Article(id=1322636257365181200, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322636234858550134, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200290, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1587744000000, receivedDateStr=2020-04-25, revisedDate=1591632000000, revisedDateStr=2020-06-09, acceptedDate=null, acceptedDateStr=null, onlineDate=1793270657148, onlineDateStr=2026-10-29, pubDate=1603123200000, pubDateStr=2020-10-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793270657148, onlineIssueDateStr=2026-10-29, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793270657148, creator=13701087609, updateTime=1793270657148, updator=13701087609, issue=Issue{id=1322636234858550134, tenantId=1146029695717560320, journalId=1263187385517883426, year='2020', volume='48', issue='10', pageStart='1505', pageEnd='1688', issueExtLink='null', onlineDate='null', pubDate='1603123200000', pubDateStr='2020-10-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793270651783, creator='13701087609', updateTime=1793277146795, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322663476976267430, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322636234858550134, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322663476976267431, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322636234858550134, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1613, endPage=1621, ext={EN=ArticleExt(id=1322636257549730577, articleId=1322636257365181200, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Fabrication of Porous Fuel Cell Electrode Layers via Inkjet Printing, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

Solid oxide fuel cell (SOFC) cathode thin layers were fabricated via inkjet printing with a novel water-based lanthanum cobalt strontium ferrite (LSCF) ceramic ink. The prepared inks and thin cathode layers after printing, drying and sintering were characterized by particle size and zeta potential measurements, surface tensiometry, rheometry, X-ray diffraction and scanning electron microscopy. The results show that a fine particle size is obtained by wet grinding, and the average particle size is reduced from a few micronmeters to approximately 100 nm. Water-based LSCF inks with superior rheological properties and dispersion stability were prepared with the nanoparticles. The problem of satellite droplets during printing and uneven distribution of the jetted droplets on the substrate were effectively solved by optimizing the voltage waveforms of printing parameters, thus greatly improving the quality of droplet injection and distribution. Thin cathode layers with a good surface morphology and a porous microstructure suitable for SOFC applications could be prepared by reducing the number of printing layers and extending the printing time interval between layers.

, authors=Piao QU, Jing OUYANG, Zhiyuan GONG, Changyong LIU, Changshi LAO, Zhangwei CHEN, authorsList=Piao QU, Jing OUYANG, Zhiyuan GONG, Changyong LIU, Changshi LAO, Zhangwei CHEN, authorCompany=null, correspAuthors=Zhangwei CHEN, authorNote=

QU Piao (1998-), male, Master candidate. E-mail:

, correspAuthorsNote=
CHEN Zhangwei (1985-), male, Ph.D., Professor. E-mail:
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通过研发水基镧锶钴铁氧体(LSCF)陶瓷墨水,制造喷墨打印固体氧化物燃料电池(SOFC)阴极薄层,通过粒径电位仪、流变仪、X射线衍射仪、扫描电子显微镜等对墨水和打印干燥烧结制得的薄层进行表征。结果表明:通过研磨细化,粉体平均粒径由数微米减少为100 nm;以此配制了具有优异分散稳定性的水基LSCF墨水;通过优化打印电压波形有效解决了卫星液滴及铺展不均问题;通过减少打印层数和延长层间打印间隔时间制备了表面形貌较好的多孔阴极薄层,可满足SOFC的使用需求。

, authors=屈飘, 欧阳竟, 龚志远, 刘长勇, 劳长石, 陈张伟, authorsList=屈飘, 欧阳竟, 龚志远, 刘长勇, 劳长石, 陈张伟, authorCompany=null, correspAuthors=陈张伟, authorNote=

屈飘(1998—),男,硕士研究生。

, correspAuthorsNote=
陈张伟(1985—),男,博士,教授。
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燃料电池多孔陶瓷电极薄层的喷墨打印制造
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屈飘 , 欧阳竟 , 龚志远 , 刘长勇 , 劳长石 , 陈张伟
硅酸盐学报 | 2020,48(10): 1613-1621
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硅酸盐学报 | 2020 , 48 (10) : 1613 -1621
燃料电池多孔陶瓷电极薄层的喷墨打印制造
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屈飘 , 欧阳竟, 龚志远, 刘长勇, 劳长石, 陈张伟
作者信息
  • 深圳大学增材制造研究所,深圳 518060
通讯作者:
陈张伟(1985—),男,博士,教授。
作者简介:

