Article(id=1319987163429716327, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319987091220574321, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20210606, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1627833600000, receivedDateStr=2021-08-02, revisedDate=1631894400000, revisedDateStr=2021-09-18, acceptedDate=null, acceptedDateStr=null, onlineDate=1792639063937, onlineDateStr=2026-10-22, pubDate=1642608000000, pubDateStr=2022-01-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792639063937, onlineIssueDateStr=2026-10-22, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792639063937, creator=13701087609, updateTime=1792639063937, updator=13701087609, issue=Issue{id=1319987091220574321, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='1', pageStart='1', pageEnd='276', issueExtLink='null', onlineDate='null', pubDate='1642608000000', pubDateStr='2022-01-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792639046721, creator='13701087609', updateTime=1792639238958, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319987897588105574, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319987091220574321, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319987897588105575, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319987091220574321, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=62, endPage=69, ext={EN=ArticleExt(id=1319987165229072744, articleId=1319987163429716327, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Preparation and Performance of Ag Modified Co₃O₄ Catalyst in Li-O₂ Battery, columnId=1321891465115062324, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Issue on Electrochemical Energy Storage Materials—Research Articles, runingTitle=null, highlight=null, articleAbstract=

A hammer-like Co₃O₄ was firstly prepared by using metal-organic framework-74 as a template, and then compounded with elemental Ag to fabricate a highly active catalyst with an improved electronic conductivity. The Li-O₂ battery with this prepared catalyst has a specific discharge capacity of 13 945 mA·h/g at a current density of 100 mA/g. Even at a high current density of 1 000 mA/g, the battery can still maintain a specific discharge capacity of 4 476.3 mA·h/g, indicating that it has an excellent rate performance. Also, the cycle performance is greatly improved. For the limited specific capacity of 1 000 mA·h/g at the current density of 500 mA/g, the battery with Ag/Co₃O₄ catalyst can be used for 195 cycles, while that with Co₃O₄ catalyst can be used for only 42 cycles.

, authors=Yajun ZHAO, Xiaoming WANG, Hao LUO, Dawei ZHANG, authorsList=Yajun ZHAO, Xiaoming WANG, Hao LUO, Dawei ZHANG, authorCompany=null, correspAuthors=Dawei ZHANG, authorNote=, correspAuthorsNote=, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319987165556228457, articleId=1319987163429716327, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=单质Ag修饰Co₃O₄的高活性Li-O₂电池催化剂的制备及性能, columnId=1321891465291223093, journalTitle=硅酸盐学报, columnName=电化学储能材料专题—研究论文, runingTitle=null, highlight=null, articleAbstract=

以金属有机框架-74为模板制备了仿锤体状Co₃O₄，然后与单质Ag复合，通过界面工程提高了材料电导率，制备出Li-O₂电池的高活性催化剂Ag/Co₃O₄。在100 mA/g电流密度，使用Ag/Co₃O₄催化剂的Li-O₂电池的放电比容量达到了13 945 mA·h/g，即使在1 000 mA/g高电流密度，依然可以保持4 476.3 mA·h/g的放电比容量，证明其具有出色的倍率性能。同时，循环性能也得到了大幅提高，在电流密度为500 mA/g，限制比容量为1 000 mA·h/g，使用Ag/Co₃O₄催化剂的电池可以稳定循环195圈，而使用Co₃O₄催化剂的电池只能循环42圈。

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ZHAO Yajun (1992-), female, Doctoral candidate. E-mail: zyj251264@163.com

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ZHAO Yajun (1992-), female, Doctoral candidate. E-mail: zyj251264@163.com

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赵亚君（1992—），女，博士研究生。

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赵亚君（1992—），女，博士研究生。

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