Article(id=1322609036575494358, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322608967147172356, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20190376, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1561910400000, receivedDateStr=2019-07-01, revisedDate=1564588800000, revisedDateStr=2019-08-01, acceptedDate=null, acceptedDateStr=null, onlineDate=1793264167206, onlineDateStr=2026-10-29, pubDate=1582128000000, pubDateStr=2020-02-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793264167206, onlineIssueDateStr=2026-10-29, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793264167206, creator=13701087609, updateTime=1793264167206, updator=13701087609, issue=Issue{id=1322608967147172356, tenantId=1146029695717560320, journalId=1263187385517883426, year='2020', volume='48', issue='2', pageStart='147', pageEnd='324', issueExtLink='null', onlineDate='null', pubDate='1582128000000', pubDateStr='2020-02-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793264150653, creator='13701087609', updateTime=1793276939599, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322662607933255748, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322608967147172356, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322662607933255749, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322608967147172356, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=316, endPage=324, ext={EN=ArticleExt(id=1322609036751655127, articleId=1322609036575494358, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Preparation of Zeolite T Membranes for Isopropanol Dehydration Using Homogenous Liquid Precursors, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

Thin and dense zeolite T membranes with a thickness of 5 μm on low-cost mullite tubular supports were synthesized via two-stage varying-temperature crystallization (TSVTC) with homogeneous liquid precursors. Effect of precursors on the crystal morphology and pervaporation performance of as-synthesized membranes, and synthesis time/temperature during the two-stage hydrothermal crystallization process was investigated. The results show that zeolite T membranes synthesized under optimized conditions have an enhanced pervaporation performance (i.e., the high flux of 4.3 kg/(m2·h), and the separation factor of 2 000 in water/isopropanol (10/90, mass ratio) aqueous solution at 348 K). These membranes show a good reproducibility and a long-term hydrothermal stability as well.

, authors=Yi LIU, Huizhi ZHANG, Jiayou ZHANG, Fei ZHANG, Tian GUI, Na HU, Xiangshu CHEN, authorsList=Yi LIU, Huizhi ZHANG, Jiayou ZHANG, Fei ZHANG, Tian GUI, Na HU, Xiangshu CHEN, authorCompany=null, correspAuthors=Na HU, Xiangshu CHEN, authorNote=

LIU Yi (1994-), female, Master candidate. E-mail:

, correspAuthorsNote=
HU Na (1984-), female, Ph.D., Senior Experimentalist; E-mail:
CHEN Xiangshu (1966-), male, Ph.D., Professor.
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322609036923621592, articleId=1322609036575494358, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=均相溶胶体系合成用于异丙醇脱水的T型分子筛膜, columnId=null, journalTitle=硅酸盐学报, columnName=, runingTitle=null, highlight=null, articleAbstract=

采用均相合成溶胶体系通过两步变温法在廉价莫来石支撑体上制备了厚度为5 μm薄且致密的T型分子筛膜。考察了均相溶胶体系、合成温度和合成时间对所制备膜的晶体形貌以及渗透汽化的影响。结果表明:最优条件下制备的T型分子筛膜在348 K、水/异丙醇质量比为10/90的混合体系中表现的渗透通量和分离因子分别高达4.3 kg/(m2·h)和2 000,且该膜具有良好的重复性和水热稳定性。

, authors=刘义, 张慧智, 张家友, 张飞, 桂田, 胡娜, 陈祥树, authorsList=刘义, 张慧智, 张家友, 张飞, 桂田, 胡娜, 陈祥树, authorCompany=null, correspAuthors=胡娜, 陈祥树, authorNote=

刘义(1994—),女,硕士研究生。

, correspAuthorsNote=
胡娜(1984—),女,博士,高级实验师;
陈祥树(1966—),男,博士,教授。
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均相溶胶体系合成用于异丙醇脱水的T型分子筛膜
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刘义 , 张慧智 , 张家友 , 张飞 , 桂田 , 胡娜 , 陈祥树
硅酸盐学报 | 2020,48(2): 316-324
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硅酸盐学报 | 2020 , 48 (2) : 316 -324
均相溶胶体系合成用于异丙醇脱水的T型分子筛膜
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刘义(1994—),女,硕士研究生。

