Article(id=1322942622997820097, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942592224211277, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200452, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1592755200000, receivedDateStr=2020-06-22, revisedDate=1594915200000, revisedDateStr=2020-07-17, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343700407, onlineDateStr=2026-10-30, pubDate=1621440000000, pubDateStr=2021-05-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343700407, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343700407, creator=13701087609, updateTime=1793343700407, updator=13701087609, issue=Issue{id=1322942592224211277, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='5', pageStart='807', pageEnd='1032', issueExtLink='null', onlineDate='null', pubDate='1621440000000', pubDateStr='2021-05-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343693071, creator='13701087609', updateTime=1793345545174, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322950360561754466, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942592224211277, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322950360565948771, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942592224211277, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=948, endPage=954, ext={EN=ArticleExt(id=1322942623207535298, articleId=1322942622997820097, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Mechanism and Properties of Glacial Acetic Acid Modified Steel Slag Powder via Dry Chemical Modification Method, columnId=1319726165087077079, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Article, runingTitle=null, highlight=null, articleAbstract=

To activate the early-age hydraulic reactivity of steel slag powder (SS), a method of using glacial acetic acid (GA)-anhydrous alcohol solution to modify the SS via dry chemical modification technology was proposed. The mineral composition, surface morphology and specific surface area of unmodified SS and GA modified SS were investigated by X-ray diffraction, Fourier transform infrared, scanning electron microscopy and Brunauer-Emmett-Teller specific surface area analysis. The hydraulic reactivity, compressive strength and soundness of SS pastes and SS blended cement pastes were investigated. The results show that calcite, portlandite and dicalcium ferrite in SS react with GA to produce calcium acetate after GA modification and some pores in the modified process, thus leading to GA modified SS with the greater specific surface area and rougher surface, compared to unmodified SS. In the hydration process, water is easier to absorb onto the surface of modified SS and enters the inner of SS particles along the pores, resulting in higher dissolution heat and reaction heat of active minerals in SS. The result show that, the higher 72-h cumulative hydration heat, the 3 d, 7 d and 90 d compressive strengths and better soundness of GA modified SS pastes and GA modified SS blended cement pastes are obtained, compared to the unmodified pastes.

, authors=Binbin HUO1, Baoliang LI1, 2, Chun CHEN1, Yamei ZHANG1, authorsList=Binbin HUO, Baoliang LI, Chun CHEN, Yamei ZHANG, authorCompany=null, correspAuthors=Yamei ZHANG, authorNote=

HUO Binbin (1991-), male, Doctoral candidate. E-mail:

, correspAuthorsNote=
ZHANG Yamei (1968-), female, Ph.D., Professor. E-mail:
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为提高钢渣的早期活性,提出了采用冰乙酸-酒精溶液对钢渣粉进行干法化学改性,并利用X射线衍射、Fourier变换红外光谱、扫描电子显微镜和BET比表面仪等表征了改性前后钢渣粉的矿物组成、表面形貌与比表面积,研究了改性前后钢渣粉与钢渣粉复合水泥的水化活性、强度发展和安定性。结果表明:经冰乙酸改性后,钢渣粉中的部分碳酸钙、氢氧化钙和铁酸二钙等与冰乙酸反应生成了乙酸钙,该反应同时伴有孔生成,孔的产生和乙酸钙的生成导致钢渣粉的表面粗糙度与比表面积增加。改性钢渣粉在水化时,水分子更易被较大比表面积的钢渣粉吸附,且水分子更易沿着孔深入到钢渣粉颗粒内部,不仅提高了钢渣粉的溶解热,也增加了钢渣粉中活性矿物的水化反应热,最终提高了钢渣粉和钢渣粉复合水泥的72 h水化放热量,3、7 d和90 d抗压强度并改善了其安定性。

, authors=霍彬彬1, 李保亮1, 2, 陈春1, 张亚梅1, authorsList=霍彬彬, 李保亮, 陈春, 张亚梅, authorCompany=null, correspAuthors=张亚梅, authorNote=

霍彬彬(1991—),男,博士研究生。

, correspAuthorsNote=
张亚梅(1968—),女,博士,教授。
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冰乙酸干法化学改性钢渣粉机理及其性能
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霍彬彬 1 , 李保亮 1, 2 , 陈春 1 , 张亚梅 1
硅酸盐学报 | 研究论文 2021,49(5): 948-954
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硅酸盐学报 |研究论文 2021 , 49 (5) : 948 -954
冰乙酸干法化学改性钢渣粉机理及其性能
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霍彬彬1 , 李保亮1, 2, 陈春1, 张亚梅1
作者信息
  • 1.东南大学材料科学与工程学院,江苏省土木工程材料重点实验室,南京 211189
  • 2.淮阴工学院建筑工程学院,江苏 淮安 223001
通讯作者:
张亚梅(1968—),女,博士,教授。
作者简介:

