Article(id=1322943220002464399, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942627649303277, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200617, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1597593600000, receivedDateStr=2020-08-17, revisedDate=1600704000000, revisedDateStr=2020-09-22, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343842745, onlineDateStr=2026-10-30, pubDate=1624118400000, pubDateStr=2021-06-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343842745, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343842745, creator=13701087609, updateTime=1793343842745, updator=13701087609, issue=Issue{id=1322942627649303277, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='6', pageStart='1033', pageEnd='1246', issueExtLink='null', onlineDate='null', pubDate='1624118400000', pubDateStr='2021-06-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343701517, creator='13701087609', updateTime=1793345989266, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322952223231181603, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942627649303277, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322952223231181604, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942627649303277, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1111, endPage=1124, ext={EN=ArticleExt(id=1322943220400923280, articleId=1322943220002464399, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Research Progress on Antimony Telluride Based Thermoelectric Thin Films, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

Micro thermoelectric devices based on thermoelectric films have promising applications in various fields such as micro-zone refrigeration and power generation. Thermoelectric films with high power factor and large ZT values are critical materials in these devices. Sb2Te3-based materials are outstanding p-type thermoelectric materials at room temperature. However, the thermoelectric properties of Sb2Te3-based thin films cannot meet the requirement of practical applications. The research background of thermoelectric materials is briefly introduced, the crystal structure of Sb2Te3 is discussed, the preparation techniques of Sb2Te3-based thin films are outlined, and the methods of improving the power factor and reducing the thermal conductivity of Sb2Te3-based thin films are summarized. In particular, the effects of microstructure on thermoelectric properties are focused on to elucidate the mechanism of improving thermoelectric properties of the films, which includes defects, preferential orientation, nanoparticles, superlattice, organic-inorganic hybridization, and so on. In addition, the future research directions for Sb2Te3-based thermoelectric thin films are discussed.

, authors=Wen YI1, 2, Yongjie ZHAO1, Boyu WANG1, Zhifang ZHOU2, Liangliang Li2, Jingbo Li1, authorsList=Wen YI, Yongjie ZHAO, Boyu WANG, Zhifang ZHOU, Liangliang Li, Jingbo Li, authorCompany=null, correspAuthors=Liangliang Li, Jingbo Li, authorNote=

YI Wen (1996-), male, Master candidate. E-mail:

, correspAuthorsNote=
LI Jingbo(1969-), male, Ph.D., Professor; E-mail:
LI Liangliang(1980-), male, Ph.D., Associate Professor.
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322943220610638481, articleId=1322943220002464399, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=Sb2Te3基热电薄膜的研究进展, columnId=0, journalTitle=硅酸盐学报, columnName=, runingTitle=null, highlight=null, articleAbstract=

基于热电薄膜的微型热电器件在微区制冷、温差发电等领域具有广阔应用前景。具有高功率因子、ZT值的热电薄膜对微型热电器件的性能至关重要。Sb2Te3基材料是室温下性能优异的p型热电材料。然而,目前Sb2Te3基薄膜的热电性能仍然不能满足实际应用的需求。简述了热电材料研究的相关背景,介绍了Sb2Te3的晶体结构,概述了Sb2Te3基薄膜的常用制备技术,从提高功率因子和降低热导率2方面综述了提高Sb2Te3基薄膜热电性能的方法。重点介绍了材料组织、微观结构与热电性能的关系,即缺陷、择优取向、纳米颗粒、超晶格、有机无机杂化等对Sb2Te3基薄膜热电性能的影响。此外,对Sb2Te3基热电薄膜的发展方向予以展望。

, authors=易文1, 2, 赵永杰1, 王伯宇1, 周志方2, 李亮亮2, 李静波1, authorsList=易文, 赵永杰, 王伯宇, 周志方, 李亮亮, 李静波, authorCompany=null, correspAuthors=李亮亮, 李静波, authorNote=

易文(1996—),男,硕士研究生。

, correspAuthorsNote=
李静波(1969—),男,博士,教授。
李亮亮(1980—),男,博士,副研究员。
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Sb2Te3基热电薄膜的研究进展
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易文 1, 2 , 赵永杰 1 , 王伯宇 1 , 周志方 2 , 李亮亮 2 , 李静波 1
硅酸盐学报 | 2021,49(6): 1111-1124
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硅酸盐学报 | 2021 , 49 (6) : 1111 -1124
Sb2Te3基热电薄膜的研究进展
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易文1, 2 , 赵永杰1, 王伯宇1, 周志方2, 李亮亮2 , 李静波1
作者信息
  • 1.北京理工大学材料学院,北京 100081
  • 2.清华大学材料学院,北京 100084
通讯作者:
李静波(1969—),男,博士,教授。
李亮亮(1980—),男,博士,副研究员。
作者简介:

易文(1996—),男,硕士研究生。

Research Progress on Antimony Telluride Based Thermoelectric Thin Films
Wen YI1, 2 , Yongjie ZHAO1, Boyu WANG1, Zhifang ZHOU2, Liangliang Li2 , Jingbo Li1
Affiliations
  • 1.School of Materials Science and Engineering, Beijing Institute of Technology, Beijing 100081, China
  • 2.School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China
  • Corresponding Author:
    LI Jingbo(1969-), male, Ph.D., Professor; E-mail:
    LI Liangliang(1980-), male, Ph.D., Associate Professor.

    YI Wen (1996-), male, Master candidate. E-mail:

出版时间: 2021-06-20 doi: 10.14062/j.issn.0454-5648.20200617
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基于热电薄膜的微型热电器件在微区制冷、温差发电等领域具有广阔应用前景。具有高功率因子、ZT值的热电薄膜对微型热电器件的性能至关重要。Sb2Te3基材料是室温下性能优异的p型热电材料。然而,目前Sb2Te3基薄膜的热电性能仍然不能满足实际应用的需求。简述了热电材料研究的相关背景,介绍了Sb2Te3的晶体结构,概述了Sb2Te3基薄膜的常用制备技术,从提高功率因子和降低热导率2方面综述了提高Sb2Te3基薄膜热电性能的方法。重点介绍了材料组织、微观结构与热电性能的关系,即缺陷、择优取向、纳米颗粒、超晶格、有机无机杂化等对Sb2Te3基薄膜热电性能的影响。此外,对Sb2Te3基热电薄膜的发展方向予以展望。

热电薄膜  /  碲化锑  /  热电性能  /  功率因子  /  热导率

Micro thermoelectric devices based on thermoelectric films have promising applications in various fields such as micro-zone refrigeration and power generation. Thermoelectric films with high power factor and large ZT values are critical materials in these devices. Sb2Te3-based materials are outstanding p-type thermoelectric materials at room temperature. However, the thermoelectric properties of Sb2Te3-based thin films cannot meet the requirement of practical applications. The research background of thermoelectric materials is briefly introduced, the crystal structure of Sb2Te3 is discussed, the preparation techniques of Sb2Te3-based thin films are outlined, and the methods of improving the power factor and reducing the thermal conductivity of Sb2Te3-based thin films are summarized. In particular, the effects of microstructure on thermoelectric properties are focused on to elucidate the mechanism of improving thermoelectric properties of the films, which includes defects, preferential orientation, nanoparticles, superlattice, organic-inorganic hybridization, and so on. In addition, the future research directions for Sb2Te3-based thermoelectric thin films are discussed.

thermoelectric thin film  /  antimony telluride  /  thermoelectric property  /  power factor  /  thermal conductivity
易文, 赵永杰, 王伯宇, 周志方, 李亮亮, 李静波. Sb2Te3基热电薄膜的研究进展. 硅酸盐学报, 2021 , 49 (6) : 1111 -1124 . DOI: 10.14062/j.issn.0454-5648.20200617
Wen YI, Yongjie ZHAO, Boyu WANG, Zhifang ZHOU, Liangliang Li, Jingbo Li. Research Progress on Antimony Telluride Based Thermoelectric Thin Films[J]. Journal of the Chinese Ceramic Society, 2021 , 49 (6) : 1111 -1124 . DOI: 10.14062/j.issn.0454-5648.20200617
  • 国家自然科学基金(51972029)
  • 国家重点研发计划(2016YFA0201003)
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2021年第49卷第6期
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doi: 10.14062/j.issn.0454-5648.20200617
  • 接收时间:2020-08-17
  • 首发时间:2026-10-30
  • 出版时间:2021-06-20
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  • 收稿日期:2020-08-17
  • 修回日期:2020-09-22
基金
国家自然科学基金(51972029)
国家重点研发计划(2016YFA0201003)
作者信息
    1.北京理工大学材料学院,北京 100081
    2.清华大学材料学院,北京 100084

通讯作者:

李静波(1969—),男,博士,教授。
李亮亮(1980—),男,博士,副研究员。
参考文献
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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