Article(id=1322612225139913314, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322612191723897081, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20190313, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1557590400000, receivedDateStr=2019-05-12, revisedDate=1561478400000, revisedDateStr=2019-06-26, acceptedDate=null, acceptedDateStr=null, onlineDate=1793264927419, onlineDateStr=2026-10-29, pubDate=1584633600000, pubDateStr=2020-03-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793264927419, onlineIssueDateStr=2026-10-29, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793264927419, creator=13701087609, updateTime=1793264927419, updator=13701087609, issue=Issue{id=1322612191723897081, tenantId=1146029695717560320, journalId=1263187385517883426, year='2020', volume='48', issue='3', pageStart='325', pageEnd='462', issueExtLink='null', onlineDate='null', pubDate='1584633600000', pubDateStr='2020-03-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793264919452, creator='13701087609', updateTime=1793277037156, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322663017125368549, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322612191723897081, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322663017125368550, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322612191723897081, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=434, endPage=441, ext={EN=ArticleExt(id=1322612225286713955, articleId=1322612225139913314, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Microstructure and Property of CuS Nanocrystalline Counter Electrode in Quantum Dot Sensitized Cells, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

Two kinds of CuS counter electrodes with different morphologies applied to QDSC were prepared by a solvothermal method and an in-situ method, respectively. The prepared counter electrodes were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, electrochemical impedance spectroscopy (EIS) and current-voltage (J-V) curve measurement, respectively. According to the results by morphology analysis, CuS nanoparticles with a size of 20 nm can be agglomerated into larger and irregular particles in CuS counter electrode prepared by the in-situ method, and CuS counter electrode prepared by the solvothermal method consists of nanorods and nanoparticles in microstructrue. The results reveal that two kinds of CuS counter electrodes are superior to Pt counter electrode in the electrical performance. CuS counter electrode prepared by the in-situ method yields the maximum power conversion efficiency (i.e., 1.840%) and the charge transfer resistance Rct is 3.346 Ω. CuS counter electrode prepared by the solvothermal method yields a power conversion efficiency of 1.450% and Rct is 2.609 Ω. The corresponding parameters of Pt counter electrode are 0.940% and 11.680 Ω, respectively.

, authors=Qiming WANG, Di WANG, Hongquan SUN, Wei ZHENG, authorsList=Qiming WANG, Di WANG, Hongquan SUN, Wei ZHENG, authorCompany=null, correspAuthors=Wei ZHENG, authorNote=

WANG Qiming (1994-), male, Master candidate. E-mai:

, correspAuthorsNote=
ZHENG Wei (1972-), female, Ph.D., Professor. E-mail:
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采用溶剂热法和原位法制备了两种具有不同形貌CuS对电极,并应用于量子点敏化太阳能电池(QDSC)中。结果表明:在原位法制备的CuS对电极中,由尺寸在20 nm左右的CuS纳米颗粒团聚成较大的不规则颗粒;在水热法制备的CuS对电极中,其微观结构为纳米棒和纳米片组成的复合结构。与Pt对电极相比,两种CuS对电极的电学性能均优于Pt对电极:原位法制备的CuS对电极的光电转换效率最大,为1.840%,界面传荷电阻Rct为3.346 Ω;溶剂热法制备的CuS对电极的光电转换效率为1.450%,界面传荷电阻Rct为2.609 Ω,Pt对电极的光电转换效率为0.940%,传荷电阻Rct为11.680 Ω。

, authors=王启明, 王迪, 孙洪全, 郑威, authorsList=王启明, 王迪, 孙洪全, 郑威, authorCompany=null, correspAuthors=郑威, authorNote=

王启明(1994—),男,硕士研究生。

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郑威(1972—),女,博士,教授。
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制备方法对量子点敏化太阳能电池CuS纳米晶对电极微观结构和性能的影响
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王启明 , 王迪 , 孙洪全 , 郑威
硅酸盐学报 | 2020,48(3): 434-441
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硅酸盐学报 | 2020 , 48 (3) : 434 -441
制备方法对量子点敏化太阳能电池CuS纳米晶对电极微观结构和性能的影响
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王启明 , 王迪, 孙洪全, 郑威
作者信息
  • 哈尔滨理工大学材料科学与工程学院,哈尔滨 150040
通讯作者:
郑威(1972—),女,博士,教授。
作者简介:

王启明(1994—),男,硕士研究生。

Microstructure and Property of CuS Nanocrystalline Counter Electrode in Quantum Dot Sensitized Cells
Qiming WANG , Di WANG, Hongquan SUN, Wei ZHENG
Affiliations
  • School of Material Science and Engineering, Harbin University of Science and Technology, Harbin 150040, China
  • Corresponding Author:
    ZHENG Wei (1972-), female, Ph.D., Professor. E-mail:

    WANG Qiming (1994-), male, Master candidate. E-mai:

出版时间: 2020-03-20 doi: 10.14062/j.issn.0454-5648.20190313
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采用溶剂热法和原位法制备了两种具有不同形貌CuS对电极,并应用于量子点敏化太阳能电池(QDSC)中。结果表明:在原位法制备的CuS对电极中,由尺寸在20 nm左右的CuS纳米颗粒团聚成较大的不规则颗粒;在水热法制备的CuS对电极中,其微观结构为纳米棒和纳米片组成的复合结构。与Pt对电极相比,两种CuS对电极的电学性能均优于Pt对电极:原位法制备的CuS对电极的光电转换效率最大,为1.840%,界面传荷电阻Rct为3.346 Ω;溶剂热法制备的CuS对电极的光电转换效率为1.450%,界面传荷电阻Rct为2.609 Ω,Pt对电极的光电转换效率为0.940%,传荷电阻Rct为11.680 Ω。

硫化铜对电极  /  溶剂热法  /  原位法  /  微观结构  /  光电转换效率

Two kinds of CuS counter electrodes with different morphologies applied to QDSC were prepared by a solvothermal method and an in-situ method, respectively. The prepared counter electrodes were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, electrochemical impedance spectroscopy (EIS) and current-voltage (J-V) curve measurement, respectively. According to the results by morphology analysis, CuS nanoparticles with a size of 20 nm can be agglomerated into larger and irregular particles in CuS counter electrode prepared by the in-situ method, and CuS counter electrode prepared by the solvothermal method consists of nanorods and nanoparticles in microstructrue. The results reveal that two kinds of CuS counter electrodes are superior to Pt counter electrode in the electrical performance. CuS counter electrode prepared by the in-situ method yields the maximum power conversion efficiency (i.e., 1.840%) and the charge transfer resistance Rct is 3.346 Ω. CuS counter electrode prepared by the solvothermal method yields a power conversion efficiency of 1.450% and Rct is 2.609 Ω. The corresponding parameters of Pt counter electrode are 0.940% and 11.680 Ω, respectively.

copper sulfide counter electrode  /  solvothermal method  /  in-situ method  /  microstructrue  /  power conversion efficiency
王启明, 王迪, 孙洪全, 郑威. 制备方法对量子点敏化太阳能电池CuS纳米晶对电极微观结构和性能的影响. 硅酸盐学报, 2020 , 48 (3) : 434 -441 . DOI: 10.14062/j.issn.0454-5648.20190313
Qiming WANG, Di WANG, Hongquan SUN, Wei ZHENG. Microstructure and Property of CuS Nanocrystalline Counter Electrode in Quantum Dot Sensitized Cells[J]. Journal of the Chinese Ceramic Society, 2020 , 48 (3) : 434 -441 . DOI: 10.14062/j.issn.0454-5648.20190313
  • 黑龙江省自然科学基金(E2018044)
  • 哈尔滨市优秀学科带头人项目(2017RAXXJ078)
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2020年第48卷第3期
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doi: 10.14062/j.issn.0454-5648.20190313
  • 接收时间:2019-05-12
  • 首发时间:2026-10-29
  • 出版时间:2020-03-20
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  • 收稿日期:2019-05-12
  • 修回日期:2019-06-26
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黑龙江省自然科学基金(E2018044)
哈尔滨市优秀学科带头人项目(2017RAXXJ078)
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    哈尔滨理工大学材料科学与工程学院,哈尔滨 150040

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郑威(1972—),女,博士,教授。
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2种不同金属材料的力学参数
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鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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