Article(id=1320090189037425638, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1320090155155829136, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20240568, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1724860800000, receivedDateStr=2024-08-29, revisedDate=1728316800000, revisedDateStr=2024-10-08, acceptedDate=null, acceptedDateStr=null, onlineDate=1792663627156, onlineDateStr=2026-10-22, pubDate=1742400000000, pubDateStr=2025-03-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792663627156, onlineIssueDateStr=2026-10-22, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792663627156, creator=13701087609, updateTime=1792663627156, updator=13701087609, issue=Issue{id=1320090155155829136, tenantId=1146029695717560320, journalId=1263187385517883426, year='2025', volume='53', issue='3', pageStart='495', pageEnd='732', issueExtLink='null', onlineDate='null', pubDate='1742400000000', pubDateStr='2025-03-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1792663619078, creator='13701087609', updateTime=1792663815055, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1320090977214255163, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1320090155155829136, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1320090977214255164, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1320090155155829136, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=718, endPage=732, ext={EN=ArticleExt(id=1320090189213586407, articleId=1320090189037425638, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=High-Temperature Insulating Materials Tolerant to Water: Preparation, Properties and Applications, columnId=1263922772401635899, journalTitle=Journal of the Chinese Ceramic Society, columnName=Review, runingTitle=null, highlight=null, articleAbstract=

Novel high-temperature thermal insulation materials (i.e., ceramic fiber insulation materials and aerogels) become research hotspots due to their low density, low thermal conductivity, and superior thermal insulation properties. Ceramic thermal insulation materials can be classified into two categories, i.e., rigid ceramic thermal insulation tiles and flexible ceramic fiber thermal insulation blankets. Ceramic thermal insulation materials serve as one of the primary thermal protection materials on the surfaces of aerospace equipment due to their superior characteristics such as porosity, low thermal conductivity, high-temperature stability, and excellent mechanical properties. Aerogel is a lightweight material with a nano-porous structure. At atmospheric pressure, silica aerogel has the lowest thermal conductivity among any other insulators. In various applications, aerogel increasingly replaces more conventional materials. The skeleton and porous morphology of aerogel can be controlled in a nanoscale to provide various remarkable physical properties, such as ultra-low density, intense adsorption capacity, ultrahigh specific surface area, and ultralow thermal conductivity.

However, the most existing thermal insulation materials are generally isotropic and hydrophilic, significantly limiting their applications in humid environments. The widely used high-temperature thermal insulation materials are typically porous structures, and their nanopores and high specific surface areas contribute to reducing thermal conductivity through a gas-phase heat transfer, thus having superior thermal insulation performance. Nevertheless, their thermal conductivity increases, and this trend intensifies with increasing ambient humidity when porous materials absorb moisture in humid environments, leading to a degraded thermal insulation performance. Moreover, in a direct contact with water, the nanoporous structure of the materials can collapse under capillary forces, causing a significant increase in thermal conductivity.

This review comprehensively represents the implementation methods and performance aspects of water resistance for three commonly used high-temperature thermal insulation materials, i.e., ceramic fiber thermal insulation tiles, ceramic fiber thermal insulation blankets, and silica aerogel. The ceramic fiber thermal insulation tiles enhance their high-temperature stability and water resistance through the application of high-emissivity coatings. The ceramic fiber thermal insulation blankets achieve a water resistance via electrostatic spinning and surface modification techniques. For silica aerogel thermal insulation materials, their water resistance is improved via modifying their surfaces with organic hydrophobic groups and adopting hydrothermal-assisted drying methods. This review also identifies some challenges for the improvement of the existing materials and provides an outlook on the future development directions.

Summary and Prospects

This review represents the research advancements in high-temperature insulation materials (i.e., water-resistant ceramic fiber insulation tiles, insulation blankets, and aerogels). Some strategies for enhancing their water resistance, such as the application of high-emissivity coatings, chemical vapor deposition, and modification with organic hydrophobic groups, are described. These materials possess a significant application potential at multiple fields due to their low density, robust water resistance, and efficient thermal insulation properties. Nevertheless, some challenges persist in maintaining water resistance at high temperatures, simplifying manufacturing processes, and developing novel materials. A future research should prioritize enhancing the water resistance of materials at elevated temperatures, streamlining production processes, and innovating novel materials. In addition, the stability and durability of these materials in practical applications also need to be further investigated to facilitate the technological advancements and industrial upgrading.

