Article(id=1322608932200235327, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322608929100649011, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20190197, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1553788800000, receivedDateStr=2019-03-29, revisedDate=1557676800000, revisedDateStr=2019-05-13, acceptedDate=null, acceptedDateStr=null, onlineDate=1793264142321, onlineDateStr=2026-10-29, pubDate=1579449600000, pubDateStr=2020-01-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1793264142321, onlineIssueDateStr=2026-10-29, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1793264142321, creator=13701087609, updateTime=1793264142321, updator=13701087609, issue=Issue{id=1322608929100649011, tenantId=1146029695717560320, journalId=1263187385517883426, year='2020', volume='48', issue='1', pageStart='1', pageEnd='146', issueExtLink='null', onlineDate='null', pubDate='1579449600000', pubDateStr='2020-01-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1793264141583, creator='13701087609', updateTime=1793276771816, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1322661904204542961, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322608929100649011, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1322661904208737266, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1322608929100649011, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=35, endPage=43, ext={EN=ArticleExt(id=1322608932607082816, articleId=1322608932200235327, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Preparation of NaBiF₄:Yb³⁺/Er³⁺ Particles via Solvothermal Method and Enhancement of Upconversion Luminescence by Rb⁺ Ion Doping, columnId=null, journalTitle=Journal of the Chinese Ceramic Society, columnName=null, runingTitle=null, highlight=null, articleAbstract=

NaBiF₄:Yb³⁺/Er³⁺ upconversion nanoparticles were synthesized by a solvothermal method. The effects of reaction temperature and time on the composition, morphology and luminescence properties of NaBiF₄:Yb³⁺/Er³⁺ were investigated. The results show that increasing the reaction temperature and time in the solvothermal reaction properly enhance the crystallinity of NaBiF₄:Yb³⁺/Er³⁺, and improve the upconversion luminescence efficiency. It is easy to produce the bismuth at the temperature of >220 ℃. In addition, the upconversion luminescence intensity of NaBiF₄:Yb³⁺/Er³⁺ can be also enhanced via Rb⁺ ion doping. The green and red emissions of NaBiF₄:Yb³⁺/Er³⁺ doped with 5 mol% Rb⁺ ions increase to 1.73 and 1.5 times, respectively. The temperature sensitivity of the upconversion luminescence was examined. The fluorescence intensity ratio of the samples at 300-500 K was characterized by a fluorescence intensity ratio (I_FIR) technique. It is indicated that the NaBiF₄:Yb³⁺/Er³⁺ samples could have a potential application in the field of temperature sensor.

, authors=Jing CHEN, Youfa WANG, authorsList=Jing CHEN, Youfa WANG, authorCompany=null, correspAuthors=Youfa WANG, authorNote=, correspAuthorsNote=, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1322608933076844865, articleId=1322608932200235327, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=溶剂热法制备NaBiF₄：Yb³⁺/Er³⁺及掺杂Rb⁺离子增强其上转换荧光, columnId=null, journalTitle=硅酸盐学报, columnName=, runingTitle=null, highlight=null, articleAbstract=

采用溶剂热法合成了NaBiF₄：Yb³⁺/Er³⁺上转换发光纳米材料，讨论了在溶剂热阶段反应温度、反应时间对NaBiF₄：Yb³⁺/Er³⁺物相组成、形貌及发光性能的影响。结果表明：在反应阶段，适当增加反应温度、延长反应时间，可以增强NaBiF₄：Yb³⁺/Er³⁺的结晶度，进而提高上转换发光效率，但溶剂热阶段反应温度高于220 ℃时，容易生成金属铋。此外，通过Rb⁺离子掺杂可进一步增强NaBiF₄：Yb³⁺/Er³⁺的上转换发光强度。Rb⁺掺杂量为5%（摩尔分数）时，绿光和红光分别增加至原来的1.73和1.5倍。最后基于荧光强度比（I_FIR）技术，研究了样品在300~500 K温度范围的I_FIR变化曲线，结果表明：NaBiF₄：Yb³⁺/Er³⁺样品在温度传感领域有潜在应用价值。

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CHEN Jing (1994-), female, Master candidate. E-mail: 821160410@qq.com

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陈静（1994—），女，硕士研究生。

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陈静（1994—），女，硕士研究生。

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