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Article(id=1322942392638256020, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942385474384734, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200580, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1596556800000, receivedDateStr=2020-08-05, revisedDate=1600272000000, revisedDateStr=2020-09-17, acceptedDate=null, acceptedDateStr=null, onlineDate=1793343645485, onlineDateStr=2026-10-30, pubDate=1611072000000, pubDateStr=2021-01-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793343645485, onlineIssueDateStr=2026-10-30, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793343645485, creator=13701087609, updateTime=1793343645485, updator=13701087609, issue=Issue{id=1322942385474384734, tenantId=1146029695717560320, journalId=1263187385517883426, year='2021', volume='49', issue='1', pageStart='1', pageEnd='210', issueExtLink='null', onlineDate='null', pubDate='1611072000000', pubDateStr='2021-01-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793343643777, creator='13701087609', updateTime=1793345438198, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322949911880282449, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942385474384734, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322949911880282450, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322942385474384734, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=26, endPage=33, ext={EN=ArticleExt(id=1322942392885719957, articleId=1322942392638256020, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Performance of Solid Oxide Fuel Cell and Stack for Stable Operation, columnId=1322942386086753121, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Issue on SOFC, runingTitle=null, highlight=null, articleAbstract=

Effects of temperature, fuel composition and flow rate on the performance of an anode-supported cell and a stack were studied. The results show that in the complex impedance spectrum, the activation energy corresponding to high frequency arc is the highest; that of the Ohmic loss is lower, which indicates that not only the ionic conductivity resistance, but also the surface resistance and possible contact resistance are included. With dry hydrogen as fuel, the results show that the activation polarization near the open circuit voltage is large and the activation energy is very small, which indicates that the rate control step of the activation polarization is not a charge transfer process, but a surface diffusion process. For simulated reforming gas fuels, the results show the activation polarization is small, but the open circuit voltage is lower, so that the performance is worse than that of hydrogen fuel. With the increase of the stack current, the temperature of the fuel exhaust gas increases, showing obvious thermal effect.

, authors=Shaomin LIU1, Zhanfeng DENG1, Jie SONG1, Danxi LIANG1, Wei KANG1, Xiaotong SUN1, Ting LUO2, Xiaochun YANG3, Shaorong WANG3, authorsList=Shaomin LIU, Zhanfeng DENG, Jie SONG, Danxi LIANG, Wei KANG, Xiaotong SUN, Ting LUO, Xiaochun YANG, Shaorong WANG, authorCompany=null, correspAuthors=Shaorong WANG, authorNote=

LIU Shaomin (1986-), male, Ph.D. E-mail:

, correspAuthorsNote=
WANG Shaorong (1964-), male, Ph.D., Professor. E-mail:
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以大面积电池和千瓦级电堆为对象，研究了温度、燃料成分、流量等对阳极支撑型电堆性能的影响。结果表明：温度的影响最大，复数阻抗谱中高频弧对应的活化能最高；欧姆阻抗的活化能较低，表明其不全是离子电导的电阻，还包括双极板的表面电阻和可能的接触电阻。利用干氢气燃料测试时，在开路电压附近表现出较大的活化极化，且其活化能很小，表明该活化极化的速率控制步骤并非是电荷转移过程，而是对应某种表面扩散过程。模拟重整气燃料测试过程中活化极化不明显，但开路电压较低，性能比氢气燃料差。随着电堆工作电流的增加，燃料尾气的温度增加，表现出明显的热效应。

, authors=刘少名1, 邓占锋1, 宋洁1, 梁丹曦1, 康伟1, 孙晓彤1, 骆婷2, 杨小春3, 王绍荣3, authorsList=刘少名, 邓占锋, 宋洁, 梁丹曦, 康伟, 孙晓彤, 骆婷, 杨小春, 王绍荣, authorCompany=null, correspAuthors=王绍荣, authorNote=

刘少名（1986—），男，博士。

, correspAuthorsNote=
王绍荣（1964—），男，博士，教授。
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LIU Shaomin (1986-), male, Ph.D. E-mail:

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刘少名（1986—），男，博士。

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固体氧化物燃料电池堆的稳定工况特性
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刘少名 1 , 邓占锋 1 , 宋洁 1 , 梁丹曦 1 , 康伟 1 , 孙晓彤 1 , 骆婷 2 , 杨小春 3 , 王绍荣 3
硅酸盐学报 | SOFC专题 2021,49(1): 26-33
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硅酸盐学报 |SOFC专题 2021 , 49 (1) : 26 -33
固体氧化物燃料电池堆的稳定工况特性
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刘少名1 , 邓占锋1, 宋洁1, 梁丹曦1, 康伟1, 孙晓彤1, 骆婷2, 杨小春3, 王绍荣3
作者信息
  • 1.先进输电技术国家重点实验室，全球能源互联网研究院有限公司，北京 102209
  • 2.中国科学院上海硅酸盐研究所，上海 201800
  • 3.中国矿业大学化工学院，江苏 徐州 221116
通讯作者:
王绍荣（1964—），男，博士，教授。
作者简介:

