Article(id=1322608953767350966, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322608929100649011, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20190283, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1556380800000, receivedDateStr=2019-04-28, revisedDate=1559145600000, revisedDateStr=2019-05-30, acceptedDate=null, acceptedDateStr=null, onlineDate=1793264147464, onlineDateStr=2026-10-29, pubDate=1579449600000, pubDateStr=2020-01-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793264147464, onlineIssueDateStr=2026-10-29, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793264147464, creator=13701087609, updateTime=1793264147464, updator=13701087609, issue=Issue{id=1322608929100649011, tenantId=1146029695717560320, journalId=1263187385517883426, year='2020', volume='48', issue='1', pageStart='1', pageEnd='146', issueExtLink='null', onlineDate='null', pubDate='1579449600000', pubDateStr='2020-01-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793264141583, creator='13701087609', updateTime=1793276771816, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322661904204542961, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322608929100649011, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322661904208737266, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322608929100649011, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=44, endPage=52, ext={EN=ArticleExt(id=1322608954182587064, articleId=1322608953767350966, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Preparation and Photocatalytic Properties under Visible Light Irradiation of Graphite-like Carbon Nitride Nanosheets, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

Graphitic carbon nitride (g-C3N4) nanosheet was synthesized by a facile fabrication method. Melamine was treated by a thermal polycondensation process. Pure g-C3N4 was treated by acid etching, heat etching and coupling with NH4Cl. The crystalline structure, morphology, specific surface area, band structure and visible absorption of the material were evaluated by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, Fourier transform infrared spectroscopy analysis, X-ray photoelectron spectroscopy, Raman spectroscopy, specific surface area (BET analysis), ultraviolet visible diffuse reflection spectroscopy and Mott-Schottky curve analysis, respectively. The photocatalytic activity was estimated by the degradation of Rhodamine and tetracycline hydrochloride solution under visible light irradiation. The results show that a clear, ordered, 2D nanosheet g-C3N4 structure with a layer thickness of 47 nm is formed, and the maximum specific surface area is a maximum (22 m2/g) when the mole ratio of melamine to NH4Cl is 5∶4. The photocatalytic performance of bulk g-C3N4 is enhanced after treatment. The photocatalytic degradation rate of the sample treated with melamine and NH4Cl at a ratio of 5∶4 is 3.4 times greater than that of untreated g-C3N4. The sample degrades 83.2% tetracycline hydrochloride solution for 4 h.

, authors=Aiqiong MA1, Dian ZHANG1, Youzi ZHANG2, Yunqin GAO1, authorsList=Aiqiong MA, Dian ZHANG, Youzi ZHANG, Yunqin GAO, authorCompany=null, correspAuthors=null, authorNote=

MA Aiqiong (1970-), female, Ph.D., Professor. E-mail:

, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322608954958533305, articleId=1322608953767350966, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=纳米片层状类石墨氮化碳的制备及其光催化性能, columnId=null, journalTitle=硅酸盐学报, columnName=, runingTitle=null, highlight=null, articleAbstract=

以三聚氰胺为原料,采用热缩聚合成法,结合酸、热刻蚀协同改性工艺,制备了二维纳米片层状类石墨氮化碳(g-C3N4)。通过X射线衍射、扫描电镜、透射电镜、红外光谱、X射线光电子能谱、Raman光谱对试样进行了物相组成、显微形貌与分子结构表征。采用BET法分析了试样的比表面积,采用紫外-可见漫反射光谱、Mott-Schottky曲线分析了试样的可见光吸收性能与能带结构。通过可见光降解罗丹明B染料与盐酸四环素溶液,评估了试样的可见光催化性能。结果表明:采用热刻蚀改性剥离时,当三聚氰胺与NH4Cl的摩尔比为5∶4时,所制备的纳米片层状g-C3N4厚度为47 nm,比表面积为22 m2/g,可见光催化降解性能提高显著,相比未经过改性处理的g-C3N4,其降解效率提高了3.4倍;4 h内对盐酸四环素溶液的降解率达到83.2%。

, authors=马爱琼1, 张电1, 张由子2, 高云琴1, authorsList=马爱琼, 张电, 张由子, 高云琴, authorCompany=null, correspAuthors=null, authorNote=

