Article(id=1322943313787093376, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942495801356913, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200441, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1592496000000, receivedDateStr=2020-06-19, revisedDate=1596816000000, revisedDateStr=2020-08-08, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343865104, onlineDateStr=2026-10-30, pubDate=1616169600000, pubDateStr=2021-03-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343865104, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343865104, creator=13701087609, updateTime=1793343865104, updator=13701087609, issue=Issue{id=1322942495801356913, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='3', pageStart='441', pageEnd='604', issueExtLink='null', onlineDate='null', pubDate='1616169600000', pubDateStr='2021-03-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343670081, creator='13701087609', updateTime=1793345495044, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322950150322258738, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942495801356913, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322950150322258739, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942495801356913, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=483, endPage=494, ext={EN=ArticleExt(id=1322943314055528833, articleId=1322943313787093376, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Solution-Processed Cu2ZnSn(S,Se)4 Thin Film Solar Cells, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

Solution-based approaches are regarded as one of great potential methods for preparing Cu2ZnSn(S,Se)4 thin film solar cells due to the advantages of simple operation, high material utilization, and low material cost. This review systematically summarized recent development on the solution-based approaches for preparing Cu2ZnSn(S,Se)4 thin film solar cells, i.e., spray pyrolysis, bath-based aqueous solution, nanoparticle solution and direct solution coating methods. Recent research results on solution-based high-efficient Cu2ZnSn(S,Se)4 thin film solar cells based on the optimization of cation ratio, sintering conditions and selenium conditions, as well as Na, Ge and other metal elements doping were represented. This review gave the advantages and problems in the process of solution-based preparation. t In addition, the future research could also focus on membrane composition and reaction pathway, as well as some effective methods to reduce the intrinsic defects of Cu2ZnSn(S,Se)4 absorber layer.

, authors=Guonan CUI1, Yanchun YANG1, 2, Yuemin LI1, Yiming WANG2, Chengjun ZHU2, authorsList=Guonan CUI, Yanchun YANG, Yuemin LI, Yiming WANG, Chengjun ZHU, authorCompany=null, correspAuthors=Yanchun YANG, authorNote=

CUI Guonan (1995-), male, Master candidate. E-mail:

, correspAuthorsNote=
YANG Yangchun (1989-), female, Ph.D., Associate Professor. E-mail:
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322943314428821891, articleId=1322943313787093376, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=溶液法制备铜锌锡硫硒薄膜太阳能电池的研究进展, columnId=0, journalTitle=硅酸盐学报, columnName=, runingTitle=null, highlight=null, articleAbstract=

溶液法因其具有操作流程简单、材料利用率高以及成本低廉等潜在优势,被认为是一种很有发展前景和应用潜力的铜锌锡硫硒(Cu2ZnSn(S,Se)4,CZTSSe)薄膜太阳能电池制备方法。本工作将溶液法的研究现状按喷雾热解法、基于浴的水溶液法、纳米粒子溶液法和直接溶液涂膜法进行分类介绍。通过分析和比较各种方法报道过的优化途径(如优化阳离子比例、烧结条件和硒化条件,以及掺入Na、Ge等金属元素),对溶液法制备的高性能Cu2ZnSn(S,Se)4薄膜太阳能电池的当前研究成果进行综述,并总结了各种溶液法制备铜锌锡硫硒薄膜电池的优势和所存在的问题。展望其未来的发展,认为今后的研究重点应侧重于薄膜组成和反应途径,以寻求降低Cu2ZnSn(S,Se)4吸收层的本征缺陷的方法。

, authors=崔国楠1, 杨艳春1, 2, 李月敏1, 王一鸣2, 朱成军2, authorsList=崔国楠, 杨艳春, 李月敏, 王一鸣, 朱成军, authorCompany=null, correspAuthors=杨艳春, authorNote=

崔国楠(1995—),男,硕士研究生。

, correspAuthorsNote=
杨艳春(1989—),女,博士,副教授。
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溶液法制备铜锌锡硫硒薄膜太阳能电池的研究进展
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崔国楠 1 , 杨艳春 1, 2 , 李月敏 1 , 王一鸣 2 , 朱成军 2
硅酸盐学报 | 2021,49(3): 483-494
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硅酸盐学报 | 2021 , 49 (3) : 483 -494
溶液法制备铜锌锡硫硒薄膜太阳能电池的研究进展
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崔国楠1 , 杨艳春1, 2 , 李月敏1, 王一鸣2, 朱成军2
作者信息
  • 1.内蒙古自治区功能材料物理与化学重点实验室,内蒙古师范大学物理与电子信息学院,呼和浩特 010022
  • 2.内蒙古大学物理科学与技术学院,呼和浩特 010021
通讯作者:
杨艳春(1989—),女,博士,副教授。
作者简介:

崔国楠(1995—),男,硕士研究生。

Solution-Processed Cu2ZnSn(S,Se)4 Thin Film Solar Cells
Guonan CUI1 , Yanchun YANG1, 2 , Yuemin LI1, Yiming WANG2, Chengjun ZHU2
Affiliations
  • 1.Key Laboratory of Functional Materials Physics and Chemistry, College of Physics and Electronic Information, Inner Mongolia Normal University, Hohhot 010022, China
  • 2.School of Physical Science and Technology, Inner Mongolia University, Hohhot 010021, China
  • Corresponding Author:
    YANG Yangchun (1989-), female, Ph.D., Associate Professor. E-mail:

    CUI Guonan (1995-), male, Master candidate. E-mail:

出版时间: 2021-03-20 doi: 10.14062/j.issn.0454-5648.20200441
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溶液法因其具有操作流程简单、材料利用率高以及成本低廉等潜在优势,被认为是一种很有发展前景和应用潜力的铜锌锡硫硒(Cu2ZnSn(S,Se)4,CZTSSe)薄膜太阳能电池制备方法。本工作将溶液法的研究现状按喷雾热解法、基于浴的水溶液法、纳米粒子溶液法和直接溶液涂膜法进行分类介绍。通过分析和比较各种方法报道过的优化途径(如优化阳离子比例、烧结条件和硒化条件,以及掺入Na、Ge等金属元素),对溶液法制备的高性能Cu2ZnSn(S,Se)4薄膜太阳能电池的当前研究成果进行综述,并总结了各种溶液法制备铜锌锡硫硒薄膜电池的优势和所存在的问题。展望其未来的发展,认为今后的研究重点应侧重于薄膜组成和反应途径,以寻求降低Cu2ZnSn(S,Se)4吸收层的本征缺陷的方法。

溶液法  /  铜锌锡硫硒  /  薄膜  /  太阳能电池

Solution-based approaches are regarded as one of great potential methods for preparing Cu2ZnSn(S,Se)4 thin film solar cells due to the advantages of simple operation, high material utilization, and low material cost. This review systematically summarized recent development on the solution-based approaches for preparing Cu2ZnSn(S,Se)4 thin film solar cells, i.e., spray pyrolysis, bath-based aqueous solution, nanoparticle solution and direct solution coating methods. Recent research results on solution-based high-efficient Cu2ZnSn(S,Se)4 thin film solar cells based on the optimization of cation ratio, sintering conditions and selenium conditions, as well as Na, Ge and other metal elements doping were represented. This review gave the advantages and problems in the process of solution-based preparation. t In addition, the future research could also focus on membrane composition and reaction pathway, as well as some effective methods to reduce the intrinsic defects of Cu2ZnSn(S,Se)4 absorber layer.

solution-based approach  /  copper zinc tin sulphur selenium  /  thin film  /  solar cell
崔国楠, 杨艳春, 李月敏, 王一鸣, 朱成军. 溶液法制备铜锌锡硫硒薄膜太阳能电池的研究进展. 硅酸盐学报, 2021 , 49 (3) : 483 -494 . DOI: 10.14062/j.issn.0454-5648.20200441
Guonan CUI, Yanchun YANG, Yuemin LI, Yiming WANG, Chengjun ZHU. Solution-Processed Cu2ZnSn(S,Se)4 Thin Film Solar Cells[J]. Journal of the Chinese Ceramic Society, 2021 , 49 (3) : 483 -494 . DOI: 10.14062/j.issn.0454-5648.20200441
  • 国家自然科学基金青年科学基金(61804085)
  • 中国科学院“西部之光”青年学者A类计划(2019年)
  • 国家级大学生创新创业训练计划(201810135002)
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2021年第49卷第3期
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doi: 10.14062/j.issn.0454-5648.20200441
  • 接收时间:2020-06-19
  • 首发时间:2026-10-30
  • 出版时间:2021-03-20
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  • 收稿日期:2020-06-19
  • 修回日期:2020-08-08
基金
国家自然科学基金青年科学基金(61804085)
中国科学院“西部之光”青年学者A类计划(2019年)
国家级大学生创新创业训练计划(201810135002)
作者信息
    1.内蒙古自治区功能材料物理与化学重点实验室,内蒙古师范大学物理与电子信息学院,呼和浩特 010022
    2.内蒙古大学物理科学与技术学院,呼和浩特 010021

通讯作者:

杨艳春(1989—),女,博士,副教授。
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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