Article(id=1322942702576349440, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942634976752425, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200971, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1609084800000, receivedDateStr=2020-12-28, revisedDate=1617638400000, revisedDateStr=2021-04-06, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343719381, onlineDateStr=2026-10-30, pubDate=1626710400000, pubDateStr=2021-07-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343719381, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343719381, creator=13701087609, updateTime=1793343719381, updator=13701087609, issue=Issue{id=1322942634976752425, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='7', pageStart='1249', pageEnd='1518', issueExtLink='null', onlineDate='null', pubDate='1626710400000', pubDateStr='2021-07-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343703264, creator='13701087609', updateTime=1793345819416, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322951510828659213, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942634976752425, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322951510828659214, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942634976752425, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1457, endPage=1465, ext={EN=ArticleExt(id=1322942702794453249, articleId=1322942702576349440, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Preparation and Lithium Storage Properties of Silicon Nanotubes Based on Halloysite, columnId=1319726165087077079, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Article, runingTitle=null, highlight=null, articleAbstract=

Natural halloysite was used as precursor and template to prepare silicon nanotubes through low temperature aluminothermic reduction. The mechanism of variation in morphology during the reduction process and the lithium storage performance of the silicon nanotube were studied. It was found that the alumina octahedron in the natural halloysite was helpful to maintain the one-dimensional nanotube structure of the products during the low temperature aluminothermic reduction process, leading to the formation of silicon nanotubes. The silicon nanotubes had excellent electrochemical performance when used as anode of lithium-ion batteries, with an initial specific capacity of 3 150 mA·h/g. After 50 cycles, the specific capacity was still 1 977 mA·h/g, which is more than twice the value of commercial silicon anode. At a current density of 2 A/g, the capacity was maintained to be 913 mA·h/g after 200 cycles, which is also much higher than that of commercial silicon anode.

, authors=Mingyuan ZHAO1, Shaobin YANG2, Wei DONG2, Lingmin ZHAO2, Ding SHEN2, authorsList=Mingyuan ZHAO, Shaobin YANG, Wei DONG, Lingmin ZHAO, Ding SHEN, authorCompany=null, correspAuthors=Shaobin YANG, authorNote=

ZHAO Mingyuan (1994-), male, Doctorial candidate. E-mail:

, correspAuthorsNote=
YANG Shaobin (1963-), male, Ph.D., Professor. E-mail:
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以天然埃洛石为前驱体,通过低温铝热还原法和自模板法合成硅纳米管,研究了结构形貌在还原过程中的维持机理及储锂性能。结果表明:在低温铝热还原过程中,天然埃洛石中的铝氧八面体有助于维持埃洛石一维纳米管状结构进而得到硅纳米管。基于埃洛石的硅纳米管作为锂离子电池负极时具有优异的电化学性能,电极首次比放电容量高达3150.2(mA·h)/g,50次循环后显示出1786.0(mA·h)/g的高容量,为商业硅材料比容量的2倍以上,采用2 A/g大电流密度循环时,电极在200次循环后比容量能够保持1197.6 mA·h/g,远高于商业硅电极。

, authors=赵明远1, 杨绍斌2, 董伟2, 赵玲敏2, 沈丁2, authorsList=赵明远, 杨绍斌, 董伟, 赵玲敏, 沈丁, authorCompany=null, correspAuthors=杨绍斌, authorNote=

赵明远(1994—),男,博士研究生。

赵明远,辽宁工程技术大学矿业工程博士研究生,研究方向为功能矿物材料在锂离子电池中的应用。所在课题组研究项目包括:石墨层间距在中间尺度范围内的可控调节及可逆储钠性能研究、炭包覆石墨嵌入化合物的反应及可逆储锂性能研究;微孔离子溶剂化膜减薄机制及煤基炭电容性能研究;锂离子电池高性能石墨负极材料产品开发。

杨绍斌,辽宁工程技术大学材料学院院长,教授,博士研究生导师,1986年毕业于大连理工大学化学工程专业。现任中国金属学会材料科学分会理事,中国硅酸盐学会矿物材料分会理事。长期从事新能源材料、新型炭材料和先进矿物材料等领域的研究工作。先后主持和参与国家自然科学基金重点项目、国家自然科学基金、教育部博士点基金和省部级科研基金及其它项目等17项。发表学术论文130余篇,其中SCI和EI等检索论文40余篇,发明专利授权22项。

