Article(id=1322942577678364874, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942545734546372, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200497, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1593964800000, receivedDateStr=2020-07-06, revisedDate=1595692800000, revisedDateStr=2020-07-26, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343689602, onlineDateStr=2026-10-30, pubDate=1618848000000, pubDateStr=2021-04-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343689602, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343689602, creator=13701087609, updateTime=1793343689602, updator=13701087609, issue=Issue{id=1322942545734546372, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='4', pageStart='605', pageEnd='806', issueExtLink='null', onlineDate='null', pubDate='1618848000000', pubDateStr='2021-04-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343681986, creator='13701087609', updateTime=1793345524324, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322950273110508350, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942545734546372, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322950273110508351, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942545734546372, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=769, endPage=776, ext={EN=ArticleExt(id=1322942577833554123, articleId=1322942577678364874, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Synthesis and Luminescent Property of Rare Earth Complexes Constructed by Isophthalic Acid and Acetylacetone, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

Four ternary complexes [Ln₂(PIA)₂(acac)₂] (Ln=Sm (1), Eu (2), Tb (3), Dy (4)) were synthesized with isophthalic acid (H₂PIA, C₈H₆O₄), acetylacetone(Hacac, C₅H₈O₂) and Ln(NO₃)₃·nH₂O in ethanol solution. These complexes were characterized by elemental analysis, infrared (IR) spectra, and thermogravimetric analysis (TG). Their possible structures were proposed. In order to compare the luminescent properties between ternary complexes and corresponding binary complexes, the binary complexes [Ln₂(PIA)₃(H₂O)₄] and Ln(acac)₃(H₂O) (Ln=Sm, Eu, Tb, Dy) were also prepared. The fluorescent spectra of the ternary and binary complexes were determined at room temperature. The results show that all complexes displayed the characteristic emissions of rare earth center ions. The luminescent intensities of the ternary complexes (except the dysprosium complex) were stronger than that of the binary complexes, indicating that the synergistic sensitization effect had occurred for the center ions from the double ligands. These experimental results can be explained by the energy matching of the lowest triplet energy level T₁ of the two ligands (calculated from Gaussian theory) and the lowest excited state energy level of the central metal ions.

, authors=Ya LU¹, Weiji HU², Gangfeng LIANG¹, Guoliang ZHAO^{1, 2}, authorsList=Ya LU, Weiji HU, Gangfeng LIANG, Guoliang ZHAO, authorCompany=null, correspAuthors=Guoliang ZHAO, authorNote=, correspAuthorsNote=, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322942578064240844, articleId=1322942577678364874, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=稀土-间苯二甲酸-乙酰丙酮三元配合物的合成及发光性能, columnId=0, journalTitle=硅酸盐学报, columnName=, runingTitle=null, highlight=null, articleAbstract=

在乙醇体系中，由双配体间苯二甲酸（H₂PIA）和乙酰丙酮（Hacac）与稀土硝酸盐反应合成了相应的4种稀土三元配合物[Ln₂（PIA）₂（acac）₂]（Ln = Sm（1），Eu（2），Tb（3），Dy（4）），用元素分析、红外光谱、热重分析进行表征，并推断了其可能的结构。为便于比较三元配合物的发光性能，同时也制备了相应的稀土间苯二甲酸[Ln₂（PIA）₃（H₂O）₄]和稀土乙酰丙酮二元配合物[Ln（acac）₃（H₂O）]。室温下，测定了三元和二元配合物的荧光光谱，结果表明，所有配合物均显示稀土中心离子特有的发射，三元配合物的发光强度好于二元配合物（除了镝配合物），说明双配体对中心离子有协同敏化作用，其实验结果用配体最低三重态能级T₁（来自Gauss理论计算）与中心金属离子最低激发态能级的匹配情况予以解释。

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LU Ya (1997-), female, Master candidate. E-mail: luya9966@163.com

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LU Ya (1997-), female, Master candidate. E-mail: luya9966@163.com

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鲁雅（1997—），女，硕士研究生。

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鲁雅（1997—），女，硕士研究生。

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