Article(id=1322636262524175171, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322636234858550134, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200087, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1582128000000, receivedDateStr=2020-02-20, revisedDate=1586793600000, revisedDateStr=2020-04-14, acceptedDate=null, acceptedDateStr=null, onlineDate=1793270658378, onlineDateStr=2026-10-29, pubDate=1603123200000, pubDateStr=2020-10-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793270658378, onlineIssueDateStr=2026-10-29, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793270658378, creator=13701087609, updateTime=1793270658378, updator=13701087609, issue=Issue{id=1322636234858550134, tenantId=1146029695717560320, journalId=1263187385517883426, year='2020', volume='48', issue='10', pageStart='1505', pageEnd='1688', issueExtLink='null', onlineDate='null', pubDate='1603123200000', pubDateStr='2020-10-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793270651783, creator='13701087609', updateTime=1793277146795, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322663476976267430, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322636234858550134, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322663476976267431, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322636234858550134, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1552, endPage=1558, ext={EN=ArticleExt(id=1322636262704530244, articleId=1322636262524175171, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Preparation of Solid Acid Materials from Kaolinite and Its Effect on Flame-Retardancy of Polypropylene Composite, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

Solid acid materials (A-K) were prepared via calcination of kaolinite (K) and successive acid treatment. The structure of products was characterized by X-ray diffraction (XRD) and scanning electronic microscopy (SEM). A-K was then introduced into polypropylene (PP) composites to further enhance the flame retardancy. The flammability and mechanical properties were evaluated by limiting oxygen index, vertical burning test, cone calorimetry and universal test. The results show that the peak heat release rate for PP composite with a loading A-K (0.5%-3.0%, in mass fraction] can reduce from 1 474 kW/m2 of neat PP to 177 kW/m2.

, authors=Wufei TANG1, Xiaoyu GU2, Sheng ZHANG2, authorsList=Wufei TANG, Xiaoyu GU, Sheng ZHANG, authorCompany=null, correspAuthors=null, authorNote=

TANG Wufei (1987-), male, Ph.D., Senior Engineer. E-mail:

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通过高温煅烧和酸反应等方法处理高岭石(K),制备高岭石基固体酸材料(A-K),并通过X射线衍射仪(XRD)和扫描电子显微镜(SEM)对其进行表征和分析。然后通过熔融挤出共混,将A-K添加到聚丙烯(PP)复合材料中,改善其阻燃性能。利用极限氧指数仪、水平垂直燃烧仪、锥型量热仪和万能试验机分别测试材料阻燃性能和力学性能。结果表明:少量A-K[(0.5%~3.0%(质量分数)]可明显改善PP复合材料阻燃性能,PP复合材料的最大热释放速率从纯PP的1 474 kW/m2大幅下降至177 kW/m2。

, authors=唐武飞1, 谷晓昱2, 张胜2, authorsList=唐武飞, 谷晓昱, 张胜, authorCompany=null, correspAuthors=null, authorNote=

唐武飞(1987—),男,博士,高级工程师。

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TANG Wufei (1987-), male, Ph.D., Senior Engineer. E-mail:

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高岭石基固体酸材料制备及其对聚丙烯复合材料阻燃性能影响
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唐武飞 1 , 谷晓昱 2 , 张胜 2
硅酸盐学报 | 2020,48(10): 1552-1558
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硅酸盐学报 | 2020 , 48 (10) : 1552 -1558
高岭石基固体酸材料制备及其对聚丙烯复合材料阻燃性能影响
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唐武飞1 , 谷晓昱2, 张胜2
作者信息
  • 1.湖南科技学院化学与生物工程学院,湖南 永州 425199
  • 2.北京化工大学材料科学与工程学院,北京 100029
作者简介:

唐武飞(1987—),男,博士,高级工程师。

Preparation of Solid Acid Materials from Kaolinite and Its Effect on Flame-Retardancy of Polypropylene Composite
Wufei TANG1 , Xiaoyu GU2, Sheng ZHANG2
Affiliations
  • 1.College of Chemistry and Bioengineering, Hunan University of Science and Engineering, Yongzhou 425199, Hunan, China
  • 2.College of Materials Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China
  • TANG Wufei (1987-), male, Ph.D., Senior Engineer. E-mail:

出版时间: 2020-10-20 doi: 10.14062/j.issn.0454-5648.20200087
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通过高温煅烧和酸反应等方法处理高岭石(K),制备高岭石基固体酸材料(A-K),并通过X射线衍射仪(XRD)和扫描电子显微镜(SEM)对其进行表征和分析。然后通过熔融挤出共混,将A-K添加到聚丙烯(PP)复合材料中,改善其阻燃性能。利用极限氧指数仪、水平垂直燃烧仪、锥型量热仪和万能试验机分别测试材料阻燃性能和力学性能。结果表明:少量A-K[(0.5%~3.0%(质量分数)]可明显改善PP复合材料阻燃性能,PP复合材料的最大热释放速率从纯PP的1 474 kW/m2大幅下降至177 kW/m2。

高岭石  /  固体酸  /  聚丙烯  /  阻燃

Solid acid materials (A-K) were prepared via calcination of kaolinite (K) and successive acid treatment. The structure of products was characterized by X-ray diffraction (XRD) and scanning electronic microscopy (SEM). A-K was then introduced into polypropylene (PP) composites to further enhance the flame retardancy. The flammability and mechanical properties were evaluated by limiting oxygen index, vertical burning test, cone calorimetry and universal test. The results show that the peak heat release rate for PP composite with a loading A-K (0.5%-3.0%, in mass fraction] can reduce from 1 474 kW/m2 of neat PP to 177 kW/m2.

kaolinite  /  solid acid  /  polypropylene  /  flame retardancy
唐武飞, 谷晓昱, 张胜. 高岭石基固体酸材料制备及其对聚丙烯复合材料阻燃性能影响. 硅酸盐学报, 2020 , 48 (10) : 1552 -1558 . DOI: 10.14062/j.issn.0454-5648.20200087
Wufei TANG, Xiaoyu GU, Sheng ZHANG. Preparation of Solid Acid Materials from Kaolinite and Its Effect on Flame-Retardancy of Polypropylene Composite[J]. Journal of the Chinese Ceramic Society, 2020 , 48 (10) : 1552 -1558 . DOI: 10.14062/j.issn.0454-5648.20200087
  • 国家自然科学基金(51873005)
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doi: 10.14062/j.issn.0454-5648.20200087
  • 接收时间:2020-02-20
  • 首发时间:2026-10-29
  • 出版时间:2020-10-20
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  • 收稿日期:2020-02-20
  • 修回日期:2020-04-14
基金
国家自然科学基金(51873005)
作者信息
    1.湖南科技学院化学与生物工程学院,湖南 永州 425199
    2.北京化工大学材料科学与工程学院,北京 100029
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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