, correspAuthorsNote=
杨绍斌(1963—),男,教授。
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赵明远,辽宁工程技术大学矿业工程博士研究生,研究方向为功能矿物材料在锂离子电池中的应用。所在课题组研究项目包括:石墨层间距在中间尺度范围内的可控调节及可逆储钠性能研究、炭包覆石墨嵌入化合物的反应及可逆储锂性能研究;微孔离子溶剂化膜减薄机制及煤基炭电容性能研究;锂离子电池高性能石墨负极材料产品开发。

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赵明远,辽宁工程技术大学矿业工程博士研究生,研究方向为功能矿物材料在锂离子电池中的应用。所在课题组研究项目包括:石墨层间距在中间尺度范围内的可控调节及可逆储钠性能研究、炭包覆石墨嵌入化合物的反应及可逆储锂性能研究;微孔离子溶剂化膜减薄机制及煤基炭电容性能研究;锂离子电池高性能石墨负极材料产品开发。

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基于埃洛石的硅纳米管制备及储锂性能
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赵明远 1 , 杨绍斌 2 , 董伟 2 , 赵玲敏 2 , 沈丁 2
硅酸盐学报 | 研究论文 2021,49(7): 1457-1465
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硅酸盐学报 |研究论文 2021 , 49 (7) : 1457 -1465
基于埃洛石的硅纳米管制备及储锂性能
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ZHAO Mingyuan (1994-), male, Doctorial candidate. E-mail:

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ZHAO Mingyuan (1994-), male, Doctorial candidate. E-mail:

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赵明远,辽宁工程技术大学矿业工程博士研究生,研究方向为功能矿物材料在锂离子电池中的应用。所在课题组研究项目包括:石墨层间距在中间尺度范围内的可控调节及可逆储钠性能研究、炭包覆石墨嵌入化合物的反应及可逆储锂性能研究;微孔离子溶剂化膜减薄机制及煤基炭电容性能研究;锂离子电池高性能石墨负极材料产品开发。

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赵明远,辽宁工程技术大学矿业工程博士研究生,研究方向为功能矿物材料在锂离子电池中的应用。所在课题组研究项目包括:石墨层间距在中间尺度范围内的可控调节及可逆储钠性能研究、炭包覆石墨嵌入化合物的反应及可逆储锂性能研究;微孔离子溶剂化膜减薄机制及煤基炭电容性能研究;锂离子电池高性能石墨负极材料产品开发。

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杨绍斌,辽宁工程技术大学材料学院院长,教授,博士研究生导师,1986年毕业于大连理工大学化学工程专业。现任中国金属学会材料科学分会理事,中国硅酸盐学会矿物材料分会理事。长期从事新能源材料、新型炭材料和先进矿物材料等领域的研究工作。先后主持和参与国家自然科学基金重点项目、国家自然科学基金、教育部博士点基金和省部级科研基金及其它项目等17项。发表学术论文130余篇,其中SCI和EI等检索论文40余篇,发明专利授权22项。

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杨绍斌,辽宁工程技术大学材料学院院长,教授,博士研究生导师,1986年毕业于大连理工大学化学工程专业。现任中国金属学会材料科学分会理事,中国硅酸盐学会矿物材料分会理事。长期从事新能源材料、新型炭材料和先进矿物材料等领域的研究工作。先后主持和参与国家自然科学基金重点项目、国家自然科学基金、教育部博士点基金和省部级科研基金及其它项目等17项。发表学术论文130余篇,其中SCI和EI等检索论文40余篇,发明专利授权22项。

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赵明远1 , 杨绍斌2 , 董伟2, 赵玲敏2, 沈丁2
作者信息
  • 1.辽宁工程技术大学矿业学院,辽宁 阜新 123000
  • 2.辽宁工程技术大学材料科学与工程学院,辽宁 阜新 123000
通讯作者:
杨绍斌(1963—),男,教授。
作者简介:

赵明远(1994—),男,博士研究生。

赵明远,辽宁工程技术大学矿业工程博士研究生,研究方向为功能矿物材料在锂离子电池中的应用。所在课题组研究项目包括:石墨层间距在中间尺度范围内的可控调节及可逆储钠性能研究、炭包覆石墨嵌入化合物的反应及可逆储锂性能研究;微孔离子溶剂化膜减薄机制及煤基炭电容性能研究;锂离子电池高性能石墨负极材料产品开发。