马爱琼(1970—),女,博士,教授。

, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=AtjlHuiMWe8HTrlBBsl4hg==, magXml=QXA2l/qap62HDV6KF4Yqog==, pdfUrl=null, pdf=IP5Ops7CqMGMuqiHue1dLg==, pdfFileSize=3312695, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=JumHtmoiW6paWmvPCqoM0g==, mapNumber=null, fund=null)}, authors=[Author(id=1322954667751256581, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, orderNo=0, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=maaiqiong@xauat.edu.cn, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1322954667868697095, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, authorId=1322954667751256581, language=EN, stringName=Aiqiong MA, firstName=Aiqiong, middleName=null, lastName=MA, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.College of Materials Science and Engineering, Xi'an University of Architecture &Technology, Xi'an 710055, China, bio={"content":"

MA Aiqiong (1970-), female, Ph.D., Professor. E-mail:

"}, bioImg=null, bioContent=

MA Aiqiong (1970-), female, Ph.D., Professor. E-mail:

, aboutCorrespAuthor=null), CN=AuthorExt(id=1322954668002914824, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, authorId=1322954667751256581, language=CN, stringName=马爱琼, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.西安建筑科技大学材料科学与工程学院,西安 710055, bio={"content":"

马爱琼(1970—),女,博士,教授。

"}, bioImg=null, bioContent=

马爱琼(1970—),女,博士,教授。

, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1322954667499598334, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, xref=1., ext=[AuthorCompanyExt(id=1322954667507986943, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, companyId=1322954667499598334, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.College of Materials Science and Engineering, Xi'an University of Architecture &Technology, Xi'an 710055, China), AuthorCompanyExt(id=1322954667520569856, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, companyId=1322954667499598334, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.西安建筑科技大学材料科学与工程学院,西安 710055)])]), Author(id=1322954668070023691, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, orderNo=1, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=null, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1322954668162298381, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, authorId=1322954668070023691, language=EN, stringName=Dian ZHANG, firstName=Dian, middleName=null, lastName=ZHANG, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.College of Materials Science and Engineering, Xi'an University of Architecture &Technology, Xi'an 710055, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1322954668225212942, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, authorId=1322954668070023691, language=CN, stringName=张电, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.西安建筑科技大学材料科学与工程学院,西安 710055, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1322954667499598334, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, xref=1., ext=[AuthorCompanyExt(id=1322954667507986943, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, companyId=1322954667499598334, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.College of Materials Science and Engineering, Xi'an University of Architecture &Technology, Xi'an 710055, China), AuthorCompanyExt(id=1322954667520569856, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, companyId=1322954667499598334, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.西安建筑科技大学材料科学与工程学院,西安 710055)])]), Author(id=1322954668300710416, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, orderNo=2, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=null, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1322954668372013586, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, authorId=1322954668300710416, language=EN, stringName=Youzi ZHANG, firstName=Youzi, middleName=null, lastName=ZHANG, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=2, address=2.College of Materials Science and Engineering, Northwestern Polytechnical University, Xi'an 710068, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1322954668460093971, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, authorId=1322954668300710416, language=CN, stringName=张由子, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=2, address=2.西北工业大学材料科学与工程学院,西安 710068, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1322954667600261633, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, xref=2., ext=[AuthorCompanyExt(id=1322954667608650242, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, companyId=1322954667600261633, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=2.College of Materials Science and Engineering, Northwestern Polytechnical University, Xi'an 710068, China), AuthorCompanyExt(id=1322954667650593283, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, companyId=1322954667600261633, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=2.