Article(id=1322943070047711535, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322943027827848128, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20210038, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1607616000000, receivedDateStr=2020-12-11, revisedDate=1617984000000, revisedDateStr=2021-04-10, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343806992, onlineDateStr=2026-10-30, pubDate=1637337600000, pubDateStr=2021-11-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343806992, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343806992, creator=13701087609, updateTime=1793343806992, updator=13701087609, issue=Issue{id=1322943027827848128, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='11', pageStart='2313', pageEnd='2548', issueExtLink='null', onlineDate='null', pubDate='1637337600000', pubDateStr='2021-11-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343796927, creator='13701087609', updateTime=1793345952795, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322952070252343421, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322943027827848128, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322952070252343422, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322943027827848128, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=2529, endPage=2537, ext={EN=ArticleExt(id=1322943070253232432, articleId=1322943070047711535, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Nano-Structural Change of C(N)-A-S-H Gel in Alkali-Activated Slag Pastes Subjected to Wetting-Drying Cyclic Sulphate Attack, columnId=1319726165087077079, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Article, runingTitle=null, highlight=null, articleAbstract=
Nano-structural change of calcium(sodium) aluminium silicate hydrates (C(N)-A-S-H) gel in alkali-activated slag (AAS) mortars after wetting-drying cyclic attack in 5 % (mass fraction, the same below) and 10% sulphate solutions was investigated. The structural and compositional changes of aluminosilicate chains in the main binding phases (C(N)-A-S-H) in AAS mortars were analyzed by Fourier-transform infrared spectroscopy, thermogravimetry-differential scanning calorimetry, 29Si magic angle spinning nuclear magnetic resonance, backscattered scanning electron microscopy and transmission electron microscopy-energy dispersive X-ray spectroscopy. The results show that the sulphate attack increases the degree of reaction of ground granulated blast-furnace slag regardless of sulphate salt type. The main corrosion products in MgSO4 solutions are gypsum, which is not detected in the samples subjected to Na2SO4 solutions. The C(N)-A-S-H with longer chains prefers to be attacked in MgSO4 solutions, whilst the end-members of the chains or short chains of C(N)-A-S-H are broken in Na2SO4 solutions. The C(N)-A-S-H after cyclic water attack is a mixture of tobermorite/jennite dimer to undecamer (T/J2-T/J11), while the Na2SO4 solutions attack results in the destroy of shorter chains and the increase of protonation (or Na-balanced ratio), thus forming a new C(N)-A-S-H gel.
, authors=Xiaohong ZHU
1, Qing LI
2, Xiaojuan KANG
3, Jiaxin DENG
2, Kai YANG
2, authorsList=Xiaohong ZHU, Qing LI, Xiaojuan KANG, Jiaxin DENG, Kai YANG, authorCompany=null, correspAuthors=Kai YANG, authorNote=
ZHU Xiaohong (1991-), male, Ph. D., Research Associate. E-mail: cnxz@leeds.ac.uk
, correspAuthorsNote=
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研究了在5%(质量分数,下同)及10%硫酸盐溶液中干湿循环条件下,碱矿渣水泥砂浆中水化硅酸钙[C(N)-A-S-H]凝胶结构的变化。使用Fourier变换红外光谱,综合热分析,29Si魔角自旋核磁共振,背散射扫描电子显微镜及透射电子显微镜-能谱分析了砂浆中物相组成及C(N)-A-S-H凝胶的化学结构变化。结果表明:硫酸盐侵蚀使碱矿渣(AAS)水泥砂浆中矿渣的水化程度增加且改变C(N)-A-S-H凝胶结构。在MgSO4溶液干湿循环侵蚀后,产生的主要侵蚀产物为石膏;Na2SO4溶液侵蚀后,则未检测到石膏;当MgSO4溶液侵蚀后,C(N)-A-S-H凝胶的部分长链发生了断裂;但Na2SO4溶液侵蚀从C(N)-A-S-H短链或长链端部开始,从而造成了平均链长显著增加。在水中干湿循环下,AAS砂浆中的C(N)-A-S-H凝胶可解释为托贝莫来石/羟基硅钙石二聚体至十一聚体(T/J2 ~ T/J11)混合物,而Na2SO4溶液侵蚀后,可以视为短链破坏且质子化(或Na取代率)提高的新的C(N)-A-S-H凝胶。
, authors=朱效宏
1, 李青
2, 康晓娟
3, 邓加鑫
2, 杨凯
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杨凯(1982—),男,博士,副研究员。
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