Article(id=1322612376898224448, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322612332010787465, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.2020.06.20190605, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1567353600000, receivedDateStr=2019-09-02, revisedDate=1576166400000, revisedDateStr=2019-12-13, acceptedDate=null, acceptedDateStr=null, onlineDate=1793264963602, onlineDateStr=2026-10-29, pubDate=1592582400000, pubDateStr=2020-06-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793264963602, onlineIssueDateStr=2026-10-29, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793264963602, creator=13701087609, updateTime=1793264963602, updator=13701087609, issue=Issue{id=1322612332010787465, tenantId=1146029695717560320, journalId=1263187385517883426, year='2020', volume='48', issue='6', pageStart='787', pageEnd='938', issueExtLink='null', onlineDate='null', pubDate='1592582400000', pubDateStr='2020-06-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793264952900, creator='13701087609', updateTime=1793277066146, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322663138810516224, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322612332010787465, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322663138810516225, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322612332010787465, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=870, endPage=876, ext={EN=ArticleExt(id=1322612377103745345, articleId=1322612376898224448, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Effect of Glass Powder Content on Properties of Ceramizable Silicone Rubber, columnId=1322612334275711626, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Paper, runingTitle=null, highlight=null, articleAbstract=

Ceramizable silicone rubber was prepared via sintering at 1 000 ℃ with MVQ as a matrix, wollastonite as a ceramic filler, glass powder as a flux and fumed silica as a reinforcing agent. The effect of glass powder content on the electrical and mechanical properties of ceramizable silicone rubber was investigated, and the samples were characterized X-ray diffraction, thermogravimetric analysis and bending strength measurement. The results show that glass powder can weaken the electrical and mechanical properties of silicone rubber slightly, reduce the decomposition temperature of silicone rubber, and improve the bending strength of the ceramics. The analysis of the ceramics microstructure indicates that the density of the ceramics increases with increasing the glass powder content. Based on the results by X-ray diffraction, wollastonite disappears after ceramization, which reacts with glass powder to form a new crystal. The bending strength is 61.1 MPa when the glass powder content is 12 g.

, authors=Hongchuan TANG, Penghu LI, Guowen KUANG, Huaidong LIU, Haiyun JIN, Naikui GAO, authorsList=Hongchuan TANG, Penghu LI, Guowen KUANG, Huaidong LIU, Haiyun JIN, Naikui GAO, authorCompany=null, correspAuthors=Haiyun JIN, authorNote=

TANG Hongchuan (1994-), female, Master candidate. E-mail:

, correspAuthorsNote=
JIN Haiyun (1971-), male, Ph.D., Professor. E-mail:
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以甲基乙烯基硅橡胶为基体、硅灰石为成瓷填料、低熔点玻璃粉为助熔剂、气相法白炭黑为补强剂,制备了陶瓷化硅橡胶,并在1 000 ℃烧结成瓷,研究了玻璃粉含量对成瓷前硅橡胶的电学性能和力学性能的影响,通过热重分析研究了硅橡胶的分解过程,测量了成瓷后陶瓷体的弯曲强度,观察了陶瓷体断面的显微形貌,并通过X射线衍射分析了材料成瓷后的晶相变化。结果表明:玻璃粉会轻微降低硅橡胶的电学性能和力学性能,并显著降低硅橡胶的分解温度,同时提高陶瓷体的弯曲强度。陶瓷断面的显微形貌显示,随着玻璃粉含量的增加,陶瓷体的致密度不断上升。硅灰石在成瓷后完全消失,并与玻璃粉反应生成了新的晶体。当玻璃粉含量为12 g时,陶瓷体的弯曲强度为61.1 MPa。

, authors=唐红川, 李鹏虎, 匡国文, 刘怀东, 金海云, 高乃奎, authorsList=唐红川, 李鹏虎, 匡国文, 刘怀东, 金海云, 高乃奎, authorCompany=null, correspAuthors=金海云, authorNote=

