Article(id=1322608946565722438, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322608929100649011, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20190221, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1554652800000, receivedDateStr=2019-04-08, revisedDate=1563206400000, revisedDateStr=2019-07-16, acceptedDate=null, acceptedDateStr=null, onlineDate=1793264145747, onlineDateStr=2026-10-29, pubDate=1579449600000, pubDateStr=2020-01-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793264145747, onlineIssueDateStr=2026-10-29, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793264145747, creator=13701087609, updateTime=1793264145747, updator=13701087609, issue=Issue{id=1322608929100649011, tenantId=1146029695717560320, journalId=1263187385517883426, year='2020', volume='48', issue='1', pageStart='1', pageEnd='146', issueExtLink='null', onlineDate='null', pubDate='1579449600000', pubDateStr='2020-01-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793264141583, creator='13701087609', updateTime=1793276771816, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322661904204542961, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322608929100649011, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322661904208737266, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322608929100649011, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=104, endPage=111, ext={EN=ArticleExt(id=1322608946750271815, articleId=1322608946565722438, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Compositions, Structures and Coloration Mechanism of Quartzite Jade from Taxkorgan, Xinjiang, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

The mineral assemblages, chemical composition, microstructure and spectral characteristics of quartzite jade from Taxkorgan, Xinjiang were investigated by polarized microscopy, electron microprobe (EPMA), laser Raman spectroscopy and ultraviolet-visible-near infrared spectroscopy (UV-Vis-NIR), and the coloration mechanism was discussed as well. The result indicates that quartzite jade from Taxkorgan consists of mainly granoblastic textured α-quartz and different amounts of epidote, dolomite, clinochlore, titanite, K-feldspar, pyrite, chalcopyrite, hematite and goethite. A combination of Fe3+ d-d electron transition and Fe2+—Fe3+ charge transfer in the crystal structure of epidote is the main reason for green color. Yellow and brownish red colors are primarily attributable to nano-micron-sized goethite and hematite within quartz particles or in cracks, and some related peaks in their first-order derivative UV-Vis-NIR spectra are located at 433-434 nm, 512-538 nm and 591 nm, respectively.

, authors=Qian ZHONG1, Zongting LIAO1, 2, 3, Meng LAI1, Di CUI1, Ling LI1, Zhengyu ZHOU1, 2, 3, Lingmin ZHANG1, authorsList=Qian ZHONG, Zongting LIAO, Meng LAI, Di CUI, Ling LI, Zhengyu ZHOU, Lingmin ZHANG, authorCompany=null, correspAuthors=Zongting LIAO, authorNote=

ZHONG Qian (1991-), female, Doctoral candidate. E-mail:

, correspAuthorsNote=
LIAO Zongting (1962-), male, Ph.D., Professor. E-mail:
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选取新疆塔县石英岩玉为研究对象,采用偏光显微镜、电子探针、激光Raman光谱仪和紫外-可见-近红外吸收光谱仪就其矿物组成、化学成分、显微结构及谱学特征进行测试分析,并对颜色成因予以探讨。结果表明:塔县石英岩玉的主要矿物组成为α-石英,具粒状变晶结构,并含有不等量绿帘石、白云石、斜绿泥石、榍石、钾长石及黄铁矿、黄铜矿、赤铁矿、针铁矿等次要矿物。塔县石英岩玉的绿色主要由致色矿物绿帘石晶体结构中Fe3+的d-d电子跃迁和Fe2+—Fe3+电荷转移引起;黄色和褐红色主要归因于石英颗粒间隙或裂隙中的纳-微米级针铁矿和赤铁矿,其紫外-可见-近红外吸收光谱的一阶导数光谱分别具有433~434 nm、512~538 nm和591 nm特征峰。

, authors=钟倩1, 廖宗廷1, 2, 3, 赖萌1, 崔笛1, 李凌1, 周征宇1, 2, 3, 张灵敏1, authorsList=钟倩, 廖宗廷, 赖萌, 崔笛, 李凌, 周征宇, 张灵敏, authorCompany=null, correspAuthors=廖宗廷, authorNote=

钟倩(1991—),女,博士研究生。

, correspAuthorsNote=
廖宗廷(1962—),男,博士,教授。
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新疆塔县石英岩玉的组成、结构与颜色成因
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钟倩 1 , 廖宗廷 1, 2, 3 , 赖萌 1 , 崔笛 1 , 李凌 1 , 周征宇 1, 2, 3 , 张灵敏 1
硅酸盐学报 | 2020,48(1): 104-111
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硅酸盐学报 | 2020 , 48 (1) : 104 -111
新疆塔县石英岩玉的组成、结构与颜色成因
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钟倩1 , 廖宗廷1, 2, 3 , 赖萌1, 崔笛1, 李凌1, 周征宇1, 2, 3, 张灵敏1
作者信息
  • 1.同济大学海洋与地球科学学院,上海 200092
  • 2.同济大学宝石及工艺材料实验室,上海 200092
  • 3.上海宝石及材料工艺工程技术研究中心,上海 200092
通讯作者:
廖宗廷(1962—),男,博士,教授。
作者简介:

钟倩(1991—),女,博士研究生。

Compositions, Structures and Coloration Mechanism of Quartzite Jade from Taxkorgan, Xinjiang
Qian ZHONG1 , Zongting LIAO1, 2, 3 , Meng LAI1, Di CUI1, Ling LI1, Zhengyu ZHOU1, 2, 3, Lingmin ZHANG1
Affiliations
  • 1.School of Ocean and Earth Sciences, Tongji University, Shanghai 200092, China
  • 2.Laboratory of Gem and Technological Materials, Tongji University, Shanghai 200092, China
  • 3,Shanghai Engineering and Technology Research Center of Gem and Material Technology, Shanghai 200092, China
  • Corresponding Author:
    LIAO Zongting (1962-), male, Ph.D., Professor. E-mail:

    ZHONG Qian (1991-), female, Doctoral candidate. E-mail:

出版时间: 2020-01-20 doi: 10.14062/j.issn.0454-5648.20190221
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选取新疆塔县石英岩玉为研究对象,采用偏光显微镜、电子探针、激光Raman光谱仪和紫外-可见-近红外吸收光谱仪就其矿物组成、化学成分、显微结构及谱学特征进行测试分析,并对颜色成因予以探讨。结果表明:塔县石英岩玉的主要矿物组成为α-石英,具粒状变晶结构,并含有不等量绿帘石、白云石、斜绿泥石、榍石、钾长石及黄铁矿、黄铜矿、赤铁矿、针铁矿等次要矿物。塔县石英岩玉的绿色主要由致色矿物绿帘石晶体结构中Fe3+的d-d电子跃迁和Fe2+—Fe3+电荷转移引起;黄色和褐红色主要归因于石英颗粒间隙或裂隙中的纳-微米级针铁矿和赤铁矿,其紫外-可见-近红外吸收光谱的一阶导数光谱分别具有433~434 nm、512~538 nm和591 nm特征峰。

α-石英  /  Raman光谱  /  石英岩玉  /  一阶导数光谱

The mineral assemblages, chemical composition, microstructure and spectral characteristics of quartzite jade from Taxkorgan, Xinjiang were investigated by polarized microscopy, electron microprobe (EPMA), laser Raman spectroscopy and ultraviolet-visible-near infrared spectroscopy (UV-Vis-NIR), and the coloration mechanism was discussed as well. The result indicates that quartzite jade from Taxkorgan consists of mainly granoblastic textured α-quartz and different amounts of epidote, dolomite, clinochlore, titanite, K-feldspar, pyrite, chalcopyrite, hematite and goethite. A combination of Fe3+ d-d electron transition and Fe2+—Fe3+ charge transfer in the crystal structure of epidote is the main reason for green color. Yellow and brownish red colors are primarily attributable to nano-micron-sized goethite and hematite within quartz particles or in cracks, and some related peaks in their first-order derivative UV-Vis-NIR spectra are located at 433-434 nm, 512-538 nm and 591 nm, respectively.

α-quartz  /  Raman spectroscopy  /  quartzite jade  /  first order derivative spectra
钟倩, 廖宗廷, 赖萌, 崔笛, 李凌, 周征宇, 张灵敏. 新疆塔县石英岩玉的组成、结构与颜色成因. 硅酸盐学报, 2020 , 48 (1) : 104 -111 . DOI: 10.14062/j.issn.0454-5648.20190221
Qian ZHONG, Zongting LIAO, Meng LAI, Di CUI, Ling LI, Zhengyu ZHOU, Lingmin ZHANG. Compositions, Structures and Coloration Mechanism of Quartzite Jade from Taxkorgan, Xinjiang[J]. Journal of the Chinese Ceramic Society, 2020 , 48 (1) : 104 -111 . DOI: 10.14062/j.issn.0454-5648.20190221
  • 上海市科委科研计划项目(15DZ2283200; 18DZ2281300)
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2020年第48卷第1期
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doi: 10.14062/j.issn.0454-5648.20190221
  • 接收时间:2019-04-08
  • 首发时间:2026-10-29
  • 出版时间:2020-01-20
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  • 收稿日期:2019-04-08
  • 修回日期:2019-07-16
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上海市科委科研计划项目(15DZ2283200; 18DZ2281300)
作者信息
    1.同济大学海洋与地球科学学院,上海 200092
    2.同济大学宝石及工艺材料实验室,上海 200092
    3.上海宝石及材料工艺工程技术研究中心,上海 200092

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廖宗廷(1962—),男,博士,教授。
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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