西北工业大学材料科学与工程学院,西安 710068)])]), Author(id=1322954668523008533, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, orderNo=3, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=null, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1322954670225895959, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, authorId=1322954668523008533, language=EN, stringName=Yunqin GAO, firstName=Yunqin, middleName=null, lastName=GAO, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.College of Materials Science and Engineering, Xi'an University of Architecture &Technology, Xi'an 710055, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1322954670330753560, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, authorId=1322954668523008533, language=CN, stringName=高云琴, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.西安建筑科技大学材料科学与工程学院,西安 710055, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1322954667499598334, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, xref=1., ext=[AuthorCompanyExt(id=1322954667507986943, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, companyId=1322954667499598334, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.College of Materials Science and Engineering, Xi'an University of Architecture &Technology, Xi'an 710055, China), AuthorCompanyExt(id=1322954667520569856, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, companyId=1322954667499598334, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.西安建筑科技大学材料科学与工程学院,西安 710055)])])], keywords=[Keyword(id=1322954670506914329, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, language=EN, orderNo=1, keyword=graphitic carbon nitride), Keyword(id=1322954670586606106, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, language=EN, orderNo=2, keyword=two-dimensional nanosheet), Keyword(id=1322954670666297883, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, language=EN, orderNo=3, keyword=visible light), Keyword(id=1322954670737601052, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, language=EN, orderNo=4, keyword=etching), Keyword(id=1322954670804709917, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, language=EN, orderNo=5, keyword=photocatalyst), Keyword(id=1322954670876013086, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, language=CN, orderNo=1, keyword=类石墨氮化碳), Keyword(id=1322954670959899167, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, language=CN, orderNo=2, keyword=二维纳米层), Keyword(id=1322954671031202336, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, language=CN, orderNo=3, keyword=可见光), Keyword(id=1322954671102505505, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, language=CN, orderNo=4, keyword=刻蚀), Keyword(id=1322954671186391586, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, language=CN, orderNo=5, keyword=光催化剂)], refs=null, funds=[Fund(id=1322954671316415011, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, awardId=2020318029, language=CN, fundingSource=陕西省自然科学基金(2020318029), fundOrder=null, country=null)], companyList=[AuthorCompany(id=1322954667499598334, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, xref=1., ext=[AuthorCompanyExt(id=1322954667507986943, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, companyId=1322954667499598334, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.College of Materials Science and Engineering, Xi'an University of Architecture &Technology, Xi'an 710055, China), AuthorCompanyExt(id=1322954667520569856, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, companyId=1322954667499598334, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.西安建筑科技大学材料科学与工程学院,西安 710055)]), AuthorCompany(id=1322954667600261633, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, xref=2., ext=[AuthorCompanyExt(id=1322954667608650242, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, companyId=1322954667600261633, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=2.College of Materials Science and Engineering, Northwestern Polytechnical University, Xi'an 710068, China), AuthorCompanyExt(id=1322954667650593283, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, companyId=1322954667600261633, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=2.