Article(id=1322942780502324109, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942780003201932, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20210014, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1609862400000, receivedDateStr=2021-01-06, revisedDate=1618848000000, revisedDateStr=2021-04-20, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343737959, onlineDateStr=2026-10-30, pubDate=1632067200000, pubDateStr=2021-09-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343737959, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343737959, creator=13701087609, updateTime=1793343737959, updator=13701087609, issue=Issue{id=1322942780003201932, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='9', pageStart='1785', pageEnd='2044', issueExtLink='null', onlineDate='null', pubDate='1632067200000', pubDateStr='2021-09-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343737841, creator='13701087609', updateTime=1793345873558, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322951737916665918, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942780003201932, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322951737916665919, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942780003201932, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1985, endPage=1993, ext={EN=ArticleExt(id=1322942781165024142, articleId=1322942780502324109, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Effect of Charge Compensator Mg2+ on Luminescent Properties of CaAl12(PO4)0.1O18.85:Mn4+ Red Phosphor, columnId=1319726165087077079, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Article, runingTitle=null, highlight=null, articleAbstract=

A novel red-emitting phosphor CaAl12-x-y(PO4)0.1O18.85: xMn4+, yMg2+ was synthesized by a high-temperature solid-state method. The crystal structure and luminescence properties of the samples were characterized by X-ray diffraction, scanning electron microscopy and fluorescence spectroscopy. The results show that the synthesized phosphor has a hexagonal crystal structure with the space group of P63/mmc. The optimal doping amounts of Mn4+ and Mg2+ are x of 0.01 and y of 0.1, respectively. Under excitation at 396 nm, CaAl11.89(PO4)0.1O18.85: 0.01Mn4+, 0.1Mg2+ phosphor shows the maximum red light emission at 654 nm, corresponding to 2E→4A2g transition of Mn4+. The luminescence intensity and lifetime of phosphor are improved due to the co-doping with Mg2+ charge compensator. The absolute quantum efficiency of phosphor is 60%, the fluorescence lifetime is 0.97 ms, the color coordinate is in the deep-red region, and the color purity is 97%. The luminescence intensity is still 60% of the initial intensity when the temperature increases to 413K, indicating that this red phosphor with a superior thermal stability is a novel red luminescent material with broad application prospects.

, authors=Han ZHANG1, 2, Guodong FAN1, 2, Fangyi RUAN1, 2, Qianhong PAN3, authorsList=Han ZHANG, Guodong FAN, Fangyi RUAN, Qianhong PAN, authorCompany=null, correspAuthors=Guodong FAN, authorNote=

ZHANG Han (1995-), female, Master candidate. E-mail:

, correspAuthorsNote=
FAN Guodong (1964-), male, Ph.D., Professor. E-mail:
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采用高温固相法合成了基于电荷补偿策略的新型CaAl12-x-y(PO4)0.1O18.85:xMn4+,yMg2+红色荧光粉。采用X射线衍射、扫描电子显微镜和荧光光谱对样品的晶体结构与发光性能进行了表征。结果表明,合成的荧光粉为六方晶系结构,空间群为P63/mmc。Mn4+的最佳掺杂量为x=0.01,Mg2+的最佳掺杂量为y=0.1。在396 nm激发下,CaAl11.89(PO4)0.1O18.85:0.01Mn4+,0.1Mg2+荧光粉在654 nm处显示出最强红光发射,对应Mn4+的2E→4A2g跃迁。通过共掺杂Mg2+电荷补偿剂显著提高了荧光粉的发光强度和寿命,荧光粉的绝对量子效率为60%,荧光寿命为0.97 ms,色坐标位于深红色区域,色纯度高达97%,当温度升高至413 K时,荧光强度仍为初始强度的60%,表明该荧光粉具有出色的热稳定性,是一种具有广阔应用前景的新型红色发光材料。

, authors=张晗1, 2, 樊国栋1, 2, 阮方毅1, 2, 潘谦宏3, authorsList=张晗, 樊国栋, 阮方毅, 潘谦宏, authorCompany=null, correspAuthors=樊国栋, authorNote=

张晗(1995—),女,硕士研究生。

, correspAuthorsNote=
樊国栋(1964—),男,博士,教授。
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电荷补偿剂Mg2+对CaAl12(PO4)0.1O18.85:Mn4+红色荧光粉发光性能的影响
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张晗 1, 2 , 樊国栋 1, 2 , 阮方毅 1, 2 , 潘谦宏 3
硅酸盐学报 | 研究论文 2021,49(9): 1985-1993
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硅酸盐学报 |研究论文 2021 , 49 (9) : 1985 -1993
电荷补偿剂Mg2+对CaAl12(PO4)0.1O18.85:Mn4+红色荧光粉发光性能的影响
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张晗1, 2 , 樊国栋1, 2 , 阮方毅1, 2, 潘谦宏3
作者信息
  • 1.陕西科技大学化学与化工学院,西安 710021
  • 2.陕西科技大学,教育部轻化工助剂化学与技术重点实验室,西安 710021
  • 3.西安长庆化工集团有限公司,西安 710018
通讯作者:
樊国栋(1964—),男,博士,教授。
作者简介:

张晗(1995—),女,硕士研究生。

Effect of Charge Compensator Mg2+ on Luminescent Properties of CaAl12(PO4)0.1O18.85:Mn4+ Red Phosphor
Han ZHANG1, 2 , Guodong FAN1, 2 , Fangyi RUAN1, 2, Qianhong PAN3
Affiliations
  • 1.College of Chemistry and Chemical Engineering, Shaanxi University of Science &Technology, Xi'an 710021, China
  • 2.Key Laboratory of Auxiliary Chemistry & Technology for Chemical Industry, Ministry of Education, Shaanxi University of Science & Technology, Xi'an 710021, China
  • 3.Xi'an Changqing Chemical Group Co., LTD, Xi'an 710018, China
  • Corresponding Author:
    FAN Guodong (1964-), male, Ph.D., Professor. E-mail:

    ZHANG Han (1995-), female, Master candidate. E-mail:

出版时间: 2021-09-20 doi: 10.14062/j.issn.0454-5648.20210014
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采用高温固相法合成了基于电荷补偿策略的新型CaAl12-x-y(PO4)0.1O18.85:xMn4+,yMg2+红色荧光粉。采用X射线衍射、扫描电子显微镜和荧光光谱对样品的晶体结构与发光性能进行了表征。结果表明,合成的荧光粉为六方晶系结构,空间群为P63/mmc。Mn4+的最佳掺杂量为x=0.01,Mg2+的最佳掺杂量为y=0.1。在396 nm激发下,CaAl11.89(PO4)0.1O18.85:0.01Mn4+,0.1Mg2+荧光粉在654 nm处显示出最强红光发射,对应Mn4+的2E→4A2g跃迁。通过共掺杂Mg2+电荷补偿剂显著提高了荧光粉的发光强度和寿命,荧光粉的绝对量子效率为60%,荧光寿命为0.97 ms,色坐标位于深红色区域,色纯度高达97%,当温度升高至413 K时,荧光强度仍为初始强度的60%,表明该荧光粉具有出色的热稳定性,是一种具有广阔应用前景的新型红色发光材料。

锰离子  /  电荷补偿  /  铝磷酸盐  /  红色荧光粉  /  白光发光二极管

A novel red-emitting phosphor CaAl12-x-y(PO4)0.1O18.85: xMn4+, yMg2+ was synthesized by a high-temperature solid-state method. The crystal structure and luminescence properties of the samples were characterized by X-ray diffraction, scanning electron microscopy and fluorescence spectroscopy. The results show that the synthesized phosphor has a hexagonal crystal structure with the space group of P63/mmc. The optimal doping amounts of Mn4+ and Mg2+ are x of 0.01 and y of 0.1, respectively. Under excitation at 396 nm, CaAl11.89(PO4)0.1O18.85: 0.01Mn4+, 0.1Mg2+ phosphor shows the maximum red light emission at 654 nm, corresponding to 2E→4A2g transition of Mn4+. The luminescence intensity and lifetime of phosphor are improved due to the co-doping with Mg2+ charge compensator. The absolute quantum efficiency of phosphor is 60%, the fluorescence lifetime is 0.97 ms, the color coordinate is in the deep-red region, and the color purity is 97%. The luminescence intensity is still 60% of the initial intensity when the temperature increases to 413K, indicating that this red phosphor with a superior thermal stability is a novel red luminescent material with broad application prospects.

manganese ion  /  charge compensation  /  aluminum phosphate  /  red-emitting phosphor  /  white-light-emitting diodes
张晗, 樊国栋, 阮方毅, 潘谦宏. 电荷补偿剂Mg2+对CaAl12(PO4)0.1O18.85:Mn4+红色荧光粉发光性能的影响. 硅酸盐学报, 2021 , 49 (9) : 1985 -1993 . DOI: 10.14062/j.issn.0454-5648.20210014
Han ZHANG, Guodong FAN, Fangyi RUAN, Qianhong PAN. Effect of Charge Compensator Mg2+ on Luminescent Properties of CaAl12(PO4)0.1O18.85:Mn4+ Red Phosphor[J]. Journal of the Chinese Ceramic Society, 2021 , 49 (9) : 1985 -1993 . DOI: 10.14062/j.issn.0454-5648.20210014
  • 轻化工助剂化学与技术教育部重点实验室开放基金(KFKT2019-11)
  • 陕西省科技攻关计划(2016GY-142)
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2021年第49卷第9期
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doi: 10.14062/j.issn.0454-5648.20210014
  • 接收时间:2021-01-06
  • 首发时间:2026-10-30
  • 出版时间:2021-09-20
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  • 收稿日期:2021-01-06
  • 修回日期:2021-04-20
基金
轻化工助剂化学与技术教育部重点实验室开放基金(KFKT2019-11)
陕西省科技攻关计划(2016GY-142)
作者信息
    1.陕西科技大学化学与化工学院,西安 710021
    2.陕西科技大学,教育部轻化工助剂化学与技术重点实验室,西安 710021
    3.西安长庆化工集团有限公司,西安 710018

通讯作者:

樊国栋(1964—),男,博士,教授。
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鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
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