Article(id=1322622758387822963, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322622757339250965, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20200066, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1581264000000, receivedDateStr=2020-02-10, revisedDate=1582041600000, revisedDateStr=2020-02-19, acceptedDate=null, acceptedDateStr=null, onlineDate=1793267438741, onlineDateStr=2026-10-29, pubDate=1595174400000, pubDateStr=2020-07-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793267438741, onlineIssueDateStr=2026-10-29, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793267438741, creator=13701087609, updateTime=1793267438741, updator=13701087609, issue=Issue{id=1322622757339250965, tenantId=1146029695717560320, journalId=1263187385517883426, year='2020', volume='48', issue='7', pageStart='939', pageEnd='1144', issueExtLink='null', onlineDate='null', pubDate='1595174400000', pubDateStr='2020-07-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793267438492, creator='13701087609', updateTime=1793277091258, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322663244053992200, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322622757339250965, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322663244053992201, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322622757339250965, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=939, endPage=946, ext={EN=ArticleExt(id=1322622758803059060, articleId=1322622758387822963, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=A Composite Solid-state Polymer Electrolyte for Solid-state Sodium Batteries, columnId=1322622757976785174, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Issue on New-type Battery, runingTitle=null, highlight=null, articleAbstract=

An organic-inorganic composite polymer electrolyte (CPE) was constructed via introducing an active filler of Na-β''-Al₂O₃ into a solid-state polymer electrolyte (SPE) composed of poly(ethylene oxide) (PEO) and sodium bis(trifluoromethanesulfonyl)-imide (NaTFSI). The phase composition, ionic conductivity, Na⁺ transference number, and electrochemical stability were investigated. The electrochemical properties of SPE and CPE in Na|Na₃V₂(PO₄)₃@C solid-state sodium batteries were obtained. The results show that the CPE has a greater Na⁺ transference number of 0.71 than SPE (i.e., 0.19) and a higher Na⁺ conductivity of 8.19×10^-4 S/cm than SPE (i.e., 1.65×10^-4 S/cm) at 80 ℃. The CPE exhibits a superior cycling stability with capacity retentions of 93.9% after 100 cycles at 0.5 C and 74.0% after 500 cycles at 2.0 C in Na|CPE|Na₃V₂(PO₄)₃@C solid-state batteries.

, authors=Qiangqiang ZHANG^{1, 2}, Xing SU^{1, 2}, Yaxiang LU^{1, 2}, Yongsheng HU^{1, 2}, authorsList=Qiangqiang ZHANG, Xing SU, Yaxiang LU, Yongsheng HU, authorCompany=null, correspAuthors=Yaxiang LU, authorNote=, correspAuthorsNote=, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322622760665330038, articleId=1322622758387822963, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=基于复合固体聚合物电解质的固态钠电池, columnId=1322622760472392053, journalTitle=硅酸盐学报, columnName=新型电池专题, runingTitle=null, highlight=null, articleAbstract=

将钠离子导体Na-β''-Al₂O₃作为活性填料引入聚氧化乙烯（PEO）/双（三氟甲基磺酰）亚胺钠（NaTFSI）固体聚合物电解质（SPE）中，得到有机-无机复合固体聚合物电解质（CPE）。对SPE及CPE的相结构、相转变、离子电导率、离子迁移数及电化学稳定性等基础理化性质进行了表征分析，对两者在固态钠电池Na₃V₂（PO₄）₃@C|Na中的电化学性能进行了测试。结果表明：Na-β''-Al₂O₃的引入，有效提升了钠离子迁移数（SPE为0.19，CPE为0.71）和钠离子电导率（80 ℃时，SPE为1.65×10^-4 S/cm，CPE为8.19×10^-4 S/cm）。基于CPE的固态钠电池表现出更加优异的循环稳定性，0.5 C循环100周后容量保持率为93.9%，2.0 C循环500周后容量保持率为74.0%。

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