硅酸盐学报

钛酸钡基压电材料的压电催化研究进展

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梁乾森 ¹ , 谢兵 ¹ , 高文鹏 ¹ , 刘智勇 ¹ , 姜胜林 ² , 张海波 ³

硅酸盐学报 | 综合评述 2026,54(3): 1097-1116

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硅酸盐学报 |综合评述 2026 , 54 (3) : 1097 -1116

钛酸钡基压电材料的压电催化研究进展

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梁乾森¹, 谢兵¹, 高文鹏¹, 刘智勇¹, 姜胜林², 张海波³

作者信息

^1．南昌航空大学动力与能源学院，南昌 330063

^2．华中科技大学集成电路学院，武汉 430074

^3．华中科技大学材料科学与工程学院，武汉 430074

通讯作者:

谢兵（1983—），男，博士，教授。

作者简介:

梁乾森（1998—），男，硕士研究生。

Development on Piezoelectric Catalysis of Barium Titanate-Based Materials

Qiansen LIANG¹, Bing XIE¹, Wenpeng GAO¹, Zhiyong LIU¹, Shenglin JIANG², Haibo ZHANG³

Affiliations

^1.School of Power and Energy, Nanchang Hangkong University, Nanchang 330063, Jiangxi, China

^2.School of Integrated Circuits, Huazhong University of Science and Technology, Wuhan 430074, China

^3.School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China

Corresponding Author:

XIE Bing(1983-), male, Ph.D., Professor. E-mail: xieb@nchu.edu.cn

LIANG Qiansen (1998-), male, Master candidate. E-mail: liangqs518@163.com

出版时间: 2026-03-20 doi: 10.14062/j.issn.0454-5648.20250161

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摘要

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随着社会经济的快速发展，能源短缺和环境污染等问题日益凸显，压电催化技术得以发展。钛酸钡（BaTiO₃）因其优异的压电性能、较低的制备成本与良好的机械稳定性，被广泛应用于压电催化领域。当前，BaTiO₃基压电材料的应用研究主要集中在降解有机污染物、分解H₂O制H₂、生产H₂O₂以及医学应用等方面。随着研究的深入，BaTiO₃基压电材料在压电催化应用领域的研究也逐渐拓展到了CO₂还原、氮气（N₂）固定、重金属离子去除等新兴领域。本文围绕BaTiO₃基压电材料，首先讨论其压电催化机理，然后介绍其能量来源。随后，将集中探讨BaTiO₃在压电催化领域的众多应用，系统回顾其在污染物降解（如有机染料和抗生素降解）、能源制备（如H₂O₂、H₂制备）、CO₂还原、固氮以及医学等多个领域的重要进展，深入分析BaTiO₃基压电催化剂在应用中面临的挑战，并探讨潜在的优化策略，以推动其在压电催化中的进一步发展和应用。

关键词

钛酸钡 / 压电催化 / 能量来源

Abstract

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With the rapid development of socio-economic structures, energy shortages and environmental pollution increasingly emerge as global challenges, creating opportunities for the advancement of piezoelectric catalytic technology. Barium titanate (BaTiO₃) is extensively utilized in piezoelectric catalysis due to its low cost, robust mechanical stability, and exceptional piezoelectric properties. The existing research on BaTiO₃-based piezoelectric materials primarily concentrates on their application in the degradation of organic pollutants, water decomposition for hydrogen production, hydrogen peroxide synthesis, and various medical applications. As research deepens, the scope of BaTiO₃-based piezoelectric materials in piezoelectric catalysis expands to some areas such as CO₂ reduction, nitrogen (N₂) fixation, and heavy metal ion removal. This review focuses on BaTiO₃-based piezoelectric materials, initially detailing their piezoelectric catalytic mechanisms and briefly outlining their energy sources. This review also represents some applications of BaTiO₃ in piezoelectric catalysis, highlighting significant advancements in diverse areas such as pollutant degradation (i.e., organic dyes and antibiotics), energy production (i.e., hydrogen peroxide and hydrogen), CO₂ reduction, nitrogen fixation, and medical applications. Furthermore, this review critically examines some challenges faced by BaTiO₃-based piezoelectric catalysts in practical applications and discusses potential optimization strategies to facilitate their development and application in the field of piezoelectric catalysis.

