Article(id=1322612238351971004, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322612191723897081, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20190394, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1560182400000, receivedDateStr=2019-06-11, revisedDate=1565193600000, revisedDateStr=2019-08-08, acceptedDate=null, acceptedDateStr=null, onlineDate=1793264930569, onlineDateStr=2026-10-29, pubDate=1584633600000, pubDateStr=2020-03-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793264930569, onlineIssueDateStr=2026-10-29, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793264930569, creator=13701087609, updateTime=1793264930569, updator=13701087609, issue=Issue{id=1322612191723897081, tenantId=1146029695717560320, journalId=1263187385517883426, year='2020', volume='48', issue='3', pageStart='325', pageEnd='462', issueExtLink='null', onlineDate='null', pubDate='1584633600000', pubDateStr='2020-03-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793264919452, creator='13701087609', updateTime=1793277037156, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322663017125368549, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322612191723897081, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322663017125368550, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322612191723897081, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=447, endPage=454, ext={EN=ArticleExt(id=1322612238809150141, articleId=1322612238351971004, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Synthesis, Thermal Stability and Photoluminescence Properties of NaLaMgWO₆:Sm³⁺ Phosphors, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

A series of orange red-emitting NaLa_1-xSm_xMgWO₆ phosphors were synthesized by a conventional solid-state reaction method. The crystal structure, microstructure, luminescence properties and thermal stability were investigated. The results show that NaLa_1-xSm_xMgWO₆ crystals form in a monoclinic structure with a space group of C2/m. Under an excitation at 406 nm, the emission spectra of NaLa_1-xSm_xMgWO₆ phosphors exhibit a most intense red emission peak at 645 nm, corresponding to the ⁴G_5/2→⁶H_9/2 transition of Sm³⁺. The photoluminescence intensity of the sample firstly increases and then decreases with the increase of Sm³⁺ doping concentration. The optimal concentration of Sm³⁺ appears at x=0.05. The mechanism of energy transfer between Sm³⁺ is proved to be dipole-dipole interaction based on the analysis of the concentration quenching curve. In addition, the temperature quenching behavior was also investigated according to the Arrhenius equation, and the results reveal that the quenching process of ⁴G_5/2 can be ascribed to the crossover process, and the calculated activation energy is 0.326 eV.

, authors=Yu WANG, Xiaohui WANG, Guifang Li, authorsList=Yu WANG, Xiaohui WANG, Guifang Li, authorCompany=null, correspAuthors=Guifang Li, authorNote=, correspAuthorsNote=, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322612239144694462, articleId=1322612238351971004, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=NaLaMgWO₆：Sm³⁺荧光材料的制备及其热稳定性与发光性能, columnId=null, journalTitle=硅酸盐学报, columnName=, runingTitle=null, highlight=null, articleAbstract=

采用固相法合成了新型白光LED用橙红色NaLa_1-xSm_xMgWO₆荧光粉，并对样品的物相、形貌、发光性质及热稳定性进行了研究。结果表明：NaLaMgWO₆具有单斜晶系的复合钙钛矿结构。在406 nm激发下，NaLa_1-xSm_xMgWO₆荧光粉将发射以645 nm为主的发射峰，其对应于Sm³⁺的4G_5/2→⁶H_9/2跃迁。样品发光强度随Sm³⁺掺杂浓度的增大，先增大后减小，Sm³⁺的最佳掺杂量为x=0.05。通过对荧光粉的发光浓度淬灭曲线分析，可知Sm³⁺在NaLaMgWO₆基质中是通过电偶极-电偶极的多极矩相互作用的方式来实现能量传递。研究了不同温度下NaLa_1-xSm_xMgWO₆荧光粉的发光特性，通过Arrhenius激活能模型对其温度淬灭过程进行分析，证明Sm³⁺的⁴G_5/2能级温度淬灭机理为Crossover过程，并计算其热激活能ΔE约为0.326 eV。

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WANG Yu (1991-), male, Master candidate. E-mail: 691583199@qq.com

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WANG Yu (1991-), male, Master candidate. E-mail: 691583199@qq.com

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王雨（1991—），男，硕士研究生。

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王雨（1991—），男，硕士研究生。

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