Article(id=1322943044252737772, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942446610559222, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200273, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1586793600000, receivedDateStr=2020-04-14, revisedDate=1592755200000, revisedDateStr=2020-06-22, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343800843, onlineDateStr=2026-10-30, pubDate=1613750400000, pubDateStr=2021-02-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343800843, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343800843, creator=13701087609, updateTime=1793343800843, updator=13701087609, issue=Issue{id=1322942446610559222, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='2', pageStart='211', pageEnd='440', issueExtLink='null', onlineDate='null', pubDate='1613750400000', pubDateStr='2021-02-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343658354, creator='13701087609', updateTime=1793345474672, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322950064863314723, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942446610559222, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322950064863314724, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942446610559222, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=391, endPage=397, ext={EN=ArticleExt(id=1322943045934653677, articleId=1322943044252737772, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Dissolution Behaviors of K-containing Silicate Fertilizer in Hydrochloric and Citric Acids, columnId=1319726165087077079, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Article, runingTitle=null, highlight=null, articleAbstract=

To clarify the dissolution behavior of K-containing silicate fertilizers produced by high-temperature sintering under acidic condition, the chemical element release and mineral evolution were investigated at ambient temperature in the extractants of hydrochloric and citric acids based on the chemical reactions of minerals contained in silicate fertilizer with acids. The results show that the more elements are released at a lower pH value of extractant. 2% citric acid with pH 2.1 is significantly more effective in dissolving the silicate fertilizer than hydrochloric acid with the same pH value. The dissolution rate of silicate fertilizer in hydrochloric acid at pH value of 0.3 is maximum, and only a mineral detected in the filter residue is leucite. Kaolinite and gibbsite are formed in the reactions of kalsilite and gehlenite with acid. Aluminum release is due to the further reactions of kaolinite and gibbsite with acid.

, authors=Xiaoyan LI1, 2, Fuwei WAN1, Bingqiang ZHAO2, Weimin YU1, authorsList=Xiaoyan LI, Fuwei WAN, Bingqiang ZHAO, Weimin YU, authorCompany=null, correspAuthors=null, authorNote=

LI Xiaoyan (1982-), female, Ph.D., Professor. E-mail:

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为研究高温煅烧法制备的含钾硅酸盐肥料在酸性条件下的溶解行为,选择盐酸与柠檬酸作为浸提液,在室温下研究营养元素溶出与矿物组成的变化,探讨硅酸盐肥料包含矿物遇酸发生的化学反应。结果表明:浸提液pH值越低,元素溶出越多;pH值为2.1的柠檬酸的溶解作用强于pH值为2.1的盐酸。pH值为0.3的盐酸对硅酸盐肥料矿物的溶解率最高,滤渣中仅检测到了白榴石的衍射峰。钾霞石和钙铝黄长石两种矿物遇酸反应后生成的高岭石、三水铝石进一步遇酸反应是铝溶出的直接原因。

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李小燕(1982—),女,博士,教授级高级工程师。

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LI Xiaoyan (1982-), female, Ph.D., Professor. E-mail:

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李小燕(1982—),女,博士,教授级高级工程师。

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李小燕(1982—),女,博士,教授级高级工程师。

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含钾硅酸盐肥料在盐酸与柠檬酸中的溶解行为
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李小燕 1, 2 , 万夫伟 1 , 赵秉强 2 , 俞为民 1
硅酸盐学报 | 研究论文 2021,49(2): 391-397
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硅酸盐学报 |研究论文 2021 , 49 (2) : 391 -397
含钾硅酸盐肥料在盐酸与柠檬酸中的溶解行为
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李小燕1, 2 , 万夫伟1, 赵秉强2, 俞为民1
作者信息
  • 1.天津水泥工业设计研究院有限公司,天津 300400
  • 2.中国农业科学院农业资源与农业区划研究所,北京 100081
作者简介:

李小燕(1982—),女,博士,教授级高级工程师。

Dissolution Behaviors of K-containing Silicate Fertilizer in Hydrochloric and Citric Acids
Xiaoyan LI1, 2 , Fuwei WAN1, Bingqiang ZHAO2, Weimin YU1
Affiliations
  • 1.Tianjin Cement Industry Design and Research Institute Co., Ltd., Tianjin 300400, China
  • 2.Institute of Agricultural Resources and Regional Planning, Chinese Academy of Agricultural Sciences, Beijing 100081, China
  • LI Xiaoyan (1982-), female, Ph.D., Professor. E-mail:

出版时间: 2021-02-20 doi: 10.14062/j.issn.0454-5648.20200273
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为研究高温煅烧法制备的含钾硅酸盐肥料在酸性条件下的溶解行为,选择盐酸与柠檬酸作为浸提液,在室温下研究营养元素溶出与矿物组成的变化,探讨硅酸盐肥料包含矿物遇酸发生的化学反应。结果表明:浸提液pH值越低,元素溶出越多;pH值为2.1的柠檬酸的溶解作用强于pH值为2.1的盐酸。pH值为0.3的盐酸对硅酸盐肥料矿物的溶解率最高,滤渣中仅检测到了白榴石的衍射峰。钾霞石和钙铝黄长石两种矿物遇酸反应后生成的高岭石、三水铝石进一步遇酸反应是铝溶出的直接原因。

pH值  /  盐酸  /  柠檬酸  /  高岭石  /  铝毒

To clarify the dissolution behavior of K-containing silicate fertilizers produced by high-temperature sintering under acidic condition, the chemical element release and mineral evolution were investigated at ambient temperature in the extractants of hydrochloric and citric acids based on the chemical reactions of minerals contained in silicate fertilizer with acids. The results show that the more elements are released at a lower pH value of extractant. 2% citric acid with pH 2.1 is significantly more effective in dissolving the silicate fertilizer than hydrochloric acid with the same pH value. The dissolution rate of silicate fertilizer in hydrochloric acid at pH value of 0.3 is maximum, and only a mineral detected in the filter residue is leucite. Kaolinite and gibbsite are formed in the reactions of kalsilite and gehlenite with acid. Aluminum release is due to the further reactions of kaolinite and gibbsite with acid.

pH value  /  hydrochloric acid  /  citric acid  /  kaolinite  /  aluminum toxicity
李小燕, 万夫伟, 赵秉强, 俞为民. 含钾硅酸盐肥料在盐酸与柠檬酸中的溶解行为. 硅酸盐学报, 2021 , 49 (2) : 391 -397 . DOI: 10.14062/j.issn.0454-5648.20200273
Xiaoyan LI, Fuwei WAN, Bingqiang ZHAO, Weimin YU. Dissolution Behaviors of K-containing Silicate Fertilizer in Hydrochloric and Citric Acids[J]. Journal of the Chinese Ceramic Society, 2021 , 49 (2) : 391 -397 . DOI: 10.14062/j.issn.0454-5648.20200273
  • 十三五国家重点研发计划(2017YFB0310801)
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2021年第49卷第2期
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doi: 10.14062/j.issn.0454-5648.20200273
  • 接收时间:2020-04-14
  • 首发时间:2026-10-30
  • 出版时间:2021-02-20
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  • 收稿日期:2020-04-14
  • 修回日期:2020-06-22
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十三五国家重点研发计划(2017YFB0310801)
作者信息
    1.天津水泥工业设计研究院有限公司,天津 300400
    2.中国农业科学院农业资源与农业区划研究所,北京 100081
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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