, authors=Yang JIAN, Yonggang JIANG, Junzong FENG, Liangjun LI, Yijie HU, Jian FENG, authorsList=Yang JIAN, Yonggang JIANG, Junzong FENG, Liangjun LI, Yijie HU, Jian FENG, authorCompany=null, correspAuthors=Yonggang JIANG, authorNote=

JIAN Yang (2000-), female, Master candidate. E-mail:

, correspAuthorsNote=
JIANG Yonggang (1979-), male, Ph.D., Associate Professor. E-mail:
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高温隔热材料兼具耐高温、低密度和低热导等性能,已广泛应用于航空航天、石油化工等领域,然而,高孔隙率使其极易吸水而导致隔热性能下降,因此,耐水高温隔热材料成为当前研究热点。本文综述了陶瓷纤维隔热瓦、陶瓷纤维隔热毡、氧化硅气凝胶3类常见高温隔热材料的耐水性能实现方法:陶瓷纤维瓦大多采用高发射涂层增强高温稳定性与防水性;陶瓷纤维毡通过静电纺丝和表面改性实现耐水性能;氧化硅气凝胶则通过有机疏水基团改性和水热辅助干燥等方法提升耐水性。本文还指出现阶段耐水材料面临的挑战,如开发更高温下使用的材料、简化耐水工艺、探索新型耐水隔热材料体系、进行材料智能设计和创新等,并展望了未来发展方向。兼具耐水性的高温隔热材料将在更多场景中发挥优势,实现更广泛应用。

, authors=简洋, 姜勇刚, 冯军宗, 李良军, 胡艺洁, 冯坚, authorsList=简洋, 姜勇刚, 冯军宗, 李良军, 胡艺洁, 冯坚, authorCompany=null, correspAuthors=姜勇刚, authorNote=

简洋(2000—),女,硕士研究生。

, correspAuthorsNote=
姜勇刚(1979—),男,博士,副研究员。
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耐水高温隔热材料的制备、性能及应用
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简洋 , 姜勇刚 , 冯军宗 , 李良军 , 胡艺洁 , 冯坚
硅酸盐学报 | 综合评述 2025,53(3): 718-732
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耐水高温隔热材料的制备、性能及应用
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简洋 , 姜勇刚 , 冯军宗, 李良军, 胡艺洁, 冯坚
作者信息
  • 国防科技大学空天科学学院,新型陶瓷纤维及其复合材料重点实验室,长沙 410073
通讯作者:
姜勇刚(1979—),男,博士,副研究员。
作者简介:

简洋(2000—),女,硕士研究生。

High-Temperature Insulating Materials Tolerant to Water: Preparation, Properties and Applications
Yang JIAN , Yonggang JIANG , Junzong FENG, Liangjun LI, Yijie HU, Jian FENG
Affiliations
  • Science and Technology on Advanced Ceramic Fibers and Composites Laboratory, College of Aero-space Science and Engineering, National University of Defense Technology, Changsha 410073, China
  • Corresponding Author:
    JIANG Yonggang (1979-), male, Ph.D., Associate Professor. E-mail:

    JIAN Yang (2000-), female, Master candidate. E-mail:

出版时间: 2025-03-20 doi: 10.14062/j.issn.0454-5648.20240568
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高温隔热材料兼具耐高温、低密度和低热导等性能,已广泛应用于航空航天、石油化工等领域,然而,高孔隙率使其极易吸水而导致隔热性能下降,因此,耐水高温隔热材料成为当前研究热点。本文综述了陶瓷纤维隔热瓦、陶瓷纤维隔热毡、氧化硅气凝胶3类常见高温隔热材料的耐水性能实现方法:陶瓷纤维瓦大多采用高发射涂层增强高温稳定性与防水性;陶瓷纤维毡通过静电纺丝和表面改性实现耐水性能;氧化硅气凝胶则通过有机疏水基团改性和水热辅助干燥等方法提升耐水性。本文还指出现阶段耐水材料面临的挑战,如开发更高温下使用的材料、简化耐水工艺、探索新型耐水隔热材料体系、进行材料智能设计和创新等,并展望了未来发展方向。兼具耐水性的高温隔热材料将在更多场景中发挥优势,实现更广泛应用。

