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Article(id=1322608984398353214, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322608929100649011, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20190291, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1557158400000, receivedDateStr=2019-05-07, revisedDate=1561564800000, revisedDateStr=2019-06-27, acceptedDate=null, acceptedDateStr=null, onlineDate=1793264154767, onlineDateStr=2026-10-29, pubDate=1579449600000, pubDateStr=2020-01-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793264154767, onlineIssueDateStr=2026-10-29, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793264154767, creator=13701087609, updateTime=1793264154767, updator=13701087609, issue=Issue{id=1322608929100649011, tenantId=1146029695717560320, journalId=1263187385517883426, year='2020', volume='48', issue='1', pageStart='1', pageEnd='146', issueExtLink='null', onlineDate='null', pubDate='1579449600000', pubDateStr='2020-01-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793264141583, creator='13701087609', updateTime=1793276771816, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322661904204542961, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322608929100649011, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322661904208737266, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322608929100649011, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=112, endPage=119, ext={EN=ArticleExt(id=1322608986050908991, articleId=1322608984398353214, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Preparation and Mechanism of Vermiculite with High Expansion Rate, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

In order to improve the utilization efficiency of vermiculite mineral resources and expand the added value of expanded vermiculite products, an high expansion rate expanded vermiculite (HEV) with was prepared by a chemical treatment-baking heating method with industrial vermiculite from Xinjiang as a raw material. The structure and morphology, optimal preparation process and expansion mechanism of HEV were investigated. The results show that the expansion rate of the HEV is approximately 70 times greater than that of the expanded vermiculite prepared by conventional methods. The preparation mechanism of HEV is related to the mosaic structure of phlogopite, hydrophlogopite and vermiculite in the raw material. This structure can form massive cavities in the industrial vermiculite layer, effectively hindering the escape of internal gas. As a result, the industrial vermiculite has a better thermal expansion performance. The preparation method can improve the application efficiency of industrial vermiculite resource and reduce the production cost. The HEV can be used as a low-cost precursor for vermiculite nanomaterials.

, authors=Yanyan XIE1, 2, Hongjuan SUN1, 2, 3, Tongjiang PENG1, 2, 3, 4, Liming LUO1, 2, Jingfei TIAN1, 2, Yating QIN1, 2, authorsList=Yanyan XIE, Hongjuan SUN, Tongjiang PENG, Liming LUO, Jingfei TIAN, Yating QIN, authorCompany=null, correspAuthors=Hongjuan SUN, authorNote=

XIE Yanyan (1994-), male, Master candidate. E-mail:

, correspAuthorsNote=
SUN Hongjuan (1976-), female, Ph.D., Professor. E-mail:
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为提高蛭石矿产资源利用效率和膨胀蛭石产品附加值，以新疆尉犁工业蛭石为原料，采用化学处理-焙烧加热法制备高膨胀倍数膨胀蛭石（HEV），研究HEV结构与形貌、最佳制备工艺与膨胀机理。结果表明：HEV样品膨胀倍数（约70倍）远超常规方法制备的膨胀蛭石样品。HEV的制备机理与工业蛭石内部金云母、水金云母及蛭石的镶嵌结构有关。该结构可导致工业蛭石片层形成大量空腔，有效阻碍内部气体的逸出，使工业蛭石获得更好的热膨胀性能。该制备方法可提高工业蛭石资源应用效率，降低生产成本。HEV可作为蛭石纳米材料的低成本前驱体。

, authors=解颜岩1, 2, 孙红娟1, 2, 3, 彭同江1, 2, 3, 4, 罗利明1, 2, 田景斐1, 2, 秦亚婷1, 2, authorsList=解颜岩, 孙红娟, 彭同江, 罗利明, 田景斐, 秦亚婷, authorCompany=null, correspAuthors=孙红娟, authorNote=

解颜岩（1994—），男，硕士研究生。

, correspAuthorsNote=
孙红娟（1976—），女，博士，教授。
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蛭石的高膨胀倍数制备工艺与机理
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解颜岩 1, 2 , 孙红娟 1, 2, 3 , 彭同江 1, 2, 3, 4 , 罗利明 1, 2 , 田景斐 1, 2 , 秦亚婷 1, 2
硅酸盐学报 | 2020,48(1): 112-119
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硅酸盐学报 | 2020 , 48 (1) : 112 -119
蛭石的高膨胀倍数制备工艺与机理
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解颜岩1, 2 , 孙红娟1, 2, 3 , 彭同江1, 2, 3, 4, 罗利明1, 2, 田景斐1, 2, 秦亚婷1, 2
作者信息
  • 1．西南科技大学，固体废物处理与资源化教育部重点实验室，四川 绵阳 621010
  • 2．西南科技大学，矿物材料及应用研究所，四川 绵阳 621010
  • 3．西南科技大学，四川省非金属矿粉体改性与高质化利用技术工程实验室，四川 绵阳 621000
  • 4．西南科技大学分析测试中心，四川 绵阳 621010
通讯作者:
孙红娟（1976—），女，博士，教授。
作者简介:

解颜岩（1994—），男，硕士研究生。

Preparation and Mechanism of Vermiculite with High Expansion Rate
Yanyan XIE1, 2 , Hongjuan SUN1, 2, 3 , Tongjiang PENG1, 2, 3, 4, Liming LUO1, 2, Jingfei TIAN1, 2, Yating QIN1, 2
Affiliations
  • 1.Key Laboratory of Ministry of Education for Solid Waste Treatment and Resource Recycle, Southwest University of Science and Technology, Mianyang 621010, Sichuan, China
  • 2.Institute of Mineral Materials and Applications, Southwest University of Science and Technology, Mianyang 621010, Sichuan, China
  • 3.Sichuan Engineering Lab of Nonmetallic Mineral Powder Modification & High-quality Utilization, Southwest University of Science and Technology, Mianyang 621010, Sichuan, China
  • 4.Center of Forecasting and Analysis, Southwest University of Science and Technology, Mianyang 621010, Sichuan, China
    • Corresponding Author:
    SUN Hongjuan (1976-), female, Ph.D., Professor. E-mail:

    XIE Yanyan (1994-), male, Master candidate. E-mail:

出版时间: 2020-01-20 doi: 10.14062/j.issn.0454-5648.20190291
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为提高蛭石矿产资源利用效率和膨胀蛭石产品附加值，以新疆尉犁工业蛭石为原料，采用化学处理-焙烧加热法制备高膨胀倍数膨胀蛭石（HEV），研究HEV结构与形貌、最佳制备工艺与膨胀机理。结果表明：HEV样品膨胀倍数（约70倍）远超常规方法制备的膨胀蛭石样品。HEV的制备机理与工业蛭石内部金云母、水金云母及蛭石的镶嵌结构有关。该结构可导致工业蛭石片层形成大量空腔，有效阻碍内部气体的逸出，使工业蛭石获得更好的热膨胀性能。该制备方法可提高工业蛭石资源应用效率，降低生产成本。HEV可作为蛭石纳米材料的低成本前驱体。

草酸  /  过氧化氢  /  工业蛭石  /  高膨胀倍数  /  镶嵌结构

In order to improve the utilization efficiency of vermiculite mineral resources and expand the added value of expanded vermiculite products, an high expansion rate expanded vermiculite (HEV) with was prepared by a chemical treatment-baking heating method with industrial vermiculite from Xinjiang as a raw material. The structure and morphology, optimal preparation process and expansion mechanism of HEV were investigated. The results show that the expansion rate of the HEV is approximately 70 times greater than that of the expanded vermiculite prepared by conventional methods. The preparation mechanism of HEV is related to the mosaic structure of phlogopite, hydrophlogopite and vermiculite in the raw material. This structure can form massive cavities in the industrial vermiculite layer, effectively hindering the escape of internal gas. As a result, the industrial vermiculite has a better thermal expansion performance. The preparation method can improve the application efficiency of industrial vermiculite resource and reduce the production cost. The HEV can be used as a low-cost precursor for vermiculite nanomaterials.

oxalic acid  /  hydrogen peroxide  /  industrial vermiculite  /  high expansion rate  /  mosaic structure
解颜岩, 孙红娟, 彭同江, 罗利明, 田景斐, 秦亚婷. 蛭石的高膨胀倍数制备工艺与机理. 硅酸盐学报, 2020 , 48 (1) : 112 -119 . DOI: 10.14062/j.issn.0454-5648.20190291
Yanyan XIE, Hongjuan SUN, Tongjiang PENG, Liming LUO, Jingfei TIAN, Yating QIN. Preparation and Mechanism of Vermiculite with High Expansion Rate[J]. Journal of the Chinese Ceramic Society, 2020 , 48 (1) : 112 -119 . DOI: 10.14062/j.issn.0454-5648.20190291
基金
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  • 四川省教育厅创新团队项目(14TD0012)
  • 国家重点研发项目(2018YFC1802902)
  • 西南科技大学研究生创新基金(18ycx043)
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2020年第48卷第1期
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doi: 10.14062/j.issn.0454-5648.20190291
  • 接收时间：2019-05-07
  • 首发时间：2026-10-29
  • 出版时间：2020-01-20
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  • 收稿日期：2019-05-07
  • 修回日期：2019-06-27
基金
四川省教育厅创新团队项目(14TD0012)
国家重点研发项目(2018YFC1802902)
西南科技大学研究生创新基金(18ycx043)
作者信息
    1．西南科技大学，固体废物处理与资源化教育部重点实验室，四川 绵阳 621010
    2．西南科技大学，矿物材料及应用研究所，四川 绵阳 621010
    3．西南科技大学，四川省非金属矿粉体改性与高质化利用技术工程实验室，四川 绵阳 621000
    4．西南科技大学分析测试中心，四川 绵阳 621010

通讯作者:

孙红娟（1976—），女，博士，教授。
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https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20190291
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2种不同金属材料的力学参数
科
Family		 属数
Number of
genus		 种数
Number of
species		 占总种数比例
Percentage of
total species (%)		 属
Genus		 种数
Number of
species		 占总种数比例
Percentage of total
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鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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