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刘义 , 张慧智, 张家友, 张飞, 桂田, 胡娜 , 陈祥树
作者信息
  • 江西师范大学先进材料研究院,分子筛膜材料国家地方联合工程实验室,江西师范大学化学化工学院,南昌 330022
通讯作者:
胡娜(1984—),女,博士,高级实验师;
陈祥树(1966—),男,博士,教授。
作者简介:

刘义(1994—),女,硕士研究生。

Preparation of Zeolite T Membranes for Isopropanol Dehydration Using Homogenous Liquid Precursors
Yi LIU , Huizhi ZHANG, Jiayou ZHANG, Fei ZHANG, Tian GUI, Na HU , Xiangshu CHEN
Affiliations
  • Institute of Advanced Materials (IAM), State-Province Joint Engineering Laboratory of Zeolite Membrane Materials, College of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, China
  • Corresponding Author:
    HU Na (1984-), female, Ph.D., Senior Experimentalist; E-mail:
    CHEN Xiangshu (1966-), male, Ph.D., Professor.

    LIU Yi (1994-), female, Master candidate. E-mail:

出版时间: 2020-02-20 doi: 10.14062/j.issn.0454-5648.20190376
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采用均相合成溶胶体系通过两步变温法在廉价莫来石支撑体上制备了厚度为5 μm薄且致密的T型分子筛膜。考察了均相溶胶体系、合成温度和合成时间对所制备膜的晶体形貌以及渗透汽化的影响。结果表明:最优条件下制备的T型分子筛膜在348 K、水/异丙醇质量比为10/90的混合体系中表现的渗透通量和分离因子分别高达4.3 kg/(m2·h)和2 000,且该膜具有良好的重复性和水热稳定性。

分子筛膜  /  均相溶胶  /  两步变温晶化  /  晶体生长  /  渗透汽化

Thin and dense zeolite T membranes with a thickness of 5 μm on low-cost mullite tubular supports were synthesized via two-stage varying-temperature crystallization (TSVTC) with homogeneous liquid precursors. Effect of precursors on the crystal morphology and pervaporation performance of as-synthesized membranes, and synthesis time/temperature during the two-stage hydrothermal crystallization process was investigated. The results show that zeolite T membranes synthesized under optimized conditions have an enhanced pervaporation performance (i.e., the high flux of 4.3 kg/(m2·h), and the separation factor of 2 000 in water/isopropanol (10/90, mass ratio) aqueous solution at 348 K). These membranes show a good reproducibility and a long-term hydrothermal stability as well.

zeolite membrane  /  homogeneous liquid precursor  /  two-stage varying-temperature crystallization  /  crystal growth  /  pervaporation
刘义, 张慧智, 张家友, 张飞, 桂田, 胡娜, 陈祥树. 均相溶胶体系合成用于异丙醇脱水的T型分子筛膜. 硅酸盐学报, 2020 , 48 (2) : 316 -324 . DOI: 10.14062/j.issn.0454-5648.20190376
Yi LIU, Huizhi ZHANG, Jiayou ZHANG, Fei ZHANG, Tian GUI, Na HU, Xiangshu CHEN. Preparation of Zeolite T Membranes for Isopropanol Dehydration Using Homogenous Liquid Precursors[J]. Journal of the Chinese Ceramic Society, 2020 , 48 (2) : 316 -324 . DOI: 10.14062/j.issn.0454-5648.20190376
  • 国家国际科技合作专项(2015DFA50190)
  • 国家自然科学基金项目(21868013; 21476099; 21766010)
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2020年第48卷第2期
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doi: 10.14062/j.issn.0454-5648.20190376
  • 接收时间:2019-07-01
  • 首发时间:2026-10-29
  • 出版时间:2020-02-20
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  • 收稿日期:2019-07-01
  • 修回日期:2019-08-01
基金
国家国际科技合作专项(2015DFA50190)
国家自然科学基金项目(21868013; 21476099; 21766010)
作者信息
    江西师范大学先进材料研究院,分子筛膜材料国家地方联合工程实验室,江西师范大学化学化工学院,南昌 330022

通讯作者:

胡娜(1984—),女,博士,高级实验师;
陈祥树(1966—),男,博士,教授。
参考文献
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2种不同金属材料的力学参数
科
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属数
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genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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