Article(id=1322636181423108109, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322636152813768892, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20190773, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1575216000000, receivedDateStr=2019-12-02, revisedDate=1578326400000, revisedDateStr=2020-01-07, acceptedDate=null, acceptedDateStr=null, onlineDate=1793270639043, onlineDateStr=2026-10-29, pubDate=1597852800000, pubDateStr=2020-08-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793270639043, onlineIssueDateStr=2026-10-29, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793270639043, creator=13701087609, updateTime=1793270639043, updator=13701087609, issue=Issue{id=1322636152813768892, tenantId=1146029695717560320, journalId=1263187385517883426, year='2020', volume='48', issue='8', pageStart='1145', pageEnd='1352', issueExtLink='null', onlineDate='null', pubDate='1597852800000', pubDateStr='2020-08-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793270632222, creator='13701087609', updateTime=1793277122165, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322663373687337109, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322636152813768892, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322663373687337110, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322636152813768892, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1295, endPage=1301, ext={EN=ArticleExt(id=1322636181641211918, articleId=1322636181423108109, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Physicochemical Performance of Fluorine-Containing Sludge and Its Effect on Cement Properties and Environmental Safety, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

It is necessary to concern the safe utilization of the fluorine-containing sludge disposed in landfills due to its possible leaching toxicity. The effect of physicochemical performance of fluorine-containing sludge, used in cement kiln on the cement properties and environmental safety was investigated by X-ray fluorescence, X-ray diffraction, scanning electron microscopy, immersion extraction and leaching toxicity tests. The results show that the fluorine content of fluorine-containing is 15.3% with a small amount of heavy metal ions (e.g. Cr, Mn, Ni, Cu, Zn, etc.). Fluorite is the major mineral phase, and secondary mineral phases are sphalerite and nantokite. Fluorine in fluorine-containing sludge is mostly calcium fluoride, and its content (mass fraction) reaches approximately 30.0% in the sludge. In addition, the leaching toxicity of F and Cr is below the toxicity restriction. However, the leaching toxicity of Ni, Cu and Zn is above the toxicity restriction. Therefore, the fluorine-containing sludge is subordinate to a heavy metal solid hazardous waste. Also, the incorporation of fluorine-containing sludge assists the formation of alite, and improves slightly the compressive strength of cement mortars. Meanwhile, 2.0% (mass fraction) fluorine-containing sludge doped cement could not cause the secondary environment risk after curing age of 28 d.

, authors=Tingshu HE¹, Minhao WANG¹, Yongqi DA¹, Yun FENG², Zhen LI³, authorsList=Tingshu HE, Minhao WANG, Yongqi DA, Yun FENG, Zhen LI, authorCompany=null, correspAuthors=null, authorNote=, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322636181905453071, articleId=1322636181423108109, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=含氟污泥的理化性质及其对水泥性能和环境安全性的影响, columnId=1263922770220560512, journalTitle=硅酸盐学报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=

鉴于含氟污泥可能存在浸出毒性超标风险，因此其安全处置非常必要。本工作通过X射线荧光光谱仪、X射线衍射仪、扫描电子显微镜、浸提试验及毒性浸出试验，研究了该种污泥的理化性质，以及水泥窑协同处置含氟污泥对水泥性能和环境安全性的影响。结果表明：污泥中氟含量（质量分数）为15.3%，且有少量Cr、Mn、Ni、Cu、Zn等重金属离子，主要晶体为萤石及少量铜盐和闪锌矿，氟主要以氟化钙形式存在，在污泥中的含量约30.0%；污泥中F、Cr的毒性浸出不超标，但Ni、Cu、Zn毒性浸出超标，故其属于重金属固体危废。水泥窑协同处置含氟污泥可促进C₃S生成，略微提高水泥抗压强度，但对水泥性能影响不大，掺2.0%污泥的水泥在28 d养护后不会对环境产生二次危废风险。

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HE Tingshu (1965-), male, Ph.D., Professor. E-mail: hetingshu@xauat.edu.cn

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何廷树（1965—），男，博士，教授。

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