Article(id=1322943336058855905, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942634976752425, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200984, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1609257600000, receivedDateStr=2020-12-30, revisedDate=1610899200000, revisedDateStr=2021-01-18, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343870414, onlineDateStr=2026-10-30, pubDate=1626710400000, pubDateStr=2021-07-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343870414, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343870414, creator=13701087609, updateTime=1793343870414, updator=13701087609, issue=Issue{id=1322942634976752425, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='7', pageStart='1249', pageEnd='1518', issueExtLink='null', onlineDate='null', pubDate='1626710400000', pubDateStr='2021-07-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343703264, creator='13701087609', updateTime=1793345819416, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322951510828659213, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942634976752425, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322951510828659214, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942634976752425, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1359, endPage=1366, ext={EN=ArticleExt(id=1322943336297931234, articleId=1322943336058855905, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Synergistic Flame Retardant Mechanism of Tripolyphosphate Intercalation Modified LDH Combination with Decabromodiphenyl Ethane, columnId=1322942641213682516, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Issue on Mineral Material, runingTitle=null, highlight=null, articleAbstract=

A tripolyphosphate-intercalated layered double hydroxide compound (LDH-P) was prepared by using exchange method, with flame retardant and structural characteristics. Then, sodium oleate was used to modify the hydroxide, thus forming LDH-P composite (LDH-P-S), by using a water bath method. The synergistic flame retardant behavior of the LDH-P-S with the combination of decabromodiphenyl ethane (DBDPE) on polypropylene (PP) was evaluated. When the content of LDH-P-S was 25% and the total loading of the flame regardant component was 30% in the system, the oxygen index of PP was increased from 24.2% to 24.9%, the total amount of smoke released was decreased by 10.3%, the peak heat release was decreased by 38%, and the vertical combustion performance reached V-0 level. Owing to the synergistic flame retardant effect of LDH-P-S and DBDPE, the amount of DBDPE could be reduced, while the comprehensive flame retardant performance could be effectively improved.

, authors=Di WU1, Xiangli XIE2, Yuan LEI3, Xin DAI3, Cunjun LI1, 4, Wenfeng ZHU1, Yanqi XU1, 4, Linjiang WANG1, 4, authorsList=Di WU, Xiangli XIE, Yuan LEI, Xin DAI, Cunjun LI, Wenfeng ZHU, Yanqi XU, Linjiang WANG, authorCompany=null, correspAuthors=Yanqi XU, Linjiang WANG, authorNote=

WU Di(1995-), male, Master candidate. E-mail:

, correspAuthorsNote=
WANG Linjiang(1962-), male, Ph.D., Professor. E-mail:
XU Yanqi(1991-), female, Ph.D., Lecturer.
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322943336570560995, articleId=1322943336058855905, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=三聚磷酸盐插层改性LDH复配十溴二苯乙烷的协效阻燃机制, columnId=1322942641389843286, journalTitle=硅酸盐学报, columnName=矿物材料专题, runingTitle=null, highlight=null, articleAbstract=

基于磷酸盐和层状双氢氧化物的阻燃性和结构特征,用离子交换法制备了三聚磷酸盐/层状双氢氧化物插层复合物(LDH-P),以油酸钠为表面改性剂,采用水浴法包覆LDH-P获得了油酸钠包覆型复合物(LDH-P-S)。研究了LDH-P-S、十溴二苯乙烷(DBDPE)复配阻燃剂对聚丙烯(PP)的协效阻燃行为。结果表明:当LDH-P-S用量占阻燃剂总量的25%时(阻燃剂总量占PP质量的30%),与单一DBDPE阻燃PP体系相比,聚丙烯的氧指数由24.2%提升至24.9%,烟雾释放总量下降10.3%,热释放峰值下降38%,垂直燃烧性能达到V-0级。LDH-P-S与DBDPE的协效阻燃作用不仅能减少DBDPE的用量,同时能有效改善综合阻燃性能。

, authors=吴迪1, 谢襄漓2, 雷圆3, 戴新3, 李存军1, 4, 朱文凤1, 许艳旗1, 4, 王林江1, 4, authorsList=吴迪, 谢襄漓, 雷圆, 戴新, 李存军, 朱文凤, 许艳旗, 王林江, authorCompany=null, correspAuthors=许艳旗, 王林江, authorNote=

吴迪(1995—),男,硕士研究生。

, correspAuthorsNote=
王林江(1962—),男,博士,教授。
许艳旗(1991—),女,博士,讲师。
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三聚磷酸盐插层改性LDH复配十溴二苯乙烷的协效阻燃机制
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吴迪 1 , 谢襄漓 2 , 雷圆 3 , 戴新 3 , 李存军 1, 4 , 朱文凤 1 , 许艳旗 1, 4 , 王林江 1, 4
硅酸盐学报 | 矿物材料专题 2021,49(7): 1359-1366
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硅酸盐学报 |矿物材料专题 2021 , 49 (7) : 1359 -1366
三聚磷酸盐插层改性LDH复配十溴二苯乙烷的协效阻燃机制
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吴迪1 , 谢襄漓2, 雷圆3, 戴新3, 李存军1, 4, 朱文凤1, 许艳旗1, 4 , 王林江1, 4
作者信息
  • 1.桂林理工大学材料科学与工程学院,广西 桂林 541004
  • 2.桂林理工大学化学与生物工程学院,广西 桂林 541004
  • 3.广西华锑科技有限公司,南宁 530004
  • 4.广西壮族自治区北部湾绿色海工材料工程研究中心,广西 桂林 541004
通讯作者:
王林江(1962—),男,博士,教授。
许艳旗(1991—),女,博士,讲师。
作者简介:

吴迪(1995—),男,硕士研究生。

Synergistic Flame Retardant Mechanism of Tripolyphosphate Intercalation Modified LDH Combination with Decabromodiphenyl Ethane
Di WU1 , Xiangli XIE2, Yuan LEI3, Xin DAI3, Cunjun LI1, 4, Wenfeng ZHU1, Yanqi XU1, 4 , Linjiang WANG1, 4
Affiliations
  • 1.College of Materials Science and Engineering, Guilin University of Technology, Guilin 541004, Guangxi, China
  • 2.College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004, Guangxi, China
  • 3.Guangxi Huati Technology Co. LTD, Nanning, 530004, China
  • 4.Beibu Gulf Engineering Research Center for Green Marine Materials, Guilin 541004, Guangxi, China
  • Corresponding Author:
    WANG Linjiang(1962-), male, Ph.D., Professor. E-mail:
    XU Yanqi(1991-), female, Ph.D., Lecturer.

    WU Di(1995-), male, Master candidate. E-mail:

出版时间: 2021-07-20 doi: 10.14062/j.issn.0454-5648.20200984
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基于磷酸盐和层状双氢氧化物的阻燃性和结构特征,用离子交换法制备了三聚磷酸盐/层状双氢氧化物插层复合物(LDH-P),以油酸钠为表面改性剂,采用水浴法包覆LDH-P获得了油酸钠包覆型复合物(LDH-P-S)。研究了LDH-P-S、十溴二苯乙烷(DBDPE)复配阻燃剂对聚丙烯(PP)的协效阻燃行为。结果表明:当LDH-P-S用量占阻燃剂总量的25%时(阻燃剂总量占PP质量的30%),与单一DBDPE阻燃PP体系相比,聚丙烯的氧指数由24.2%提升至24.9%,烟雾释放总量下降10.3%,热释放峰值下降38%,垂直燃烧性能达到V-0级。LDH-P-S与DBDPE的协效阻燃作用不仅能减少DBDPE的用量,同时能有效改善综合阻燃性能。

复配阻燃剂  /  十溴二苯乙烷  /  层状双氢氧化物  /  三聚磷酸钠

A tripolyphosphate-intercalated layered double hydroxide compound (LDH-P) was prepared by using exchange method, with flame retardant and structural characteristics. Then, sodium oleate was used to modify the hydroxide, thus forming LDH-P composite (LDH-P-S), by using a water bath method. The synergistic flame retardant behavior of the LDH-P-S with the combination of decabromodiphenyl ethane (DBDPE) on polypropylene (PP) was evaluated. When the content of LDH-P-S was 25% and the total loading of the flame regardant component was 30% in the system, the oxygen index of PP was increased from 24.2% to 24.9%, the total amount of smoke released was decreased by 10.3%, the peak heat release was decreased by 38%, and the vertical combustion performance reached V-0 level. Owing to the synergistic flame retardant effect of LDH-P-S and DBDPE, the amount of DBDPE could be reduced, while the comprehensive flame retardant performance could be effectively improved.

compound flame retardant  /  decabromodiphenyl ethane  /  layered double hydroxides  /  sodium tripolyphosophate
吴迪, 谢襄漓, 雷圆, 戴新, 李存军, 朱文凤, 许艳旗, 王林江. 三聚磷酸盐插层改性LDH复配十溴二苯乙烷的协效阻燃机制. 硅酸盐学报, 2021 , 49 (7) : 1359 -1366 . DOI: 10.14062/j.issn.0454-5648.20200984
Di WU, Xiangli XIE, Yuan LEI, Xin DAI, Cunjun LI, Wenfeng ZHU, Yanqi XU, Linjiang WANG. Synergistic Flame Retardant Mechanism of Tripolyphosphate Intercalation Modified LDH Combination with Decabromodiphenyl Ethane[J]. Journal of the Chinese Ceramic Society, 2021 , 49 (7) : 1359 -1366 . DOI: 10.14062/j.issn.0454-5648.20200984
  • 南宁市科学研究与技术开发计划项目(20191019)
  • 国家自然科学基金(42062003)
  • 广西自然科学基金(2018GXNSFAA294012; 2019GXNSFBA245052)
  • 桂林理工大学科研启动基金(GUTQDJJ2019133)
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2021年第49卷第7期
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doi: 10.14062/j.issn.0454-5648.20200984
  • 接收时间:2020-12-30
  • 首发时间:2026-10-30
  • 出版时间:2021-07-20
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  • 收稿日期:2020-12-30
  • 修回日期:2021-01-18
基金
南宁市科学研究与技术开发计划项目(20191019)
国家自然科学基金(42062003)
广西自然科学基金(2018GXNSFAA294012; 2019GXNSFBA245052)
桂林理工大学科研启动基金(GUTQDJJ2019133)
作者信息
    1.桂林理工大学材料科学与工程学院,广西 桂林 541004
    2.桂林理工大学化学与生物工程学院,广西 桂林 541004
    3.广西华锑科技有限公司,南宁 530004
    4.广西壮族自治区北部湾绿色海工材料工程研究中心,广西 桂林 541004

通讯作者:

王林江(1962—),男,博士,教授。
许艳旗(1991—),女,博士,讲师。
参考文献
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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