Article(id=1322636213199159834, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322636193100050547, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20190774, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1574956800000, receivedDateStr=2019-11-29, revisedDate=1578844800000, revisedDateStr=2020-01-13, acceptedDate=null, acceptedDateStr=null, onlineDate=1793270646618, onlineDateStr=2026-10-29, pubDate=1600531200000, pubDateStr=2020-09-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793270646618, onlineIssueDateStr=2026-10-29, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793270646618, creator=13701087609, updateTime=1793270646618, updator=13701087609, issue=Issue{id=1322636193100050547, tenantId=1146029695717560320, journalId=1263187385517883426, year='2020', volume='48', issue='9', pageStart='1353', pageEnd='1510', issueExtLink='null', onlineDate='null', pubDate='1594569600000', pubDateStr='2020-07-13', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793270641826, creator='13701087609', updateTime=1793270641826, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext=null, issueFiles=null, downloadFileDto=null}, startPage=1414, endPage=1423, ext={EN=ArticleExt(id=1322636213354349083, articleId=1322636213199159834, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Effects of Silica Sol and Thermal Complex Activation on Properties of Electrodes for All Vanadium Redox Flow Battery, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=
Graphite felt (GF) was modified with a silica sol via thermal treatment to improve its hydrophilicity and electrochemical activity. The surface morphology, microstructure, and electrochemical performance of the modified samples were investigated. The results show that GF electrodes after modification have a better hydrophilicity, a greater specific surface area and more oxygen functional groups. The amount of C—O on the GF surface as the catalytic active sites for vanadium redox couples is 4.18% when the amount of silica sol is 50% (mass fraction). The VRFB based on GF modified with 50% silica sol by thermal treatment has coulombic efficiency of 95.58%, voltage efficiency of 86.07% and energy efficiency, of 92.35% at a current density of 40 mA/cm2, which is increased by 10.93%, 9.16% and 3.22%, respectively, compared to the VRFB based on unmodified GF.
, authors=Na CHEN, Huan ZHANG, Xudong LUO, authorsList=Na CHEN, Huan ZHANG, Xudong LUO, authorCompany=null, correspAuthors=Huan ZHANG, authorNote=
, correspAuthorsNote=
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利用硅溶胶/热空气复合活化法改性石墨毡,并对其表面形貌、微观结构以及电化学性能进行了分析研究。结果表明:硅溶胶/热空气复合活化使石墨毡电极的亲液性增强、比表面积增大、氧官能团数量提升,由此组装的钒电池电化学性能显著提高;活化后石墨毡表面的C—O氧官能团是钒电池氧化还原反应的有效活性位点,当硅溶胶添加量为50%(质量分数)时,石墨毡表面的C—O氧官能团数量达到4.18%;当电流密度为40 mA/cm2时,以硅溶胶添加量50%的石墨毡为电极组装钒电池,其库仑效率达到95.58%,能量效率达到86.07%,电压效率达到92.35%,比未活化石墨毡为电极组装的钒电池分别高出10.93%、9.16%、3.22%。
, authors=陈娜, 张欢, 罗旭东, authorsList=陈娜, 张欢, 罗旭东, authorCompany=null, correspAuthors=张欢, authorNote=
, correspAuthorsNote=
张欢(1981—),女,博士,副教授。
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CHEN Na (1994-), female, Master candidate. E-mail: 794267205@qq.com
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CHEN Na (1994-), female, Master candidate. E-mail: 794267205@qq.com
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陈娜(1994—),女,硕士研究生。
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陈娜(1994—),女,硕士研究生。
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