西北工业大学材料科学与工程学院,西安 710068)])], figs=null, attaches=null, journal=Journal(id=1263186332462366751, delFlag=0, nameCn=硅酸盐学报, nameEn=Journal of the Chinese Ceramic Society, nameHistory1=null, nameHistory2=null, issn=0454-5648, eissn=null, cn=11-2310/TQ, coden=null, periodic=0, language=CN, oaType=null, ccby=null, superviseOffice=null, ownerOffice=null, pubOffice=null, editorOffice=null, officeType=null, aims=null, clcCode=null, officeProv=null, officeCity=null, officeAddr=null, officeZip=null, officeEmail=null, officePhone=null, editDirector=null, officeDirector=null, officeDirectorPhone=null, officeStaffNum=null, officeEmpNum=null, coverPicUrl=8Qg1+Is+LeRD1Lv6UJcXRg==, journalPrice=null, startedYear=null, abbrevIsoEn=Journal of the Chinese Ceramic Society, journalRemark=null, publicationField=null, createdTime=1779096690528, updatedTime=1788951192520, createdBy=18614031015, updatedBy=13041195026, firstLetterCn=G, firstLetterEn=G, subjectCode=Engineering, subjectName=null, subjectCodeEn=Engineering, subjectNameEn=null, picCn=8Qg1+Is+LeRD1Lv6UJcXRg==, picEn=AY9tl+TwuKtB81GF+w4WAg==, jcr=null, cjcr=null, exts=[JournalExt(id=1304519110767960749, language=CN, name=硅酸盐学报, nameHistory1=null, nameHistory2=null, managedBy=, sponsoredBy=, publishedBy=, editorOffice=, officeProv=null, officeCity=null, officeAddr=, officeZip=, editDirector=, officeDirector=null, officePhone=null, coverPicUrl=null, journalRemark=, submitArticleUrl=null, websiteUrl=, createdTime=1788951192800, updatedTime=1788951192800, createdBy=13041195026, updatedBy=13041195026, submissionGuidelinesUrl=, submissionAuthorUrl=https://gxyb.cbpt.cnki.net/index.aspx?t=1, submissionEditorUrl=https://gxyb.cbpt.cnki.net/index.aspx?t=3, submissionReviewUrl=https://gxyb.cbpt.cnki.net/index.aspx?t=2, submissionCeEditorUrl=, submissionAeEditorUrl=, option={"copyright":""}), JournalExt(id=1304519110839263918, language=EN, name=Journal of the Chinese Ceramic Society, nameHistory1=null, nameHistory2=null, managedBy=, sponsoredBy=, publishedBy=, editorOffice=, officeProv=null, officeCity=null, officeAddr=, officeZip=, editDirector=, officeDirector=null, officePhone=null, coverPicUrl=null, journalRemark=, submitArticleUrl=null, websiteUrl=, createdTime=1788951192817, updatedTime=1788951192817, createdBy=13041195026, updatedBy=13041195026, submissionGuidelinesUrl=, submissionAuthorUrl=https://gxyb.cbpt.cnki.net/index.aspx?t=1, submissionEditorUrl=https://gxyb.cbpt.cnki.net/index.aspx?t=3, submissionReviewUrl=https://gxyb.cbpt.cnki.net/index.aspx?t=2, submissionCeEditorUrl=, submissionAeEditorUrl=, option={"copyright":""})], databaseList=null, tenantJournalId=1263187385517883426, websiteList=[Website(id=1263188159895093557, webName=null, webTitle=null, webDomain=null, webCopyrigh=null, webIpcNo=null, seoTitle=null, seoKeywords=null, seoDescription=null, tenantJournalId=null, journalId=1263187385517883426, journalNameCn=null, journalNameEn=null, grayFlag=null, tenantId=1146029695717560320, platformId=null, journalGroupId=null, journalGroupNameCn=null, journalGroupNameEn=null, type=1, domain=https://castjournals.cast.org.cn/joweb/gsyxb/CN, language=CN, createTime=1779097126220, createBy=18614031015, updateTime=1779097837121, updateBy=18614031015, name=硅酸盐学报-中文, tplId=1146099689490845704, title=硅酸盐学报, delFlag=0, indexPage=/home, props=[WebsiteProps(id=1263191261578649862, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=articleTextType, value=kx, createTime=1779097865719, updateTime=1779097865719, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191261545095427, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=banner, value=null, createTime=1779097865711, updateTime=1779097865711, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191261599621385, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=grayFlag, value=0, createTime=1779097865724, updateTime=1779097865724, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191261532512514, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=logo, value=https://castjournals.cast.org.cn/joweb/gsyxb/CN/file/pic?fileId=Oqq9gXZG0JiYeHvLNwX/eg==, createTime=1779097865708, updateTime=1779097865708, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191261620592907, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=minRunFlag, value=0, createTime=1779097865729, updateTime=1779097865729, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191261574455557, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=picServerUrl, value=https://castjournals.cast.org.cn/joweb/gsyxb/CN/file/pic, createTime=1779097865718, updateTime=1779097865718, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191261616398602, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=silenceFlag, value=0, createTime=1779097865728, updateTime=1779097865728, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191261566066948, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=staticResourcePath, value=https://castjournals.cast.org.cn/joweb/cast_kjdb_cn_619/, createTime=1779097865716, updateTime=1779097865716, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191261587038471, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=themeColor, value=null, createTime=1779097865721, updateTime=1779097865721, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191261591232776, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188159895093557, code=themeStyle, value=null, createTime=1779097865722, updateTime=1779097865722, creator=18614031015, updator=18614031015)]), Website(id=1263188160188694841, webName=null, webTitle=null, webDomain=null, webCopyrigh=null, webIpcNo=null, seoTitle=null, seoKeywords=null, seoDescription=null, tenantJournalId=null, journalId=1263187385517883426, journalNameCn=null, journalNameEn=null, grayFlag=null, tenantId=1146029695717560320, platformId=null, journalGroupId=null, journalGroupNameCn=null, journalGroupNameEn=null, type=1, domain=https://castjournals.cast.org.cn/joweb/gsyxb/EN, language=EN, createTime=1779097126348, createBy=18614031015, updateTime=1779097825280, updateBy=18614031015, name=硅酸盐学报-英文, tplId=1146101810881728533, title=Journal