Article(id=1322943052683281215, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942446610559222, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200499, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1593964800000, receivedDateStr=2020-07-06, revisedDate=1605369600000, revisedDateStr=2020-11-15, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343802852, onlineDateStr=2026-10-30, pubDate=1613750400000, pubDateStr=2021-02-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343802852, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343802852, creator=13701087609, updateTime=1793343802852, updator=13701087609, issue=Issue{id=1322942446610559222, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='2', pageStart='211', pageEnd='440', issueExtLink='null', onlineDate='null', pubDate='1613750400000', pubDateStr='2021-02-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343658354, creator='13701087609', updateTime=1793345474672, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322950064863314723, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942446610559222, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322950064863314724, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942446610559222, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=250, endPage=255, ext={EN=ArticleExt(id=1322943055241806657, articleId=1322943052683281215, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=New Exploration of Hydrogen-based High-temperature Superconductors under High Pressure, columnId=1319987100586459893, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Issue on Inerim Achievements of Key Program of National Natural Science Foundation of China, runingTitle=null, highlight=null, articleAbstract=
Developing room-temperature superconductors is the ultimate goal of superconducting research field. Recent work focus onthe development of high-temperature superconductors in hydrogen-rich materials under high pressure. Sulfur hydride (H3S) and lanthanide hydride (LaH10) with superconducting transition temperatures (Tc) of >200 K are theoretically predicted and then experimentally confirmed. Hydrogen-rich materials are considered as one of optimum candidates for room-temperature superconductors, thus becoming a hot research aspect in physics and materials. Some contributions in this aspect were achieved involve a variety of new cage-like superhydridesPrH9 and NdH9 are synthesized under high pressure, and their Tc is determined, The magnetic properties of NdH9 are discovered and its magnetic properties suppress a superconductivity; Novel cage-like superhydrides of CaH9 are designed under high pressure, and its Tc is predicted to be 266 K; superconducting zirconium hydrogen compounds ZrH3 and Zr4H15 are synthesized under mild pressure conditions by experimental and theoretical studie; The binary hydrides are extended to ternary hydrides, and MgXH6 (X=Si, Ge) with Tc of 60 K are designed.
, authors=Defang DUAN
1, Xiaoli HUANG
1, Tian CUI
1, 2, authorsList=Defang DUAN, Xiaoli HUANG, Tian CUI, authorCompany=null, correspAuthors=Tian CUI, authorNote=
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实现室温超导是超导研究的终极目标。最近科学家在高压下富氢材料中发现了系列高温超导体,特别是首先被理论预测随后被实验证实的新型硫氢化物H3S和镧系氢化物LaH10,它们的超导转变温度均超过200 K。富氢材料已经被认为是室温超导体的最佳候选体系,成为物理、材料、超导等多学科的研究热点。综述了本课题组在此领域的主要成果,包括:在高压下成功制备了多种新型的笼状结构超氢化物PrH9和NdH9,确定了它们的超导转变温度(Tc),首次发现了具有强磁功能特性的NdH9,其磁性抑制了超导电性;设计了新型笼状超氢化物CaH9,其高压下的理论Tc达到了266 K;实验和理论紧密结合,在温和压力条件下合成了超导锆氢化合物ZrH3和Zr4H15;进一步将二元氢化物拓展到三元氢化物,设计了Tc超过60 K的MgXH6(X=Si,Ge)。
, authors=段德芳
1, 黄晓丽
1, 崔田
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崔田(1964—),男,博士,教授。
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