Article(id=1322943298234622193, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942634976752425, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20210082, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1611676800000, receivedDateStr=2021-01-27, revisedDate=1617724800000, revisedDateStr=2021-04-07, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343861396, onlineDateStr=2026-10-30, pubDate=1626710400000, pubDateStr=2021-07-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343861396, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343861396, creator=13701087609, updateTime=1793343861396, updator=13701087609, issue=Issue{id=1322942634976752425, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='7', pageStart='1249', pageEnd='1518', issueExtLink='null', onlineDate='null', pubDate='1626710400000', pubDateStr='2021-07-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343703264, creator='13701087609', updateTime=1793345819416, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322951510828659213, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942634976752425, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322951510828659214, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942634976752425, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1278, endPage=1295, ext={EN=ArticleExt(id=1322943299815874802, articleId=1322943298234622193, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Recent Development and Future Perspective for Multivalent Ion Batteries, columnId=1322942635891110698, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Issue on Energy Material, runingTitle=null, highlight=null, articleAbstract=

In recent years, rechargeable batteries based on multivalent cations (Al3+, Mg2+, Ca2+, Zn2+, etc.) have attracted extensive attention due to their high natural abundance, low cost and good chemical safety. In this review, some achievements and breakthrough progress in the study of multivalent ion batteries, both from home and abroad research teams were summarized. It is found that most researches are focused on the development of anode and cathode materials and the optimization of electrolyte components in aluminum-ion and magnesium-ion batteries. However, there are still some tricky problems to be solved in the rapid development of multivalent ion batteries, such as the structural instability of the cathode materials, the slow migration of ions, the passivation and dendrite problems of the anodes, and the corrosion of the electrolytes. Finally, the future perspective of multivalent ion batteries is prospected. In the later study, looking for multivalent ion battery model with high energy density is the main research direction, in which we could make some explorations and experiments on the modification to the cathode and anode structures to improve corresponding performance, as well as the optimization and matching of multicomponent electrolytes to obtain high-performance multivalent ion batteries.

, authors=Jingyu GAO, Gongrui WANG, Jie LI, Genqiang ZHANG, authorsList=Jingyu GAO, Gongrui WANG, Jie LI, Genqiang ZHANG, authorCompany=null, correspAuthors=Genqiang ZHANG, authorNote=

GAO Jingyu (1996-), male, Doctoral candidate. E-mail:

, correspAuthorsNote=
ZHANG Genqiang (1982-), male, Ph.D, Professor. E-mail:
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近些年来,因金属镁、铝、钙、锌等储量丰富,成本低廉和高安全性,基于多价阳离子(如Al3+,Mg2+,Ca2+,Zn2+等)的可充电电池受到了广泛关注。本工作总结了国内外研究团队在多价离子电池研究方面取得的成果和突破性进展,发现目前多价离子电池研究体系中关于铝离子和镁离子电池的相关研究工作较多,主要侧重于正负极材料的开发以及电解液组分的优化。然而,在多价离子电池体系的快速发展中,我们发现仍然存在一些棘手的问题有待解决,比如正极材料的结构不稳定,较慢的离子迁移速率,负极的钝化及枝晶问题,以及电解液的腐蚀性等。最后就目前多价离子电池体系未来的发展方向进行了展望,即在以后的研究中寻找高能量密度的多价离子电池模型是主要的研究方向,其中可以在正负极材料的结构修饰和性能改进、电解液优化及多组分的匹配等方面进行探究和尝试,以此来获得高性能的多价离子电池。

, authors=高靖宇, 王功瑞, 李杰, 章根强, authorsList=高靖宇, 王功瑞, 李杰, 章根强, authorCompany=null, correspAuthors=章根强, authorNote=

高靖宇(1996—),男,博士研究生。

, correspAuthorsNote=
章根强(1982—),男,博士,教授。
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高靖宇(1996—),男,博士研究生。