杨绍斌,辽宁工程技术大学材料学院院长,教授,博士研究生导师,1986年毕业于大连理工大学化学工程专业。现任中国金属学会材料科学分会理事,中国硅酸盐学会矿物材料分会理事。长期从事新能源材料、新型炭材料和先进矿物材料等领域的研究工作。先后主持和参与国家自然科学基金重点项目、国家自然科学基金、教育部博士点基金和省部级科研基金及其它项目等17项。发表学术论文130余篇,其中SCI和EI等检索论文40余篇,发明专利授权22项。

Preparation and Lithium Storage Properties of Silicon Nanotubes Based on Halloysite
Mingyuan ZHAO1 , Shaobin YANG2 , Wei DONG2, Lingmin ZHAO2, Ding SHEN2
Affiliations
  • 1.College of Mines, Liaoning Technical University, Fuxin 123000, Liaoning, China
  • 2.College of Materials Science and Engineering, Liaoning Technical University, Fuxin 123000, Liaoning, China
  • Corresponding Author:
    YANG Shaobin (1963-), male, Ph.D., Professor. E-mail:

    ZHAO Mingyuan (1994-), male, Doctorial candidate. E-mail:

出版时间: 2021-07-20 doi: 10.14062/j.issn.0454-5648.20200971
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以天然埃洛石为前驱体,通过低温铝热还原法和自模板法合成硅纳米管,研究了结构形貌在还原过程中的维持机理及储锂性能。结果表明:在低温铝热还原过程中,天然埃洛石中的铝氧八面体有助于维持埃洛石一维纳米管状结构进而得到硅纳米管。基于埃洛石的硅纳米管作为锂离子电池负极时具有优异的电化学性能,电极首次比放电容量高达3150.2(mA·h)/g,50次循环后显示出1786.0(mA·h)/g的高容量,为商业硅材料比容量的2倍以上,采用2 A/g大电流密度循环时,电极在200次循环后比容量能够保持1197.6 mA·h/g,远高于商业硅电极。

埃洛石  /  低温铝热还原  /  硅纳米管  /  锂离子电池  /  负极材料

Natural halloysite was used as precursor and template to prepare silicon nanotubes through low temperature aluminothermic reduction. The mechanism of variation in morphology during the reduction process and the lithium storage performance of the silicon nanotube were studied. It was found that the alumina octahedron in the natural halloysite was helpful to maintain the one-dimensional nanotube structure of the products during the low temperature aluminothermic reduction process, leading to the formation of silicon nanotubes. The silicon nanotubes had excellent electrochemical performance when used as anode of lithium-ion batteries, with an initial specific capacity of 3 150 mA·h/g. After 50 cycles, the specific capacity was still 1 977 mA·h/g, which is more than twice the value of commercial silicon anode. At a current density of 2 A/g, the capacity was maintained to be 913 mA·h/g after 200 cycles, which is also much higher than that of commercial silicon anode.

halloysite  /  low temperature aluminothermic reduction  /  silicon nanotube  /  lithium-ion battery  /  anode material
赵明远, 杨绍斌, 董伟, 赵玲敏, 沈丁. 基于埃洛石的硅纳米管制备及储锂性能. 硅酸盐学报, 2021 , 49 (7) : 1457 -1465 . DOI: 10.14062/j.issn.0454-5648.20200971
Mingyuan ZHAO, Shaobin YANG, Wei DONG, Lingmin ZHAO, Ding SHEN. Preparation and Lithium Storage Properties of Silicon Nanotubes Based on Halloysite[J]. Journal of the Chinese Ceramic Society, 2021 , 49 (7) : 1457 -1465 . DOI: 10.14062/j.issn.0454-5648.20200971
  • 国家自然科学基金(51774175; 51874167; 21808095)
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doi: 10.14062/j.issn.0454-5648.20200971
  • 接收时间:2020-12-28
  • 首发时间:2026-10-30
  • 出版时间:2021-07-20
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  • 收稿日期:2020-12-28
  • 修回日期:2021-04-06
基金
国家自然科学基金(51774175; 51874167; 21808095)
作者信息
    1.辽宁工程技术大学矿业学院,辽宁 阜新 123000
    2.辽宁工程技术大学材料科学与工程学院,辽宁 阜新 123000

通讯作者:

杨绍斌(1963—),男,教授。
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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