唐红川(1994—),女,硕士研究生。

, correspAuthorsNote=
金海云(1971—),男,博士,教授。
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玻璃粉含量对陶瓷化硅橡胶性能的影响
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唐红川 , 李鹏虎 , 匡国文 , 刘怀东 , 金海云 , 高乃奎
硅酸盐学报 | 研究论文 2020,48(6): 870-876
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硅酸盐学报 |研究论文 2020 , 48 (6) : 870 -876
玻璃粉含量对陶瓷化硅橡胶性能的影响
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唐红川 , 李鹏虎, 匡国文, 刘怀东, 金海云 , 高乃奎
作者信息
  • 西安交通大学电力设备电气绝缘国家重点实验室,西安 710049
通讯作者:
金海云(1971—),男,博士,教授。
作者简介:

唐红川(1994—),女,硕士研究生。

Effect of Glass Powder Content on Properties of Ceramizable Silicone Rubber
Hongchuan TANG , Penghu LI, Guowen KUANG, Huaidong LIU, Haiyun JIN , Naikui GAO
Affiliations
  • State Key Laboratory of Electrical Insulation and Power Equipment, Xi'an Jiaotong University, Xi'an 710049, China
  • Corresponding Author:
    JIN Haiyun (1971-), male, Ph.D., Professor. E-mail:

    TANG Hongchuan (1994-), female, Master candidate. E-mail:

出版时间: 2020-06-20 doi: 10.14062/j.issn.0454-5648.2020.06.20190605
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以甲基乙烯基硅橡胶为基体、硅灰石为成瓷填料、低熔点玻璃粉为助熔剂、气相法白炭黑为补强剂,制备了陶瓷化硅橡胶,并在1 000 ℃烧结成瓷,研究了玻璃粉含量对成瓷前硅橡胶的电学性能和力学性能的影响,通过热重分析研究了硅橡胶的分解过程,测量了成瓷后陶瓷体的弯曲强度,观察了陶瓷体断面的显微形貌,并通过X射线衍射分析了材料成瓷后的晶相变化。结果表明:玻璃粉会轻微降低硅橡胶的电学性能和力学性能,并显著降低硅橡胶的分解温度,同时提高陶瓷体的弯曲强度。陶瓷断面的显微形貌显示,随着玻璃粉含量的增加,陶瓷体的致密度不断上升。硅灰石在成瓷后完全消失,并与玻璃粉反应生成了新的晶体。当玻璃粉含量为12 g时,陶瓷体的弯曲强度为61.1 MPa。

陶瓷化硅橡胶  /  低熔点玻璃粉  /  材料性能  /  显微结构  /  成瓷机理

Ceramizable silicone rubber was prepared via sintering at 1 000 ℃ with MVQ as a matrix, wollastonite as a ceramic filler, glass powder as a flux and fumed silica as a reinforcing agent. The effect of glass powder content on the electrical and mechanical properties of ceramizable silicone rubber was investigated, and the samples were characterized X-ray diffraction, thermogravimetric analysis and bending strength measurement. The results show that glass powder can weaken the electrical and mechanical properties of silicone rubber slightly, reduce the decomposition temperature of silicone rubber, and improve the bending strength of the ceramics. The analysis of the ceramics microstructure indicates that the density of the ceramics increases with increasing the glass powder content. Based on the results by X-ray diffraction, wollastonite disappears after ceramization, which reacts with glass powder to form a new crystal. The bending strength is 61.1 MPa when the glass powder content is 12 g.

ceramizable silicone rubber  /  low melting glass powder  /  properties  /  microstructure  /  ceramization mechanism
唐红川, 李鹏虎, 匡国文, 刘怀东, 金海云, 高乃奎. 玻璃粉含量对陶瓷化硅橡胶性能的影响. 硅酸盐学报, 2020 , 48 (6) : 870 -876 . DOI: 10.14062/j.issn.0454-5648.2020.06.20190605
Hongchuan TANG, Penghu LI, Guowen KUANG, Huaidong LIU, Haiyun JIN, Naikui GAO. Effect of Glass Powder Content on Properties of Ceramizable Silicone Rubber[J]. Journal of the Chinese Ceramic Society, 2020 , 48 (6) : 870 -876 . DOI: 10.14062/j.issn.0454-5648.2020.06.20190605

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doi: 10.14062/j.issn.0454-5648.2020.06.20190605
  • 接收时间:2019-09-02
  • 首发时间:2026-10-29
  • 出版时间:2020-06-20
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  • 收稿日期:2019-09-02
  • 修回日期:2019-12-13
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    西安交通大学电力设备电气绝缘国家重点实验室,西安 710049

通讯作者:

金海云(1971—),男,博士,教授。
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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