刘少名（1986—），男，博士。

Performance of Solid Oxide Fuel Cell and Stack for Stable Operation
Shaomin LIU1 , Zhanfeng DENG1, Jie SONG1, Danxi LIANG1, Wei KANG1, Xiaotong SUN1, Ting LUO2, Xiaochun YANG3, Shaorong WANG3
Affiliations
  • 1.State Key Laboratory of Advanced Transmission Technology (Global Energy Interconnection Research Institute Co., Ltd), Beijing 102209, China
  • 2.Shanghai Institute of Ceramics, Chinese Academy of Sciences, Shanghai 201800, China
  • 3.School of Chemical Engineering and Technology, China University of Mining and Technology, Xuzhou 221116, Jiangsu, China
    • Corresponding Author:
    WANG Shaorong (1964-), male, Ph.D., Professor. E-mail:

    LIU Shaomin (1986-), male, Ph.D. E-mail:

出版时间: 2021-01-20 doi: 10.14062/j.issn.0454-5648.20200580
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以大面积电池和千瓦级电堆为对象，研究了温度、燃料成分、流量等对阳极支撑型电堆性能的影响。结果表明：温度的影响最大，复数阻抗谱中高频弧对应的活化能最高；欧姆阻抗的活化能较低，表明其不全是离子电导的电阻，还包括双极板的表面电阻和可能的接触电阻。利用干氢气燃料测试时，在开路电压附近表现出较大的活化极化，且其活化能很小，表明该活化极化的速率控制步骤并非是电荷转移过程，而是对应某种表面扩散过程。模拟重整气燃料测试过程中活化极化不明显，但开路电压较低，性能比氢气燃料差。随着电堆工作电流的增加，燃料尾气的温度增加，表现出明显的热效应。

固体氧化物燃料电池  /  电堆  /  变工况  /  碳基燃料

Effects of temperature, fuel composition and flow rate on the performance of an anode-supported cell and a stack were studied. The results show that in the complex impedance spectrum, the activation energy corresponding to high frequency arc is the highest; that of the Ohmic loss is lower, which indicates that not only the ionic conductivity resistance, but also the surface resistance and possible contact resistance are included. With dry hydrogen as fuel, the results show that the activation polarization near the open circuit voltage is large and the activation energy is very small, which indicates that the rate control step of the activation polarization is not a charge transfer process, but a surface diffusion process. For simulated reforming gas fuels, the results show the activation polarization is small, but the open circuit voltage is lower, so that the performance is worse than that of hydrogen fuel. With the increase of the stack current, the temperature of the fuel exhaust gas increases, showing obvious thermal effect.

solid oxide fuel cell  /  stack  /  various operating condition  /  carbon containing fuel
刘少名, 邓占锋, 宋洁, 梁丹曦, 康伟, 孙晓彤, 骆婷, 杨小春, 王绍荣. 固体氧化物燃料电池堆的稳定工况特性. 硅酸盐学报, 2021 , 49 (1) : 26 -33 . DOI: 10.14062/j.issn.0454-5648.20200580
Shaomin LIU, Zhanfeng DENG, Jie SONG, Danxi LIANG, Wei KANG, Xiaotong SUN, Ting LUO, Xiaochun YANG, Shaorong WANG. Performance of Solid Oxide Fuel Cell and Stack for Stable Operation[J]. Journal of the Chinese Ceramic Society, 2021 , 49 (1) : 26 -33 . DOI: 10.14062/j.issn.0454-5648.20200580
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  • 国家电网有限公司科技资助项目-固体氧化物燃料电池发电系统关键技术研究(SGRIDLKJ[2017]720)
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2021年第49卷第1期
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doi: 10.14062/j.issn.0454-5648.20200580
  • 接收时间：2020-08-05
  • 首发时间：2026-10-30
  • 出版时间：2021-01-20
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  • 收稿日期：2020-08-05
  • 修回日期：2020-09-17
基金
国家电网有限公司科技资助项目-固体氧化物燃料电池发电系统关键技术研究(SGRIDLKJ[2017]720)
作者信息
    1.先进输电技术国家重点实验室，全球能源互联网研究院有限公司，北京 102209
    2.中国科学院上海硅酸盐研究所，上海 201800
    3.中国矿业大学化工学院，江苏 徐州 221116

通讯作者:

王绍荣（1964—），男，博士，教授。
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https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20200580
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鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
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红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
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