Article(id=1322943214847664743, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942627649303277, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200651, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1598630400000, receivedDateStr=2020-08-29, revisedDate=1603123200000, revisedDateStr=2020-10-20, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343841516, onlineDateStr=2026-10-30, pubDate=1624118400000, pubDateStr=2021-06-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343841516, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343841516, creator=13701087609, updateTime=1793343841516, updator=13701087609, issue=Issue{id=1322942627649303277, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='6', pageStart='1033', pageEnd='1246', issueExtLink='null', onlineDate='null', pubDate='1624118400000', pubDateStr='2021-06-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343701517, creator='13701087609', updateTime=1793345989266, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322952223231181603, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942627649303277, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322952223231181604, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942627649303277, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1135, endPage=1142, ext={EN=ArticleExt(id=1322943215057379944, articleId=1322943214847664743, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Oxidation Resistance and Microwave Absorption of FeCo@Nano-SiO2, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

FeCo@nano-SiO2 was prepared via a modified Stöber method using tetraethyl orthosilicate using FeCo as raw materials. The results show that the powder has a uniform core-shell structure. The reflection loss (RL) of FeCo@nano-SiO2 reaches -36.1 dB with the thickness of 2.6 mm, and the effective absorption bandwidth with RL<-10 dB is 3.2 GHz when the content of SiO2 is 35% (in mass fraction). The mass of FeCo@nano-SiO2 only increases 2% from room temperature to 800℃, and the optimum oxidation resistance can be obtained at the content of SiO2 of 65%. The SiO2 shell optimizes the impedance matching of FeCo, further facilitating the electromagnetic wave absorption, and prevents the contact between FeCo and oxygen at a high temperature, thus improving the oxidation resistance.

, authors=Jing LI, Yingli ZHU, Xiangcheng LI, Ping'an CHEN, Boquan ZHU, authorsList=Jing LI, Yingli ZHU, Xiangcheng LI, Ping'an CHEN, Boquan ZHU, authorCompany=null, correspAuthors=Yingli ZHU, Xiangcheng LI, authorNote=

LI Jing (1997-), female, Master candidate. E-mail:

, correspAuthorsNote=
ZHU Yingli (1993-), female, Ph.D., Lecturer; E-mail:
LI Xiangcheng (1978-), male, Ph.D., Professor.
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322943215443255913, articleId=1322943214847664743, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=FeCo@纳米SiO2的抗氧化及吸波性能, columnId=0, journalTitle=硅酸盐学报, columnName=, runingTitle=null, highlight=null, articleAbstract=

以正硅酸四乙酯和FeCo为原料,采用改进的Stöber工艺制备了FeCo@纳米SiO2。结果表明:制备粉体为均匀核壳结构;当SiO2含量为35%(质量分数)时,样品的最低反射损耗(RL)在厚度为2.6 mm时达到-36.1 dB,有效吸收带宽(RL<-10 dB)为3.2 GHz;当SiO2含量为65%时,样品具有最佳的抗氧化性,升温至800℃,质量增加仅2%。SiO2的包覆不仅优化了FeCo的阻抗匹配,有利于电磁波吸收,而且在高温下SiO2可以阻隔FeCo和氧气接触,增加其抗氧化性。

, authors=李晶, 朱颖丽, 李享成, 陈平安, 朱伯铨, authorsList=李晶, 朱颖丽, 李享成, 陈平安, 朱伯铨, authorCompany=null, correspAuthors=朱颖丽, 李享成, authorNote=

李晶(1997—),女,硕士研究生。

, correspAuthorsNote=
朱颖丽(1993—),女,博士,讲师。
李享成(1978—),男,博士,教授。
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李晶(1997—),女,硕士研究生。

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FeCo@纳米SiO2的抗氧化及吸波性能
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李晶 , 朱颖丽 , 李享成 , 陈平安 , 朱伯铨
硅酸盐学报 | 2021,49(6): 1135-1142
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硅酸盐学报 | 2021 , 49 (6) : 1135 -1142
FeCo@纳米SiO2的抗氧化及吸波性能
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李晶 , 朱颖丽 , 李享成 , 陈平安, 朱伯铨
作者信息
  • 武汉科技大学省部共建耐火材料与冶金国家重点实验室,武汉 430081
通讯作者:
朱颖丽(1993—),女,博士,讲师。
李享成(1978—),男,博士,教授。
作者简介:

李晶(1997—),女,硕士研究生。

Oxidation Resistance and Microwave Absorption of FeCo@Nano-SiO2
Jing LI , Yingli ZHU , Xiangcheng LI , Ping'an CHEN, Boquan ZHU
Affiliations
  • The State Key Laboratory of Refractories and Metallurgy, Wuhan University of Science and Technology, Wuhan 430081, China
  • Corresponding Author:
    ZHU Yingli (1993-), female, Ph.D., Lecturer; E-mail:
    LI Xiangcheng (1978-), male, Ph.D., Professor.

    LI Jing (1997-), female, Master candidate. E-mail:

出版时间: 2021-06-20 doi: 10.14062/j.issn.0454-5648.20200651
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以正硅酸四乙酯和FeCo为原料,采用改进的Stöber工艺制备了FeCo@纳米SiO2。结果表明:制备粉体为均匀核壳结构;当SiO2含量为35%(质量分数)时,样品的最低反射损耗(RL)在厚度为2.6 mm时达到-36.1 dB,有效吸收带宽(RL<-10 dB)为3.2 GHz;当SiO2含量为65%时,样品具有最佳的抗氧化性,升温至800℃,质量增加仅2%。SiO2的包覆不仅优化了FeCo的阻抗匹配,有利于电磁波吸收,而且在高温下SiO2可以阻隔FeCo和氧气接触,增加其抗氧化性。

铁钴合金@纳米二氧化硅  /  电磁波吸收  /  有效吸收带宽  /  抗氧化性

FeCo@nano-SiO2 was prepared via a modified Stöber method using tetraethyl orthosilicate using FeCo as raw materials. The results show that the powder has a uniform core-shell structure. The reflection loss (RL) of FeCo@nano-SiO2 reaches -36.1 dB with the thickness of 2.6 mm, and the effective absorption bandwidth with RL<-10 dB is 3.2 GHz when the content of SiO2 is 35% (in mass fraction). The mass of FeCo@nano-SiO2 only increases 2% from room temperature to 800℃, and the optimum oxidation resistance can be obtained at the content of SiO2 of 65%. The SiO2 shell optimizes the impedance matching of FeCo, further facilitating the electromagnetic wave absorption, and prevents the contact between FeCo and oxygen at a high temperature, thus improving the oxidation resistance.

iron-cobalt alloy@nano-silicon dioxide  /  electromagnetic wave absorption  /  effective absorption bandwidth  /  oxidation resistance
李晶, 朱颖丽, 李享成, 陈平安, 朱伯铨. FeCo@纳米SiO2的抗氧化及吸波性能. 硅酸盐学报, 2021 , 49 (6) : 1135 -1142 . DOI: 10.14062/j.issn.0454-5648.20200651
Jing LI, Yingli ZHU, Xiangcheng LI, Ping'an CHEN, Boquan ZHU. Oxidation Resistance and Microwave Absorption of FeCo@Nano-SiO2[J]. Journal of the Chinese Ceramic Society, 2021 , 49 (6) : 1135 -1142 . DOI: 10.14062/j.issn.0454-5648.20200651
  • 国家自然科学基金(51972242)
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doi: 10.14062/j.issn.0454-5648.20200651
  • 接收时间:2020-08-29
  • 首发时间:2026-10-30
  • 出版时间:2021-06-20
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  • 收稿日期:2020-08-29
  • 修回日期:2020-10-20
基金
国家自然科学基金(51972242)
作者信息
    武汉科技大学省部共建耐火材料与冶金国家重点实验室,武汉 430081

通讯作者:

朱颖丽(1993—),女,博士,讲师。
李享成(1978—),男,博士,教授。
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2种不同金属材料的力学参数
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属数
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genus
种数
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species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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