Summary and prospects

BaTiO₃ is widely investigated as a piezoelectric catalyst due to its high safety, low preparation cost, stability, and environmental friendliness. This review provides a comprehensive review of the catalytic mechanisms of BaTiO₃-based piezoelectric materials, their energy sources, and recent advancements in the field of piezoelectric catalysis. The existing research into the applications of BaTiO₃-based materials primarily focuses on organic pollutant degradation, hydrogen production via water splitting, hydrogen peroxide synthesis, and biomedical uses. However, most studies remain in lab-scale and do not deal with industrial applications. The practical applications of BaTiO₃-based materials face some challenges despite having superior piezoelectric catalytic performance in various fields. Firstly, in practical applications, BaTiO₃ suffers from a low carrier concentration and a rapid recombination rate, restricting its catalytic efficiency. Secondly, there is a lack of comprehensive understanding of the piezoelectric catalytic mechanisms of BaTiO₃. The band theory and shielding charge effects are used to explain these mechanisms, but they do not fully elucidate all catalytic phenomena. The existing research shows that the piezoelectric effect of BaTiO₃ can enhance reactant conversion. However, the specific reaction pathways and intermediate formation mechanisms require a further investigation. In addition, the stability and reusability of BaTiO₃-based piezoelectric catalytic materials in practical applications need a urgent attention. To address these challenges, future research should focus on the following aspects:

1) Development of new material systems and optimization of modification strategies: Moving beyond conventional modification frameworks and exploring composition design methods utilizing machine learning can develop composite structures with gradient piezoelectric characteristics. A photopiezoelectric dual-drive catalytic system can be created to achieve a synergistic enhancement in carrier generation and separation via coupling plasmon resonance effects with piezoelectric responses. Interface engineering of two-dimensional materials, such as MXene, can offer new insights for constructing efficient charge transfer channels.

2) In-depth study of catalytic mechanisms: A multi-scale characterization platform is established via integrating in-situ transmission electron microscopy with ultrafast spectroscopy to monitor interfacial charge dynamics induced by piezoelectric potentials in real-time. Dynamic density functional theory (DFT) calculation methods are developed to elucidate the nonlinear coupling mechanisms among stress, potential, and catalytic activity, especially focusing on the formation and conversion pathways of transient intermediate states.

3) Expansion and optimization of practical applications: BaTiO₃-based piezoelectric catalysts in more complex real-world environmental systems, such as industrial wastewater treatment, are implemented to assess their performance and limitations, thereby promoting the industrial application of piezoelectric catalysis technology. In addition, material designs with self-healing capabilities are also explored to enhance long-term stability and recyclability, preventing secondary pollution.

Key words

barium titanate / piezoelectric catalysis / energy source

引用本文

梁乾森, 谢兵, 高文鹏, 刘智勇, 姜胜林, 张海波. 钛酸钡基压电材料的压电催化研究进展. 硅酸盐学报, 2026 , 54 (3) : 1097 -1116 . DOI: 10.14062/j.issn.0454-5648.20250161

Qiansen LIANG, Bing XIE, Wenpeng GAO, Zhiyong LIU, Shenglin JIANG, Haibo ZHANG. Development on Piezoelectric Catalysis of Barium Titanate-Based Materials[J]. Journal of the Chinese Ceramic Society, 2026 , 54 (3) : 1097 -1116 . DOI: 10.14062/j.issn.0454-5648.20250161

基金

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国家自然科学基金(52462018)
江西省杰出青年基金(20224ACB214007)

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2026年第54卷第3期

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文章信息

doi: 10.14062/j.issn.0454-5648.20250161

接收时间：2025-03-11
首发时间：2026-10-27
出版时间：2026-03-20

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出版历史

收稿日期：2025-03-11
修回日期：2025-05-15

基金

国家自然科学基金(52462018)

江西省杰出青年基金(20224ACB214007)

作者信息

^1．南昌航空大学动力与能源学院，南昌 330063

^2．华中科技大学集成电路学院，武汉 430074

^3．华中科技大学材料科学与工程学院，武汉 430074

通讯作者:

谢兵（1983—），男，博士，教授。

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https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20250161

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2种不同金属材料的力学参数

科 Family	属数 Number of genus	种数 Number of species	占总种数比例 Percentage of total species (%)	属 Genus	种数 Number of species	占总种数比例 Percentage of total species (%)
鹅膏菌科Amanitaceae	2	11	5.26	鹅膏菌属 Amanita	10	4.78
小菇科 Mycenaceae	2	12	5.74	丝盖伞属 Inocybe	5	2.39
多孔菌科 Polyporaceae	8	14	6.70	蜡蘑属 Laccaria	5	2.39
红菇科 Russulaceae	3	23	11.00	小皮伞属 Marasmius	6	2.87
				小菇属 Mycena	11	5.26
				光柄菇属 Pluteus	5	2.39
				红菇属 Russula	17	8.13
				栓菌属 Trametes	5	2.39

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