Article(id=1322943270153757664, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942627649303277, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200608, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1597507200000, receivedDateStr=2020-08-16, revisedDate=1600099200000, revisedDateStr=2020-09-15, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343854701, onlineDateStr=2026-10-30, pubDate=1624118400000, pubDateStr=2021-06-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343854701, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343854701, creator=13701087609, updateTime=1793343854701, updator=13701087609, issue=Issue{id=1322942627649303277, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='6', pageStart='1033', pageEnd='1246', issueExtLink='null', onlineDate='null', pubDate='1624118400000', pubDateStr='2021-06-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343701517, creator='13701087609', updateTime=1793345989266, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322952223231181603, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942627649303277, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322952223231181604, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942627649303277, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1151, endPage=1156, ext={EN=ArticleExt(id=1322943270321529825, articleId=1322943270153757664, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Structure and Optical-Electric Properties of VO
2 Films Prepared by Annealing V Films, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=
Metal V films were prepared on quartz substrates via magnetron sputtering, and then converted to VO2 films via vacuum annealing. The effect of annealing temperature on the surface morphologies, crystalline structures, optical properties and electric properties of VO2 films was investigated. The results show that the crystallinity of the films increases with the increase of annealing temperature from 300℃ to 450℃. The films annealed at 400℃ and 450℃ are a pure monoclinic phase. The grains grow better and the grain boundaries are clear. The valent states of V element for different samples include +4 and +5 states. The presence of V5+ in the films is due to the oxidation in atmosphere. The annealing temperature has little effect on the visible transmittance, but the solar modulation efficiency increases. The metal-insulator transition (MIT) temperature and the resistance of semiconductor phase increase with increasing the annealing temperature. The resistance change amplitude across the MIT for the films annealed at 400℃ and 450℃ is more than 2 orders of magnitude. The hysteresis width and the MIT temperature of the film annealed at 450℃ are 14.6℃ and 61.0℃, respectively.
, authors=Wenhui YUAN
1, Baoshun LIU
2, authorsList=Wenhui YUAN, Baoshun LIU, authorCompany=null, correspAuthors=Baoshun LIU, authorNote=
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2薄膜的结构和光电性能, columnId=0, journalTitle=硅酸盐学报, columnName=, runingTitle=null, highlight=null, articleAbstract=
先用磁控溅射法在石英玻璃基片上制备了金属V膜,然后经过真空退火处理被转变为VO2薄膜。研究了退火温度对VO2薄膜表面形貌、晶体结构、光学性能和电学性能的影响。结果表明:随着退火温度由300℃增加到450℃,VO2薄膜的结晶度明显增加。退火温度在400℃和450℃制备的样品是高纯M相单斜结构,晶粒发育较好,晶界清晰。不同温度退火的样品的表面V元素包含由4+和5+态,5+态的出现是由于表面V元素受环境中氧化导致。虽然退火温度的改变对VO2薄膜的可见光透过率无明显影响,但是可以改善对太阳光的调节效率。VO2薄膜半导体-金属相变温度和半导体相的电阻随热处理温度增加而增加,在400℃和450℃退火样品电阻相变前后的变化幅度可达2个数量级,450℃退火制备样品的滞后宽度和半导体金属相变临界温度分别为14.6℃和61.0℃。
, authors=袁文辉
1, 刘保顺
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刘保顺(1977—),男,博士,研究员。
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