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¹H low-field nuclear magnetic resonance instrument was used to continuously monitor the changes in the transverse relaxation time of white cement with silica nanoparticles with different sizes (i.e., 15 nm, 50 nm and 100 nm) from adding water to hydration for 72 h. The effect of silica nanoparticles with different sizes on the hydration process of cement was investigated. The setting time of cement paste was measured using the Vicat apparatus. The results show that the crystal nucleation of silica nanoparticles can affect the early hydration process of cement, thus breaking the flocculation structure of cement paste due to the physical adsorption and pozzolanic reaction, reducing the number of macropores, and improving the uniformity of cement paste. In addition, the smaller the silica nano particles is, the less the free water content in hydration process and the shorter the setting time will be.

, authors=Ai ZHANG, Yong GE, authorsList=Ai ZHANG, Yong GE, authorCompany=null, correspAuthors=Yong GE, authorNote=, correspAuthorsNote=, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322943403373241277, articleId=1322943402987365307, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=不同粒径纳米氧化硅改性白水泥水化过程的¹H低场核磁弛豫特征, columnId=1263922770220560512, journalTitle=硅酸盐学报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=

采用¹H低场核磁共振仪连续监测不同粒径（15，50 nm和100 nm）纳米氧化硅对白水泥从加水到水化72 h横向弛豫时间的变化，研究不同粒径氧化硅对水泥水化过程的影响程度，最后结合维卡仪测定水泥浆的凝结时间。结果表明：纳米氧化硅的晶核作用会影响水泥的早期水化过程，还可以通过物理吸附和火山灰反应打破早期水泥浆体的絮凝结构，减少大孔隙的数量，提高水泥浆体的均质性。此外，纳米氧化硅粒径越小，水化过程中自由水含量消耗越快，表现出的凝结时间越短。

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ZHANG Ai (1992-), female, Doctoral candidate. E-mail: zgaino1@163.com

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ZHANG Ai (1992-), female, Doctoral candidate. E-mail: zgaino1@163.com

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张爱（1992—），女，博士研究生。

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张爱（1992—），女，博士研究生。

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