霍彬彬(1991—),男,博士研究生。

Mechanism and Properties of Glacial Acetic Acid Modified Steel Slag Powder via Dry Chemical Modification Method
Binbin HUO1 , Baoliang LI1, 2, Chun CHEN1, Yamei ZHANG1
Affiliations
  • 1.Jiangsu Key Laboratory of Construction Materials, School of Materials Science and Engineering, Southeast University, Nanjing, China, 211189
  • 2.Faculty of Architecture and Civil Engineering, Huaiyin Institute of Technology, Huaian 223001, Jiangsu, China
  • Corresponding Author:
    ZHANG Yamei (1968-), female, Ph.D., Professor. E-mail:

    HUO Binbin (1991-), male, Doctoral candidate. E-mail:

出版时间: 2021-05-20 doi: 10.14062/j.issn.0454-5648.20200452
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为提高钢渣的早期活性,提出了采用冰乙酸-酒精溶液对钢渣粉进行干法化学改性,并利用X射线衍射、Fourier变换红外光谱、扫描电子显微镜和BET比表面仪等表征了改性前后钢渣粉的矿物组成、表面形貌与比表面积,研究了改性前后钢渣粉与钢渣粉复合水泥的水化活性、强度发展和安定性。结果表明:经冰乙酸改性后,钢渣粉中的部分碳酸钙、氢氧化钙和铁酸二钙等与冰乙酸反应生成了乙酸钙,该反应同时伴有孔生成,孔的产生和乙酸钙的生成导致钢渣粉的表面粗糙度与比表面积增加。改性钢渣粉在水化时,水分子更易被较大比表面积的钢渣粉吸附,且水分子更易沿着孔深入到钢渣粉颗粒内部,不仅提高了钢渣粉的溶解热,也增加了钢渣粉中活性矿物的水化反应热,最终提高了钢渣粉和钢渣粉复合水泥的72 h水化放热量,3、7 d和90 d抗压强度并改善了其安定性。

钢渣粉  /  冰乙酸  /  干法化学改性  /  水化  /  矿物组成  /  表面形貌

To activate the early-age hydraulic reactivity of steel slag powder (SS), a method of using glacial acetic acid (GA)-anhydrous alcohol solution to modify the SS via dry chemical modification technology was proposed. The mineral composition, surface morphology and specific surface area of unmodified SS and GA modified SS were investigated by X-ray diffraction, Fourier transform infrared, scanning electron microscopy and Brunauer-Emmett-Teller specific surface area analysis. The hydraulic reactivity, compressive strength and soundness of SS pastes and SS blended cement pastes were investigated. The results show that calcite, portlandite and dicalcium ferrite in SS react with GA to produce calcium acetate after GA modification and some pores in the modified process, thus leading to GA modified SS with the greater specific surface area and rougher surface, compared to unmodified SS. In the hydration process, water is easier to absorb onto the surface of modified SS and enters the inner of SS particles along the pores, resulting in higher dissolution heat and reaction heat of active minerals in SS. The result show that, the higher 72-h cumulative hydration heat, the 3 d, 7 d and 90 d compressive strengths and better soundness of GA modified SS pastes and GA modified SS blended cement pastes are obtained, compared to the unmodified pastes.

steel slag powder  /  glacial acetic acid  /  dry chemical modification  /  hydration  /  mineral composition  /  surface morphology
霍彬彬, 李保亮, 陈春, 张亚梅. 冰乙酸干法化学改性钢渣粉机理及其性能. 硅酸盐学报, 2021 , 49 (5) : 948 -954 . DOI: 10.14062/j.issn.0454-5648.20200452
Binbin HUO, Baoliang LI, Chun CHEN, Yamei ZHANG. Mechanism and Properties of Glacial Acetic Acid Modified Steel Slag Powder via Dry Chemical Modification Method[J]. Journal of the Chinese Ceramic Society, 2021 , 49 (5) : 948 -954 . DOI: 10.14062/j.issn.0454-5648.20200452
  • 国家自然科学基金面上项目(51778132; 51972057)
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2021年第49卷第5期
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doi: 10.14062/j.issn.0454-5648.20200452
  • 接收时间:2020-06-22
  • 首发时间:2026-10-30
  • 出版时间:2021-05-20
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  • 收稿日期:2020-06-22
  • 修回日期:2020-07-17
基金
国家自然科学基金面上项目(51778132; 51972057)
作者信息
    1.东南大学材料科学与工程学院,江苏省土木工程材料重点实验室,南京 211189
    2.淮阴工学院建筑工程学院,江苏 淮安 223001

通讯作者:

张亚梅(1968—),女,博士,教授。
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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