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高靖宇(1996—),男,博士研究生。

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多价离子电池的研究现状与展望
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高靖宇 , 王功瑞 , 李杰 , 章根强
硅酸盐学报 | 能源材料专题 2021,49(7): 1278-1295
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硅酸盐学报 |能源材料专题 2021 , 49 (7) : 1278 -1295
多价离子电池的研究现状与展望
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高靖宇 , 王功瑞, 李杰, 章根强
作者信息
  • 中国科学技术大学化学与材料科学学院,合肥 230026
通讯作者:
章根强(1982—),男,博士,教授。
作者简介:

高靖宇(1996—),男,博士研究生。

Recent Development and Future Perspective for Multivalent Ion Batteries
Jingyu GAO , Gongrui WANG, Jie LI, Genqiang ZHANG
Affiliations
  • Department of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026, China
  • Corresponding Author:
    ZHANG Genqiang (1982-), male, Ph.D, Professor. E-mail:

    GAO Jingyu (1996-), male, Doctoral candidate. E-mail:

出版时间: 2021-07-20 doi: 10.14062/j.issn.0454-5648.20210082
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近些年来,因金属镁、铝、钙、锌等储量丰富,成本低廉和高安全性,基于多价阳离子(如Al3+,Mg2+,Ca2+,Zn2+等)的可充电电池受到了广泛关注。本工作总结了国内外研究团队在多价离子电池研究方面取得的成果和突破性进展,发现目前多价离子电池研究体系中关于铝离子和镁离子电池的相关研究工作较多,主要侧重于正负极材料的开发以及电解液组分的优化。然而,在多价离子电池体系的快速发展中,我们发现仍然存在一些棘手的问题有待解决,比如正极材料的结构不稳定,较慢的离子迁移速率,负极的钝化及枝晶问题,以及电解液的腐蚀性等。最后就目前多价离子电池体系未来的发展方向进行了展望,即在以后的研究中寻找高能量密度的多价离子电池模型是主要的研究方向,其中可以在正负极材料的结构修饰和性能改进、电解液优化及多组分的匹配等方面进行探究和尝试,以此来获得高性能的多价离子电池。

多价离子电池  /  正极材料  /  负极材料  /  电解液

In recent years, rechargeable batteries based on multivalent cations (Al3+, Mg2+, Ca2+, Zn2+, etc.) have attracted extensive attention due to their high natural abundance, low cost and good chemical safety. In this review, some achievements and breakthrough progress in the study of multivalent ion batteries, both from home and abroad research teams were summarized. It is found that most researches are focused on the development of anode and cathode materials and the optimization of electrolyte components in aluminum-ion and magnesium-ion batteries. However, there are still some tricky problems to be solved in the rapid development of multivalent ion batteries, such as the structural instability of the cathode materials, the slow migration of ions, the passivation and dendrite problems of the anodes, and the corrosion of the electrolytes. Finally, the future perspective of multivalent ion batteries is prospected. In the later study, looking for multivalent ion battery model with high energy density is the main research direction, in which we could make some explorations and experiments on the modification to the cathode and anode structures to improve corresponding performance, as well as the optimization and matching of multicomponent electrolytes to obtain high-performance multivalent ion batteries.

multivalent ion batteries  /  cathode material  /  anode material  /  electrolyte
高靖宇, 王功瑞, 李杰, 章根强. 多价离子电池的研究现状与展望. 硅酸盐学报, 2021 , 49 (7) : 1278 -1295 . DOI: 10.14062/j.issn.0454-5648.20210082
Jingyu GAO, Gongrui WANG, Jie LI, Genqiang ZHANG. Recent Development and Future Perspective for Multivalent Ion Batteries[J]. Journal of the Chinese Ceramic Society, 2021 , 49 (7) : 1278 -1295 . DOI: 10.14062/j.issn.0454-5648.20210082
  • 国家自然科学基金(51772284)
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2021年第49卷第7期
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doi: 10.14062/j.issn.0454-5648.20210082
  • 接收时间:2021-01-27
  • 首发时间:2026-10-30
  • 出版时间:2021-07-20
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  • 收稿日期:2021-01-27
  • 修回日期:2021-04-07
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国家自然科学基金(51772284)
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    中国科学技术大学化学与材料科学学院,合肥 230026

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章根强(1982—),男,博士,教授。
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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