Article(id=1322943093913297464, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942495801356913, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200538, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1595260800000, receivedDateStr=2020-07-21, revisedDate=1598457600000, revisedDateStr=2020-08-27, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343812682, onlineDateStr=2026-10-30, pubDate=1616169600000, pubDateStr=2021-03-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343812682, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343812682, creator=13701087609, updateTime=1793343812682, updator=13701087609, issue=Issue{id=1322942495801356913, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='3', pageStart='441', pageEnd='604', issueExtLink='null', onlineDate='null', pubDate='1616169600000', pubDateStr='2021-03-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343670081, creator='13701087609', updateTime=1793345495044, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322950150322258738, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942495801356913, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322950150322258739, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942495801356913, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=511, endPage=518, ext={EN=ArticleExt(id=1322943095456801337, articleId=1322943093913297464, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Structure and Ferroelectric Properties of BiFeO3 Nano-Crystalline Film Substituted at A/B Site, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

The nano-crystalline ferroelectric films composed of BiFe0.95Mn0.05O3 and Bi0.9Nd0.1FeO3 were fabricated on the fluorine-doped tin oxide/glass substrates via the simple and cost-effective chemical solution deposition method combined with spin-coating and the subsequent layer-by-layer annealing technique. Microstructures and ferroelectric properties of the samples were investigated. Results show that either BiFe0.95Mn0.05O3 or Bi0.9Nd0.1FeO3 film has a single polycrystalline perovskite phase structure with fine and homogeneous grains and smooth surface in addition to a compact and dense structure. Both film samples exhibited well-saturated polarization-electric field hysteresis loops. Especially, the BiFe0.95Mn0.05O3 film showed more preferential upward polarization orientation and superior ferroelectric properties than the Bi0.9Nd0.1FeO3 film, which was reflected by a high remanent polarization (Pr) of 60 μC·cm-2 and stable ferroelectric responses to frequency and temperature in the ranges of 1 to 50 kHz and 25 to 200℃ in addition to retention capability of 1×103 seconds and fatigue endurance over 1×109 cycles.

, authors=Yajie HAN1, 2, Jin QIAN1, 2, Jianrong WANG2, Xiujuan LIN1, Changhong YANG1, Shifeng HUANG1, authorsList=Yajie HAN, Jin QIAN, Jianrong WANG, Xiujuan LIN, Changhong YANG, Shifeng HUANG, authorCompany=null, correspAuthors=Changhong YANG, authorNote=

HAN Yajie (1995-), female, Master. E-mail:

, correspAuthorsNote=
YANG Changhong (1977-), female, Ph.D., Professor. E-mail:
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322943095649739322, articleId=1322943093913297464, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=A/B位离子掺杂BiFeO3纳米薄膜的微结构与铁电性能, columnId=0, journalTitle=硅酸盐学报, columnName=, runingTitle=null, highlight=null, articleAbstract=

采用化学溶液法结合层层旋涂退火工艺,在掺氟氧化锡导电玻璃基片上制备了BiFe0.95Mn0.05O3和Bi0.9Nd0.1FeO3纳米晶铁电薄膜,并分析比较了其微结构和铁电性能。结果表明:2组分样品均为单相多晶钙钛矿结构,晶粒细小均匀,表面平整,结构致密。两薄膜均获得了饱和电滞回线,且BiFe0.95Mn0.05O3薄膜具有向上的择优取向极化和更优异的铁电性能,其剩余极化强度(Pr)达60 μC·cm-2,在1~50 kHz频率范围与25~200℃温度区间内铁电极化响应稳定,保持时间长达1×103 s工作与反复极化翻转高达1×109次表现出优异的电荷保持力和抗疲劳稳定性。

, authors=韩亚洁1, 2, 钱进1, 2, 王建荣2, 林秀娟1, 杨长红1, 黄世峰1, authorsList=韩亚洁, 钱进, 王建荣, 林秀娟, 杨长红, 黄世峰, authorCompany=null, correspAuthors=杨长红, authorNote=

韩亚洁(1995—),女,硕士研究生。

, correspAuthorsNote=
杨长红(1977—),女,博士,教授。
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A/B位离子掺杂BiFeO3纳米薄膜的微结构与铁电性能
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韩亚洁 1, 2 , 钱进 1, 2 , 王建荣 2 , 林秀娟 1 , 杨长红 1 , 黄世峰 1
硅酸盐学报 | 2021,49(3): 511-518
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硅酸盐学报 | 2021 , 49 (3) : 511 -518
A/B位离子掺杂BiFeO3纳米薄膜的微结构与铁电性能
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2.School of Materials Science and Engineering, University of Jinan, Jinan 250022, China, bio={"content":"

HAN Yajie (1995-), female, Master. E-mail:

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HAN Yajie (1995-), female, Master. E-mail:

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韩亚洁(1995—),女,硕士研究生。

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韩亚洁(1995—),女,硕士研究生。

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韩亚洁1, 2 , 钱进1, 2, 王建荣2, 林秀娟1, 杨长红1 , 黄世峰1
作者信息
  • 1.济南大学,山东省建筑材料制备与测试技术重点实验室,济南 250022
  • 2.济南大学,材料科学与工程学院,济南 250022
通讯作者:
杨长红(1977—),女,博士,教授。
作者简介:

韩亚洁(1995—),女,硕士研究生。

Structure and Ferroelectric Properties of BiFeO3 Nano-Crystalline Film Substituted at A/B Site
Yajie HAN1, 2 , Jin QIAN1, 2, Jianrong WANG2, Xiujuan LIN1, Changhong YANG1 , Shifeng HUANG1
Affiliations
  • 1.Shandong Provincial Key Laboratory of Preparation and Measurement of Building Materials, University of Jinan, Jinan 250022, China
  • 2.School of Materials Science and Engineering, University of Jinan, Jinan 250022, China
  • Corresponding Author:
    YANG Changhong (1977-), female, Ph.D., Professor. E-mail:

    HAN Yajie (1995-), female, Master. E-mail:

出版时间: 2021-03-20 doi: 10.14062/j.issn.0454-5648.20200538
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采用化学溶液法结合层层旋涂退火工艺,在掺氟氧化锡导电玻璃基片上制备了BiFe0.95Mn0.05O3和Bi0.9Nd0.1FeO3纳米晶铁电薄膜,并分析比较了其微结构和铁电性能。结果表明:2组分样品均为单相多晶钙钛矿结构,晶粒细小均匀,表面平整,结构致密。两薄膜均获得了饱和电滞回线,且BiFe0.95Mn0.05O3薄膜具有向上的择优取向极化和更优异的铁电性能,其剩余极化强度(Pr)达60 μC·cm-2,在1~50 kHz频率范围与25~200℃温度区间内铁电极化响应稳定,保持时间长达1×103 s工作与反复极化翻转高达1×109次表现出优异的电荷保持力和抗疲劳稳定性。

薄膜  /  铁酸铋  /  离子掺杂  /  微结构  /  铁电性

The nano-crystalline ferroelectric films composed of BiFe0.95Mn0.05O3 and Bi0.9Nd0.1FeO3 were fabricated on the fluorine-doped tin oxide/glass substrates via the simple and cost-effective chemical solution deposition method combined with spin-coating and the subsequent layer-by-layer annealing technique. Microstructures and ferroelectric properties of the samples were investigated. Results show that either BiFe0.95Mn0.05O3 or Bi0.9Nd0.1FeO3 film has a single polycrystalline perovskite phase structure with fine and homogeneous grains and smooth surface in addition to a compact and dense structure. Both film samples exhibited well-saturated polarization-electric field hysteresis loops. Especially, the BiFe0.95Mn0.05O3 film showed more preferential upward polarization orientation and superior ferroelectric properties than the Bi0.9Nd0.1FeO3 film, which was reflected by a high remanent polarization (Pr) of 60 μC·cm-2 and stable ferroelectric responses to frequency and temperature in the ranges of 1 to 50 kHz and 25 to 200℃ in addition to retention capability of 1×103 seconds and fatigue endurance over 1×109 cycles.

thin film  /  bismuth ferrite  /  ion doping  /  microstructure  /  ferroelectric property
韩亚洁, 钱进, 王建荣, 林秀娟, 杨长红, 黄世峰. A/B位离子掺杂BiFeO3纳米薄膜的微结构与铁电性能. 硅酸盐学报, 2021 , 49 (3) : 511 -518 . DOI: 10.14062/j.issn.0454-5648.20200538
Yajie HAN, Jin QIAN, Jianrong WANG, Xiujuan LIN, Changhong YANG, Shifeng HUANG. Structure and Ferroelectric Properties of BiFeO3 Nano-Crystalline Film Substituted at A/B Site[J]. Journal of the Chinese Ceramic Society, 2021 , 49 (3) : 511 -518 . DOI: 10.14062/j.issn.0454-5648.20200538
  • 国家自然科学基金面上项目(51972144; 51632003)
  • 国家自然科学基金联合基金项目(U1806221)
  • 山东省重点研发计划(2019GGX102015)
  • 泰山学者攀登计划
  • 济南市顶尖人才“一事一议”项目
  • 济南市“高校20条”项目(2019GXRC017)
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2021年第49卷第3期
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文章信息
doi: 10.14062/j.issn.0454-5648.20200538
  • 接收时间:2020-07-21
  • 首发时间:2026-10-30
  • 出版时间:2021-03-20
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出版历史
  • 收稿日期:2020-07-21
  • 修回日期:2020-08-27
基金
国家自然科学基金面上项目(51972144; 51632003)
国家自然科学基金联合基金项目(U1806221)
山东省重点研发计划(2019GGX102015)
泰山学者攀登计划
济南市顶尖人才“一事一议”项目
济南市“高校20条”项目(2019GXRC017)
作者信息
    1.济南大学,山东省建筑材料制备与测试技术重点实验室,济南 250022
    2.济南大学,材料科学与工程学院,济南 250022

通讯作者:

杨长红(1977—),女,博士,教授。
参考文献
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https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20200538
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2种不同金属材料的力学参数
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鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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