of the Chinese Ceramic Society, delFlag=0, indexPage=/home, props=[WebsiteProps(id=1263191231102836987, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=articleTextType, value=kx, createTime=1779097858453, updateTime=1779097858453, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191231052505336, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=banner, value=null, createTime=1779097858441, updateTime=1779097858441, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191231186723070, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=grayFlag, value=0, createTime=1779097858473, updateTime=1779097858473, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191231039922423, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=logo, value=https://castjournals.cast.org.cn/joweb/gsyxb/EN/file/pic?fileId=Oqq9gXZG0JiYeHvLNwX/eg==, createTime=1779097858438, updateTime=1779097858438, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191231358689536, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=minRunFlag, value=0, createTime=1779097858514, updateTime=1779097858514, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191231094448378, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=picServerUrl, value=https://castjournals.cast.org.cn/joweb/gsyxb/EN/file/pic, createTime=1779097858451, updateTime=1779097858451, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191231195111679, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=silenceFlag, value=0, createTime=1779097858475, updateTime=1779097858475, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191231086059769, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=staticResourcePath, value=https://castjournals.cast.org.cn/joweb/cast_kjdb_en_623/, createTime=1779097858449, updateTime=1779097858449, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191231111225596, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=themeColor, value=null, createTime=1779097858455, updateTime=1779097858455, creator=18614031015, updator=18614031015), WebsiteProps(id=1263191231144780029, tenantId=1146029695717560320, journalId=null, journalGroupId=null, siteId=1263188160188694841, code=themeStyle, value=null, createTime=1779097858463, updateTime=1779097858463, creator=18614031015, updator=18614031015)])], journalTitle=硅酸盐学报, weixinUrl=null, journalUrl=https://jccsoc.cbpt.cnki.net/, iacademicId=null, status=1, seqNo=null, journalTitleEn=Journal of the Chinese Ceramic Society, journalPhotoCn=8Qg1+Is+LeRD1Lv6UJcXRg==, journalPhotoEn=AY9tl+TwuKtB81GF+w4WAg==, journalFirstLetter=G, journalRecommend=null, journalNew=null, journalCollection=null, jcrJf=null, cjcrJf=null, jcrJfStr=null, cjcrJfStr=null, submissionFirstDecision=null, sciSubjectClassification=null, casSubjectClassification=null, citeScore=null, totalCitationFrequency=null, icpCode=null, psCode=null, advertisingLicenseCode=null, copyrightInformation=null, country=null, option=, provinceCode=null, provinceName=null, collectFlag=false, interPubPlatform=, interPubPlatformUrl=null), detailUrlCn=https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20190283, detailUrlEn=https://castjournals.cast.org.cn/joweb/gsyxb/EN/10.14062/j.issn.0454-5648.20190283, pdfUrlCn=https://castjournals.cast.org.cn/joweb/gsyxb/CN/PDF/10.14062/j.issn.0454-5648.20190283, pdfUrlEn=https://castjournals.cast.org.cn/joweb/gsyxb/EN/PDF/10.14062/j.issn.0454-5648.20190283, aliStartDate=0, aliEndDate=0, collectionFlag=false, citedCount=null, citedUrl=null, previewStatus=0, delFlag=0, hasFullText=0, orderTime=1579449600000, fullTextJson=null, articleText=null, reference=null)
收藏切换
纳米片层状类石墨氮化碳的制备及其光催化性能
收藏切换
PDF下载
马爱琼 1 , 张电 1 , 张由子 2 , 高云琴 1
硅酸盐学报 | 2020,48(1): 44-52
收起
收藏切换
硅酸盐学报 | 2020 , 48 (1) : 44 -52
纳米片层状类石墨氮化碳的制备及其光催化性能
全屏
[Author(id=1322954667751256581, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, orderNo=0, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=maaiqiong@xauat.edu.cn, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1322954667868697095, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, authorId=1322954667751256581, language=EN, stringName=Aiqiong MA, firstName=Aiqiong, middleName=null, lastName=MA, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.College of Materials Science and Engineering, Xi'an University of Architecture &Technology, Xi'an 710055, China, bio={"content":"

