Article(id=1322943198775095438, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322943149844345666, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20210540, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1625241600000, receivedDateStr=2021-07-03, revisedDate=1627488000000, revisedDateStr=2021-07-29, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343837684, onlineDateStr=2026-10-30, pubDate=1639929600000, pubDateStr=2021-12-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343837684, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343837684, creator=13701087609, updateTime=1793343837684, updator=13701087609, issue=Issue{id=1322943149844345666, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='12', pageStart='2549', pageEnd='2816', issueExtLink='null', onlineDate='null', pubDate='1639929600000', pubDateStr='2021-12-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343826018, creator='13701087609', updateTime=1793345974749, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322952162350859029, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322943149844345666, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322952162350859030, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322943149844345666, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=2589, endPage=2594, ext={EN=ArticleExt(id=1322943199462961295, articleId=1322943198775095438, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Effect of In-situ Synthesized ZrB2 Content on Microstructure and Properties of SiC-ZrB2 Composites, columnId=1322943189916725340, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Topic on Engineering Ceramic Material, runingTitle=null, highlight=null, articleAbstract=

ZrB2 with different volume contents (30%, 35%, 40% and 45%) was in-situ synthesized in SiC matrix with silicon carbide (SiC), zirconium dioxide (ZrO2), boron carbide (B4C), water-soluble phenolic resin and carbon black as raw materials. SiC-ZrB2 composites were prepared via pressureless sintering. The effect of ZrB2 content on the microstructure and properties was investigated by X-ray diffraction, scanning electron microscopy, and electronic universal tests. The results show that the phase composition of the composites with different ZrB2 contents are SiC and ZrB2 with a little of B13C2. The grain size of ZrB2 increases, the particles interconnect, the density, mechanical properties and electrical conductivity of the composites increase when ZrB2 content increases. At ZrB2 content of 45%, the volume density, open porosity, relative density, flexural strength, vickers hardness and volume resistivity of the composites are 4.16 g/cm3, 0.27%, 95%, (332±17) MPa, (16±2) GPa and (2.35±0.7×10-6)Ω·m, respectively.

, authors=Nan HUANG, Lingfeng HAN, Cuiping ZHANG, Xinyan YUE, Hongqiang RU, Wei WANG, authorsList=Nan HUANG, Lingfeng HAN, Cuiping ZHANG, Xinyan YUE, Hongqiang RU, Wei WANG, authorCompany=null, correspAuthors=Cuiping ZHANG, authorNote=

HUANG Nan(1997-), female, Master candidate. E-mail:

, correspAuthorsNote=
ZHANG Cuiping(1983-), female, Ph.D., Lecturer. E-mail:
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以碳化硅(SiC)、二氧化锆(ZrO2)、碳化硼(B4C)、水溶性酚醛树脂以及炭黑为原料,基于原位反应合成法在SiC基体中合成不同体积含量[30%(体积分数)、35%、40%、45%]的ZrB2,并采用无压烧结法制备得到SiC-ZrB2陶瓷复合材料,研究了ZrB2含量对SiC-ZrB2复合材料物相组成、显微组织、力学性能以及电学性能的影响。结果表明:不同ZrB2含量的复合材料中,其相组成均为SiC和ZrB2,并存在少量的B13C2;随着ZrB2含量的增加,复合材料中ZrB2晶粒尺寸增大、ZrB2颗粒间呈相互连接趋势,并且复合材料致密度、力学性能与导电性能均呈增加趋势。当ZrB2含量为45%时,复合材料的体积密度、开口气孔率、相对密度、抗折强度、Vickers硬度和电阻率分别为4.16 g/cm3、0.27%、95%、(332±17)MPa、(16±2) GPa和(2.35±0.7×10-6)Ω·m。

, authors=黄楠, 韩凌锋, 张翠萍, 岳新艳, 茹红强, 王伟, authorsList=黄楠, 韩凌锋, 张翠萍, 岳新艳, 茹红强, 王伟, authorCompany=null, correspAuthors=张翠萍, authorNote=

黄楠(1997—),女,硕士研究生。

, correspAuthorsNote=
张翠萍(1983—),女,讲师。
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原位合成ZrB2对SiC-ZrB2陶瓷复合材料组织与性能的影响
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黄楠 , 韩凌锋 , 张翠萍 , 岳新艳 , 茹红强 , 王伟
硅酸盐学报 | 工程陶瓷材料专题 2021,49(12): 2589-2594
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硅酸盐学报 |工程陶瓷材料专题 2021 , 49 (12) : 2589 -2594
原位合成ZrB2对SiC-ZrB2陶瓷复合材料组织与性能的影响
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黄楠 , 韩凌锋, 张翠萍 , 岳新艳, 茹红强, 王伟
作者信息
  • 东北大学材料科学与工程学院,材料各向异性与织构教育部重点实验室,沈阳 110819
通讯作者:
张翠萍(1983—),女,讲师。
作者简介:

黄楠(1997—),女,硕士研究生。

Effect of In-situ Synthesized ZrB2 Content on Microstructure and Properties of SiC-ZrB2 Composites
Nan HUANG , Lingfeng HAN, Cuiping ZHANG , Xinyan YUE, Hongqiang RU, Wei WANG
Affiliations
  • School of Materials Science and Engineering, Northeastern University, Shenyang 110819, China; Key Laboratory for Anisotropy and Texture of Materials Ministry of Education, Shenyang 110819, China
  • Corresponding Author:
    ZHANG Cuiping(1983-), female, Ph.D., Lecturer. E-mail:

    HUANG Nan(1997-), female, Master candidate. E-mail:

出版时间: 2021-12-20 doi: 10.14062/j.issn.0454-5648.20210540
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以碳化硅(SiC)、二氧化锆(ZrO2)、碳化硼(B4C)、水溶性酚醛树脂以及炭黑为原料,基于原位反应合成法在SiC基体中合成不同体积含量[30%(体积分数)、35%、40%、45%]的ZrB2,并采用无压烧结法制备得到SiC-ZrB2陶瓷复合材料,研究了ZrB2含量对SiC-ZrB2复合材料物相组成、显微组织、力学性能以及电学性能的影响。结果表明:不同ZrB2含量的复合材料中,其相组成均为SiC和ZrB2,并存在少量的B13C2;随着ZrB2含量的增加,复合材料中ZrB2晶粒尺寸增大、ZrB2颗粒间呈相互连接趋势,并且复合材料致密度、力学性能与导电性能均呈增加趋势。当ZrB2含量为45%时,复合材料的体积密度、开口气孔率、相对密度、抗折强度、Vickers硬度和电阻率分别为4.16 g/cm3、0.27%、95%、(332±17)MPa、(16±2) GPa和(2.35±0.7×10-6)Ω·m。

碳化硅-硼化锆陶瓷复合材料  /  原位合成  /  无压烧结  /  显微组织

ZrB2 with different volume contents (30%, 35%, 40% and 45%) was in-situ synthesized in SiC matrix with silicon carbide (SiC), zirconium dioxide (ZrO2), boron carbide (B4C), water-soluble phenolic resin and carbon black as raw materials. SiC-ZrB2 composites were prepared via pressureless sintering. The effect of ZrB2 content on the microstructure and properties was investigated by X-ray diffraction, scanning electron microscopy, and electronic universal tests. The results show that the phase composition of the composites with different ZrB2 contents are SiC and ZrB2 with a little of B13C2. The grain size of ZrB2 increases, the particles interconnect, the density, mechanical properties and electrical conductivity of the composites increase when ZrB2 content increases. At ZrB2 content of 45%, the volume density, open porosity, relative density, flexural strength, vickers hardness and volume resistivity of the composites are 4.16 g/cm3, 0.27%, 95%, (332±17) MPa, (16±2) GPa and (2.35±0.7×10-6)Ω·m, respectively.

silicon carbide-zirconium boride composites  /  in-situ synthesis  /  pressureless sintering  /  microstructure
黄楠, 韩凌锋, 张翠萍, 岳新艳, 茹红强, 王伟. 原位合成ZrB2对SiC-ZrB2陶瓷复合材料组织与性能的影响. 硅酸盐学报, 2021 , 49 (12) : 2589 -2594 . DOI: 10.14062/j.issn.0454-5648.20210540
Nan HUANG, Lingfeng HAN, Cuiping ZHANG, Xinyan YUE, Hongqiang RU, Wei WANG. Effect of In-situ Synthesized ZrB2 Content on Microstructure and Properties of SiC-ZrB2 Composites[J]. Journal of the Chinese Ceramic Society, 2021 , 49 (12) : 2589 -2594 . DOI: 10.14062/j.issn.0454-5648.20210540
  • 辽宁省自然基金资助计划(2019-MS-126)
  • 国家重点研发计划(2017YFB0310300)
  • 国家自然科学基金(51602041; 51772048)
  • 装备预先研究项目(41422010905; 41422010903)
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doi: 10.14062/j.issn.0454-5648.20210540
  • 接收时间:2021-07-03
  • 首发时间:2026-10-30
  • 出版时间:2021-12-20
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  • 收稿日期:2021-07-03
  • 修回日期:2021-07-29
基金
辽宁省自然基金资助计划(2019-MS-126)
国家重点研发计划(2017YFB0310300)
国家自然科学基金(51602041; 51772048)
装备预先研究项目(41422010905; 41422010903)
作者信息
    东北大学材料科学与工程学院,材料各向异性与织构教育部重点实验室,沈阳 110819

通讯作者:

张翠萍(1983—),女,讲师。
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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