屈飘(1998—),男,硕士研究生。

Fabrication of Porous Fuel Cell Electrode Layers via Inkjet Printing
Piao QU , Jing OUYANG, Zhiyuan GONG, Changyong LIU, Changshi LAO, Zhangwei CHEN
Affiliations
  • Shenzhen University, Additive Manufacturing Institute, Shenzhen 518060, China
  • Corresponding Author:
    CHEN Zhangwei (1985-), male, Ph.D., Professor. E-mail:

    QU Piao (1998-), male, Master candidate. E-mail:

出版时间: 2020-10-20 doi: 10.14062/j.issn.0454-5648.20200290
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通过研发水基镧锶钴铁氧体(LSCF)陶瓷墨水,制造喷墨打印固体氧化物燃料电池(SOFC)阴极薄层,通过粒径电位仪、流变仪、X射线衍射仪、扫描电子显微镜等对墨水和打印干燥烧结制得的薄层进行表征。结果表明:通过研磨细化,粉体平均粒径由数微米减少为100 nm;以此配制了具有优异分散稳定性的水基LSCF墨水;通过优化打印电压波形有效解决了卫星液滴及铺展不均问题;通过减少打印层数和延长层间打印间隔时间制备了表面形貌较好的多孔阴极薄层,可满足SOFC的使用需求。

固体氧化物燃料电池  /  陶瓷电极  /  喷墨打印  /  墨水  /  薄层  /  多孔微结构

Solid oxide fuel cell (SOFC) cathode thin layers were fabricated via inkjet printing with a novel water-based lanthanum cobalt strontium ferrite (LSCF) ceramic ink. The prepared inks and thin cathode layers after printing, drying and sintering were characterized by particle size and zeta potential measurements, surface tensiometry, rheometry, X-ray diffraction and scanning electron microscopy. The results show that a fine particle size is obtained by wet grinding, and the average particle size is reduced from a few micronmeters to approximately 100 nm. Water-based LSCF inks with superior rheological properties and dispersion stability were prepared with the nanoparticles. The problem of satellite droplets during printing and uneven distribution of the jetted droplets on the substrate were effectively solved by optimizing the voltage waveforms of printing parameters, thus greatly improving the quality of droplet injection and distribution. Thin cathode layers with a good surface morphology and a porous microstructure suitable for SOFC applications could be prepared by reducing the number of printing layers and extending the printing time interval between layers.

solid oxide fuel cell  /  ceramic electrode  /  inkjet printing  /  ink  /  thin layer  /  porous microstructure
屈飘, 欧阳竟, 龚志远, 刘长勇, 劳长石, 陈张伟. 燃料电池多孔陶瓷电极薄层的喷墨打印制造. 硅酸盐学报, 2020 , 48 (10) : 1613 -1621 . DOI: 10.14062/j.issn.0454-5648.20200290
Piao QU, Jing OUYANG, Zhiyuan GONG, Changyong LIU, Changshi LAO, Zhangwei CHEN. Fabrication of Porous Fuel Cell Electrode Layers via Inkjet Printing[J]. Journal of the Chinese Ceramic Society, 2020 , 48 (10) : 1613 -1621 . DOI: 10.14062/j.issn.0454-5648.20200290
  • 国家自然科学基金面上项目(51975384)
  • 广东省自然科学基金面上项目(2020A151501549)
  • 深圳市基础研究面上项目(JCYJ20190808144009478)
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2020年第48卷第10期
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doi: 10.14062/j.issn.0454-5648.20200290
  • 接收时间:2020-04-25
  • 首发时间:2026-10-29
  • 出版时间:2020-10-20
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  • 收稿日期:2020-04-25
  • 修回日期:2020-06-09
基金
国家自然科学基金面上项目(51975384)
广东省自然科学基金面上项目(2020A151501549)
深圳市基础研究面上项目(JCYJ20190808144009478)
作者信息
    深圳大学增材制造研究所,深圳 518060

通讯作者:

陈张伟(1985—),男,博士,教授。
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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