology, Xidian University, Xi'an 710071, China
  • LIAN Qin(1971-), female, Professor. E-mail:

出版时间: 2021-09-20 doi: 10.14062/j.issn.0454-5648.20210181
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利用自由基树脂材料进行光固化3D打印时出现的“氧阻聚层”,为其连续制造和表面质量的提升提供了可能,但因对打印件的结构精度的调控机理不清,打印具有复杂外形的多孔结构件难以控制其成型精度。利用自制自由基生物陶瓷浆料经光固化3D打印制造多孔生物骨陶瓷支架,研究并提出了光固化过程中的3阶段的固化区间和氧阻聚层调控成型精度原理;建立了寻找合理的氧阻聚调控打印工艺参数的方法;发现了氧阻聚层不仅能够提升陶瓷制件的成型精度,也会影响其力学性能。由此建立起的氧阻聚层厚度对生物骨陶瓷支架的多孔结构成型精度和力学性能的作用机制,为多功能陶瓷打印技术及其陶瓷基骨替代物应用提供了高精度制造基础理论与方法。

氧阻聚  /  光固化3D打印  /  多功能陶瓷  /  骨支架  /  成型精度

There is an "oxygen inhibition layer" forming when light-curing 3D printing with radicals resin material, leading to continuous printing and surface quality improvement. Since the mechanism of controlling the structural precision of printing parts is unclear, it is thus difficult to control the precision of printing porous parts with complex shape. This paper used a self-made free radical bioceramic slurry to produce porous bioceramic scaffolds through stereolithography, investigated the three-stage curing interval in the lithography process and the principle of controlling the molding accuracy of the oxygen barrier layer. and proposed a reasonable control oxygen-inhibition layer method for adjusting the printing process parameters. It is indicated that the oxygen-inhibition layer can improve the molding accuracy of ceramic parts, and affect its mechanical properties. According to the established mechanism of the thickness of the oxygen-inhibition layer on the forming accuracy and mechanical properties of the porous structure of the bio-bone ceramic scaffold, the high-precision manufacturing basic theory and method for the multifunctional ceramic printing technique and the application of ceramic base bone substitutes were proposed.

oxygen-inhibition  /  stereolithography  /  multifunctional ceramic  /  bone scaffold  /  structural precision
连芩, 王永辉, 李涤尘, 何晓宁. 氧阻聚层调控原理及其对陶瓷光固化成型精度的影响. 硅酸盐学报, 2021 , 49 (9) : 1846 -1852 . DOI: 10.14062/j.issn.0454-5648.20210181
Qin LIAN, Yonghui WANG, Dichen LI, Xiaoning HE. Control Mechanism and Effect of Oxygen-inhibition Layer of Ceramic Stereolithography on Orming Precision[J]. Journal of the Chinese Ceramic Society, 2021 , 49 (9) : 1846 -1852 . DOI: 10.14062/j.issn.0454-5648.20210181
  • 国家重点研发计划(2018YFE0207900)
  • 陕西省重点研发计划(2019ZDLGY04-03)
  • 国家自然科学基金重点项目(51835010)
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2021年第49卷第9期
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doi: 10.14062/j.issn.0454-5648.20210181
  • 接收时间:2021-03-15
  • 首发时间:2026-10-30
  • 出版时间:2021-09-20
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  • 收稿日期:2021-03-15
  • 修回日期:2021-04-11
基金
国家重点研发计划(2018YFE0207900)
陕西省重点研发计划(2019ZDLGY04-03)
国家自然科学基金重点项目(51835010)
作者信息
    1.西安交通大学,机械制造系统工程国家重点实验室,西安 710054
    2.国家药品监督管理局医用增材制造器械研究与评价重点实验室,西安 710054
    3.西安电子科技大学,宽带隙半导体技术国家重点学科实验室,西安 710071
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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