Article(id=1322943237924725489, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942627649303277, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200657, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1598803200000, receivedDateStr=2020-08-31, revisedDate=1600704000000, revisedDateStr=2020-09-22, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343847017, onlineDateStr=2026-10-30, pubDate=1624118400000, pubDateStr=2021-06-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343847017, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343847017, creator=13701087609, updateTime=1793343847017, updator=13701087609, issue=Issue{id=1322942627649303277, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='6', pageStart='1033', pageEnd='1246', issueExtLink='null', onlineDate='null', pubDate='1624118400000', pubDateStr='2021-06-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343701517, creator='13701087609', updateTime=1793345989266, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322952223231181603, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942627649303277, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322952223231181604, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942627649303277, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1167, endPage=1175, ext={EN=ArticleExt(id=1322943238428041970, articleId=1322943237924725489, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Preparation and Photocatalytic Activity of ZnIn2S4/MIL-125 Nanocomposites, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

Zinc indium sulfide (ZnIn2S4)/MIL-125 composites were synthesized by a two-step hydrothermal method. The effect of ZnIn2S4 on the phase, morphology, chemical state, spectral response and photocatalytic performance of the composite was evaluated in detail. The results show that a small amount of ZnIn2S4 results in the morphological evolution of MIL-125 from discoid block to pie shape, and a gradual decrease of the specific surface area. The photocatalytic degradation activity towards rhodamine B dye is greatly improved at the optimal ratio of 0.8% (in mole fraction). The degradation efficiency for the composite is 97.7% while the degradation efficiency for pure MIL-125 is only 70.3% within 50 min. It is indicated that a small amount of ZnIn2S4 suppresses the carrier recombination and improves the carrier transport, finally resulting in the enhancement of photocatalytic activity. In addition, the possible mechanism is also proposed.

, authors=Fei HUANG1, 2, Qi LI2, Sen LUO2, Ai hua YAN1, Yifeng XU2, Xin XIONG2, Miao HU2, authorsList=Fei HUANG, Qi LI, Sen LUO, Ai hua YAN, Yifeng XU, Xin XIONG, Miao HU, authorCompany=null, correspAuthors=Fei HUANG, authorNote=null, correspAuthorsNote=
HUANG Fei, male, Ph.D., Associate Professor. E-mail:
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采用两步水热法合成ZnIn2S4/MIL-125复合纳米材料,评估ZnIn2S4对MIL-125物相结构、形貌结构、化学态、光谱响应和光催化性能的影响。结果表明:添加少量ZnIn2S4使MIL-125由盘状块体逐渐演变为薄饼状,比表面积逐渐减小;当ZnIn2S4添加量(摩尔分数)为0.8%时,ZnIn2S4/MIL-125复合光催化材料在50 min内对罗丹明B的降解效率达到97.7%,而纯相MIL-125的仅为70.3%。引入少量ZnIn2S4显著抑制了MIL-125电子/空穴对的复合速率,提高了载流子传输能力,最终导致光催化活性的显著提高,并据此提出了光催化机理。

, authors=黄飞1, 2, 李祺2, 罗森2, 闫爱华1, 徐怡丰2, 熊鑫2, 胡淼2, authorsList=黄飞, 李祺, 罗森, 闫爱华, 徐怡丰, 熊鑫, 胡淼, authorCompany=null, correspAuthors=黄飞, authorNote=

黄飞(1978—),男,博士,副研究员。

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ZnIn2S4/MIL-125复合纳米材料的制备及光催化活性
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黄飞 1, 2 , 李祺 2 , 罗森 2 , 闫爱华 1 , 徐怡丰 2 , 熊鑫 2 , 胡淼 2
硅酸盐学报 | 2021,49(6): 1167-1175
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硅酸盐学报 | 2021 , 49 (6) : 1167 -1175
ZnIn2S4/MIL-125复合纳米材料的制备及光催化活性
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黄飞1, 2 , 李祺2, 罗森2, 闫爱华1, 徐怡丰2, 熊鑫2, 胡淼2
作者信息
  • 1.中国矿业大学低碳能源研究院,江苏 徐州 221008
  • 2.中国矿业大学材料与物理学院,江苏 徐州 221116
通讯作者:
黄飞
作者简介:

黄飞(1978—),男,博士,副研究员。

Preparation and Photocatalytic Activity of ZnIn2S4/MIL-125 Nanocomposites
Fei HUANG1, 2 , Qi LI2, Sen LUO2, Ai hua YAN1, Yifeng XU2, Xin XIONG2, Miao HU2
Affiliations
  • 1.Low Carbon Energy Institute, China University of Mining and Technology, Xuzhou 221008, Jiangsu, China
  • 2.School of Materials Science and Physics, China University of Mining and Technology, Xuzhou 221116, Jiangsu, China
  • Corresponding Author:
    HUANG Fei, male, Ph.D., Associate Professor. E-mail:
出版时间: 2021-06-20 doi: 10.14062/j.issn.0454-5648.20200657
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采用两步水热法合成ZnIn2S4/MIL-125复合纳米材料,评估ZnIn2S4对MIL-125物相结构、形貌结构、化学态、光谱响应和光催化性能的影响。结果表明:添加少量ZnIn2S4使MIL-125由盘状块体逐渐演变为薄饼状,比表面积逐渐减小;当ZnIn2S4添加量(摩尔分数)为0.8%时,ZnIn2S4/MIL-125复合光催化材料在50 min内对罗丹明B的降解效率达到97.7%,而纯相MIL-125的仅为70.3%。引入少量ZnIn2S4显著抑制了MIL-125电子/空穴对的复合速率,提高了载流子传输能力,最终导致光催化活性的显著提高,并据此提出了光催化机理。

硫铟化锌  /  复合材料  /  光催化  /  载流子复合  /  载流子传输

Zinc indium sulfide (ZnIn2S4)/MIL-125 composites were synthesized by a two-step hydrothermal method. The effect of ZnIn2S4 on the phase, morphology, chemical state, spectral response and photocatalytic performance of the composite was evaluated in detail. The results show that a small amount of ZnIn2S4 results in the morphological evolution of MIL-125 from discoid block to pie shape, and a gradual decrease of the specific surface area. The photocatalytic degradation activity towards rhodamine B dye is greatly improved at the optimal ratio of 0.8% (in mole fraction). The degradation efficiency for the composite is 97.7% while the degradation efficiency for pure MIL-125 is only 70.3% within 50 min. It is indicated that a small amount of ZnIn2S4 suppresses the carrier recombination and improves the carrier transport, finally resulting in the enhancement of photocatalytic activity. In addition, the possible mechanism is also proposed.

zinc indium sulfide  /  nanocomposites  /  photocatalysis  /  carrier recombination  /  carrier transport
黄飞, 李祺, 罗森, 闫爱华, 徐怡丰, 熊鑫, 胡淼. ZnIn2S4/MIL-125复合纳米材料的制备及光催化活性. 硅酸盐学报, 2021 , 49 (6) : 1167 -1175 . DOI: 10.14062/j.issn.0454-5648.20200657
Fei HUANG, Qi LI, Sen LUO, Ai hua YAN, Yifeng XU, Xin XIONG, Miao HU. Preparation and Photocatalytic Activity of ZnIn2S4/MIL-125 Nanocomposites[J]. Journal of the Chinese Ceramic Society, 2021 , 49 (6) : 1167 -1175 . DOI: 10.14062/j.issn.0454-5648.20200657
  • 中央高校基本科研业务费专项(2019XKQYMS04)
  • 江苏省江苏省煤基温室气体减排与资源化利用重点实验室开放基金(2019B006)
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2021年第49卷第6期
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doi: 10.14062/j.issn.0454-5648.20200657
  • 接收时间:2020-08-31
  • 首发时间:2026-10-30
  • 出版时间:2021-06-20
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  • 收稿日期:2020-08-31
  • 修回日期:2020-09-22
基金
中央高校基本科研业务费专项(2019XKQYMS04)
江苏省江苏省煤基温室气体减排与资源化利用重点实验室开放基金(2019B006)
作者信息
    1.中国矿业大学低碳能源研究院,江苏 徐州 221008
    2.中国矿业大学材料与物理学院,江苏 徐州 221116

通讯作者:

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黄飞(1978—),男,博士,副研究员。

"}
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2种不同金属材料的力学参数
科
Family
属数
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genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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