Article(id=1322612383663636846, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322612332010787465, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.2020.06.20190653, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1569340800000, receivedDateStr=2019-09-25, revisedDate=1571068800000, revisedDateStr=2019-10-15, acceptedDate=null, acceptedDateStr=null, onlineDate=1793264965214, onlineDateStr=2026-10-29, pubDate=1592582400000, pubDateStr=2020-06-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793264965214, onlineIssueDateStr=2026-10-29, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793264965214, creator=13701087609, updateTime=1793264965214, updator=13701087609, issue=Issue{id=1322612332010787465, tenantId=1146029695717560320, journalId=1263187385517883426, year='2020', volume='48', issue='6', pageStart='787', pageEnd='938', issueExtLink='null', onlineDate='null', pubDate='1592582400000', pubDateStr='2020-06-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793264952900, creator='13701087609', updateTime=1793277066146, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322663138810516224, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322612332010787465, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322663138810516225, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322612332010787465, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=855, endPage=862, ext={EN=ArticleExt(id=1322612383902712175, articleId=1322612383663636846, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Enhanced Relaxor Ferroelectrics and Energy Storage of BaTiO₃-based Ceramics Modified by Bi(Al_0.5Sc_0.5)O₃, columnId=1322612334275711626, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Paper, runingTitle=null, highlight=null, articleAbstract=

Lead-free single-phase perovskite BaTiO₃-Bi(Al_0.5Sc_0.5)O₃ ceramics as novel high performance BaTiO_3-based energy storage ceramics were synthesized by a solid-state reaction method. Effect of BAS content on the structure, dielectric properties, energy storage of (1-x) BT-xBAS ceramics was investigated. The (1-x)BT-xBAS solid solution transforms from tetragonal (x≤0.05) to cubic (x≥0.1), but is still based on the tetragonal. The T_m moves toward a low temperature range, and the dielectric peak broadens with the BAS content increases, exhibiting a dispersive dielectric behavior with respect to frequency. The long-range ferroelectric order of ceramics is destroyed by BAS. Also, the phase transition of BT-xBAS ceramics is from a typical ferroelectric phase to a relaxor phase. The phenomena both indicate that the BT-BAS ceramics could have the excellent characteristics of relaxor ferroelectrics. The 0.85BT-0.15BAS ceramics show a good temperature stability, and the diffusion coefficient γ is 1.97. There are an energy storage density of 0.684 J·cm^-3 and an energy efficiency of 95% in an electric field of about 105 kV/cm.

, authors=Xueyan XI, Huiling DU, Cuiying MA, Xinrui JING, Haiting WANG, authorsList=Xueyan XI, Huiling DU, Cuiying MA, Xinrui JING, Haiting WANG, authorCompany=null, correspAuthors=Huiling DU, authorNote=, correspAuthorsNote=, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322612384183730544, articleId=1322612383663636846, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=Bi（Al_0.5Sc_0.5）O₃增强BaTiO₃陶瓷弛豫铁电及储能性能, columnId=1263922770220560512, journalTitle=硅酸盐学报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=

设计并合成了一种无铅改性BaTiO₃基储能陶瓷，通过固相反应法制备了无铅单相钙钛矿BaTiO₃-Bi（Al_0.5Sc_0.5）O₃陶瓷，研究了掺杂不同含量BAS对陶瓷的结构、介电性能、铁电性能及储能特性的影响。结果表明：（1-x）BT-xBAS固溶体从四方相（x≤0.05）转变为部分立方相（x≥0.1），但仍以四方相为主且细晶化；随着其含量的增加，Curie温度（T_m）向低温方向移动并出现了介电峰宽化，表现出明显的介电色散行为；BAS的引入破坏了BT陶瓷铁电畴的长程有序，发生了铁电相到弛豫铁电相的相变；2种现象均表明BT-BAS陶瓷具有弛豫铁电体的优异特点。在所有样品中，0.85BT-0.15BAS陶瓷的介电温度稳定性最佳，弛豫因子γ为1.97；外加电场~ 105 kV/cm时，储能密度为0.684 J·cm^-3，储能效率为95.0%，陶瓷具有最佳储能特性。

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郗雪艳（1995—），女，硕士研究生。

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