MA Aiqiong (1970-), female, Ph.D., Professor. E-mail:

"}, bioImg=null, bioContent=

MA Aiqiong (1970-), female, Ph.D., Professor. E-mail:

, aboutCorrespAuthor=null), CN=AuthorExt(id=1322954668002914824, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, authorId=1322954667751256581, language=CN, stringName=马爱琼, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.西安建筑科技大学材料科学与工程学院,西安 710055, bio={"content":"

马爱琼(1970—),女,博士,教授。

"}, bioImg=null, bioContent=

马爱琼(1970—),女,博士,教授。

, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1322954667499598334, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, xref=1., ext=[AuthorCompanyExt(id=1322954667507986943, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, companyId=1322954667499598334, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.College of Materials Science and Engineering, Xi'an University of Architecture &Technology, Xi'an 710055, China), AuthorCompanyExt(id=1322954667520569856, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, companyId=1322954667499598334, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.西安建筑科技大学材料科学与工程学院,西安 710055)])]), Author(id=1322954668070023691, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, orderNo=1, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=null, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1322954668162298381, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, authorId=1322954668070023691, language=EN, stringName=Dian ZHANG, firstName=Dian, middleName=null, lastName=ZHANG, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.College of Materials Science and Engineering, Xi'an University of Architecture &Technology, Xi'an 710055, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1322954668225212942, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, authorId=1322954668070023691, language=CN, stringName=张电, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.西安建筑科技大学材料科学与工程学院,西安 710055, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1322954667499598334, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, xref=1., ext=[AuthorCompanyExt(id=1322954667507986943, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, companyId=1322954667499598334, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.College of Materials Science and Engineering, Xi'an University of Architecture &Technology, Xi'an 710055, China), AuthorCompanyExt(id=1322954667520569856, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, companyId=1322954667499598334, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.西安建筑科技大学材料科学与工程学院,西安 710055)])]), Author(id=1322954668300710416, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, orderNo=2, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=null, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1322954668372013586, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, authorId=1322954668300710416, language=EN, stringName=Youzi ZHANG, firstName=Youzi, middleName=null, lastName=ZHANG, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=2, address=2.College of Materials Science and Engineering, Northwestern Polytechnical University, Xi'an 710068, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1322954668460093971, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, authorId=1322954668300710416, language=CN, stringName=张由子, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=2, address=2.西北工业大学材料科学与工程学院,西安 710068, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1322954667600261633, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, xref=2., ext=[AuthorCompanyExt(id=1322954667608650242, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, companyId=1322954667600261633, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=2.College of Materials Science and Engineering, Northwestern Polytechnical University, Xi'an 710068, China), AuthorCompanyExt(id=1322954667650593283, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, companyId=1322954667600261633, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=2.西北工业大学材料科学与工程学院,西安 710068)])]), Author(id=1322954668523008533, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, orderNo=3, firstName=null, middleName=null, lastName=null, nameCn=null, orcid=null, stid=null, country=null, authorPic=null, dead=0, email=null, emailSecond=null, emailThird=null, correspondingAuthor=0, authorType=1, ext={EN=AuthorExt(id=1322954670225895959, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, authorId=1322954668523008533, language=EN, stringName=Yunqin GAO, firstName=Yunqin, middleName=null, lastName=GAO, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.College of Materials Science and Engineering, Xi'an University of Architecture &Technology, Xi'an 710055, China, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null), CN=AuthorExt(id=1322954670330753560, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, authorId=1322954668523008533, language=CN, stringName=高云琴, firstName=null, middleName=null, lastName=null, prefix=null, suffix=null, authorComment=null, nameInitials=null, affiliation=null, department=null, xref=1, address=1.西安建筑科技大学材料科学与工程学院,西安 710055, bio=null, bioImg=null, bioContent=null, aboutCorrespAuthor=null)}, companyList=[AuthorCompany(id=1322954667499598334, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, xref=1., ext=[AuthorCompanyExt(id=1322954667507986943, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, companyId=1322954667499598334, language=EN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.College of Materials Science and Engineering, Xi'an University of Architecture &Technology, Xi'an 710055, China), AuthorCompanyExt(id=1322954667520569856, tenantId=1146029695717560320, journalId=1263187385517883426, articleId=1322608953767350966, companyId=1322954667499598334, language=CN, country=null, province=null, city=null, postcode=null, companyName=null, departmentName=null, remark=1.西安建筑科技大学材料科学与工程学院,西安 710055)])])]
马爱琼1 , 张电1, 张由子2, 高云琴1
作者信息
  • 1.西安建筑科技大学材料科学与工程学院,西安 710055
  • 2.西北工业大学材料科学与工程学院,西安 710068
作者简介:

马爱琼(1970—),女,博士,教授。

Preparation and Photocatalytic Properties under Visible Light Irradiation of Graphite-like Carbon Nitride Nanosheets
Aiqiong MA1 , Dian ZHANG1, Youzi ZHANG2, Yunqin GAO1
Affiliations
  • 1.College of Materials Science and Engineering, Xi'an University of Architecture &Technology, Xi'an 710055, China
  • 2.College of Materials Science and Engineering, Northwestern Polytechnical University, Xi'an 710068, China
  • MA Aiqiong (1970-), female, Ph.D., Professor. E-mail:

出版时间: 2020-01-20 doi: 10.14062/j.issn.0454-5648.20190283
文章导航
收藏切换

以三聚氰胺为原料,采用热缩聚合成法,结合酸、热刻蚀协同改性工艺,制备了二维纳米片层状类石墨氮化碳(g-C3N4)。通过X射线衍射、扫描电镜、透射电镜、红外光谱、X射线光电子能谱、Raman光谱对试样进行了物相组成、显微形貌与分子结构表征。采用BET法分析了试样的比表面积,采用紫外-可见漫反射光谱、Mott-Schottky曲线分析了试样的可见光吸收性能与能带结构。通过可见光降解罗丹明B染料与盐酸四环素溶液,评估了试样的可见光催化性能。结果表明:采用热刻蚀改性剥离时,当三聚氰胺与NH4Cl的摩尔比为5∶4时,所制备的纳米片层状g-C3N4厚度为47 nm,比表面积为22 m2/g,可见光催化降解性能提高显著,相比未经过改性处理的g-C3N4,其降解效率提高了3.4倍;4 h内对盐酸四环素溶液的降解率达到83.2%。

类石墨氮化碳  /  二维纳米层  /  可见光  /  刻蚀  /  光催化剂

Graphitic carbon nitride (g-C3N4) nanosheet was synthesized by a facile fabrication method. Melamine was treated by a thermal polycondensation process. Pure g-C3N4 was treated by acid etching, heat etching and coupling with NH4Cl. The crystalline structure, morphology, specific surface area, band structure and visible absorption of the material were evaluated by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, Fourier transform infrared spectroscopy analysis, X-ray photoelectron spectroscopy, Raman spectroscopy, specific surface area (BET analysis), ultraviolet visible diffuse reflection spectroscopy and Mott-Schottky curve analysis, respectively. The photocatalytic activity was estimated by the degradation of Rhodamine and tetracycline hydrochloride solution under visible light irradiation. The results show that a clear, ordered, 2D nanosheet g-C3N4 structure with a layer thickness of 47 nm is formed, and the maximum specific surface area is a maximum (22 m2/g) when the mole ratio of melamine to NH4Cl is 5∶4. The photocatalytic performance of bulk g-C3N4 is enhanced after treatment. The photocatalytic degradation rate of the sample treated with melamine and NH4Cl at a ratio of 5∶4 is 3.4 times greater than that of untreated g-C3N4. The sample degrades 83.2% tetracycline hydrochloride solution for 4 h.

graphitic carbon nitride  /  two-dimensional nanosheet  /  visible light  /  etching  /  photocatalyst
马爱琼, 张电, 张由子, 高云琴. 纳米片层状类石墨氮化碳的制备及其光催化性能. 硅酸盐学报, 2020 , 48 (1) : 44 -52 . DOI: 10.14062/j.issn.0454-5648.20190283
Aiqiong MA, Dian ZHANG, Youzi ZHANG, Yunqin GAO. Preparation and Photocatalytic Properties under Visible Light Irradiation of Graphite-like Carbon Nitride Nanosheets[J]. Journal of the Chinese Ceramic Society, 2020 , 48 (1) : 44 -52 . DOI: 10.14062/j.issn.0454-5648.20190283
  • 陕西省自然科学基金(2020318029)
参考文献 引证文献
排序方式:
2020年第48卷第1期
PDF下载
18
6
引用本文
BibTeX
文章信息
doi: 10.14062/j.issn.0454-5648.20190283
  • 接收时间:2019-04-28
  • 首发时间:2026-10-29
  • 出版时间:2020-01-20
补充材料
相关文章
文章信息
作者
出版历史
  • 收稿日期:2019-04-28
  • 修回日期:2019-05-30
基金
陕西省自然科学基金(2020318029)
作者信息
    1.西安建筑科技大学材料科学与工程学院,西安 710055
    2.西北工业大学材料科学与工程学院,西安 710068
参考文献
分享链接
https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20190283
分享至
全文二维码

扫描看全文

引用本文
BibTeX
本文的引用情况
2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
关闭全屏