陶瓷纤维隔热瓦  /  陶瓷纤维隔热毡  /  气凝胶隔热材料  /  耐水  /  隔热

Novel high-temperature thermal insulation materials (i.e., ceramic fiber insulation materials and aerogels) become research hotspots due to their low density, low thermal conductivity, and superior thermal insulation properties. Ceramic thermal insulation materials can be classified into two categories, i.e., rigid ceramic thermal insulation tiles and flexible ceramic fiber thermal insulation blankets. Ceramic thermal insulation materials serve as one of the primary thermal protection materials on the surfaces of aerospace equipment due to their superior characteristics such as porosity, low thermal conductivity, high-temperature stability, and excellent mechanical properties. Aerogel is a lightweight material with a nano-porous structure. At atmospheric pressure, silica aerogel has the lowest thermal conductivity among any other insulators. In various applications, aerogel increasingly replaces more conventional materials. The skeleton and porous morphology of aerogel can be controlled in a nanoscale to provide various remarkable physical properties, such as ultra-low density, intense adsorption capacity, ultrahigh specific surface area, and ultralow thermal conductivity.

However, the most existing thermal insulation materials are generally isotropic and hydrophilic, significantly limiting their applications in humid environments. The widely used high-temperature thermal insulation materials are typically porous structures, and their nanopores and high specific surface areas contribute to reducing thermal conductivity through a gas-phase heat transfer, thus having superior thermal insulation performance. Nevertheless, their thermal conductivity increases, and this trend intensifies with increasing ambient humidity when porous materials absorb moisture in humid environments, leading to a degraded thermal insulation performance. Moreover, in a direct contact with water, the nanoporous structure of the materials can collapse under capillary forces, causing a significant increase in thermal conductivity.

This review comprehensively represents the implementation methods and performance aspects of water resistance for three commonly used high-temperature thermal insulation materials, i.e., ceramic fiber thermal insulation tiles, ceramic fiber thermal insulation blankets, and silica aerogel. The ceramic fiber thermal insulation tiles enhance their high-temperature stability and water resistance through the application of high-emissivity coatings. The ceramic fiber thermal insulation blankets achieve a water resistance via electrostatic spinning and surface modification techniques. For silica aerogel thermal insulation materials, their water resistance is improved via modifying their surfaces with organic hydrophobic groups and adopting hydrothermal-assisted drying methods. This review also identifies some challenges for the improvement of the existing materials and provides an outlook on the future development directions.

Summary and Prospects

This review represents the research advancements in high-temperature insulation materials (i.e., water-resistant ceramic fiber insulation tiles, insulation blankets, and aerogels). Some strategies for enhancing their water resistance, such as the application of high-emissivity coatings, chemical vapor deposition, and modification with organic hydrophobic groups, are described. These materials possess a significant application potential at multiple fields due to their low density, robust water resistance, and efficient thermal insulation properties. Nevertheless, some challenges persist in maintaining water resistance at high temperatures, simplifying manufacturing processes, and developing novel materials. A future research should prioritize enhancing the water resistance of materials at elevated temperatures, streamlining production processes, and innovating novel materials. In addition, the stability and durability of these materials in practical applications also need to be further investigated to facilitate the technological advancements and industrial upgrading.

water-tolerance  /  thermal insulation  /  ceramic tile  /  ceramic blankets  /  aerogel insulation material
简洋, 姜勇刚, 冯军宗, 李良军, 胡艺洁, 冯坚. 耐水高温隔热材料的制备、性能及应用. 硅酸盐学报, 2025 , 53 (3) : 718 -732 . DOI: 10.14062/j.issn.0454-5648.20240568
Yang JIAN, Yonggang JIANG, Junzong FENG, Liangjun LI, Yijie HU, Jian FENG. High-Temperature Insulating Materials Tolerant to Water: Preparation, Properties and Applications[J]. Journal of the Chinese Ceramic Society, 2025 , 53 (3) : 718 -732 . DOI: 10.14062/j.issn.0454-5648.20240568
  • 湖南省重点研发计划项目(2022GK2027)
  • 湖南省自然科学基金(2023JJ30632)
  • 国防科技重点实验室基金(6142907230101)
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doi: 10.14062/j.issn.0454-5648.20240568
  • 接收时间:2024-08-29
  • 首发时间:2026-10-22
  • 出版时间:2025-03-20
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  • 收稿日期:2024-08-29
  • 修回日期:2024-10-08
基金
湖南省重点研发计划项目(2022GK2027)
湖南省自然科学基金(2023JJ30632)
国防科技重点实验室基金(6142907230101)
作者信息
    国防科技大学空天科学学院,新型陶瓷纤维及其复合材料重点实验室,长沙 410073

通讯作者:

姜勇刚(1979—),男,博士,副研究员。
参考文献
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2种不同金属材料的力学参数
科
Family
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Number of
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种数
Number of
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占总种数比例
Percentage of
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属
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Number of
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Percentage of total
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鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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