Article(id=1319987109570654563, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319987091220574321, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20210375, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1620748800000, receivedDateStr=2021-05-12, revisedDate=1625068800000, revisedDateStr=2021-07-01, acceptedDate=null, acceptedDateStr=null, onlineDate=1792639051095, onlineDateStr=2026-10-22, pubDate=1642608000000, pubDateStr=2022-01-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792639051095, onlineIssueDateStr=2026-10-22, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792639051095, creator=13701087609, updateTime=1792639051095, updator=13701087609, issue=Issue{id=1319987091220574321, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='1', pageStart='1', pageEnd='276', issueExtLink='null', onlineDate='null', pubDate='1642608000000', pubDateStr='2022-01-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792639046721, creator='13701087609', updateTime=1792639238958, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319987897588105574, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319987091220574321, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319987897588105575, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319987091220574321, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=204, endPage=211, ext={EN=ArticleExt(id=1319987109759398244, articleId=1319987109570654563, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=FexMo1-xS2 as Anode for High-Performance Sodium Ion Batteries, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

FexMo1-xS2 with an expanded interlayer spacing of 0.75 nm was prepared via a simple solvothermal method. The larger interlayer spacing enhances the rate of Na+ diffusion during initial cycle. FexMo1-xS2 as an anode for sodium ion batteries exhibits a high capacity of 285 mA·h/g at 0.1 A/g after 100 cycles and an excellent rate capability of 178 mA·h/g at 5 A/g. The fresh and cycled electrodes were characterized by in-situ X-ray photoelectric spectroscopy and transmission electronic microscopy to investigate electrochemical reaction mechanism of FexMo1-xS2 during cycling. The results indicate that the irreversible conversion reaction of FexMo1-xS2 with Na+ results in the formation of main products of Fe-Mo alloy and S.

, authors=Jing LI, Huachao TAO, Xuelin YANG, authorsList=Jing LI, Huachao TAO, Xuelin YANG, authorCompany=null, correspAuthors=Huachao TAO, Xuelin YANG, authorNote=

LI Jing (1995-), female, Master candidate. E-mail:

, correspAuthorsNote=
TAO Huachao (1984-), male, Ph.D., Associate Professor; E-mail: (TAO Huachao)
YANG Xuelin (1973-), male, Ph.D., Professor. (YANG Xuelin)
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通过一步溶剂热法制备了层间距0.75 nm的三元FexMo1-xS2,扩大的层间距改善了Na+首次循环过程中扩散速率。FexMo1-xS2作为钠离子电池负极在0.1 A/g电流密度循环100圈后可逆容量为285 mA·h/g,同时显示出较好倍率性能(5 A/g电流密度下容量为178 mA·h/g)。通过X射线光电子能谱仪和透射电子显微镜对循环前后电极材料进行了表征,分析FexMo1-xS2在循环过程中的电化学反应机理。结果表明:FexMo1-xS2与Na+发生不可逆转换反应,多次循环后生成Fe-Mo合金和S。

, authors=李静, 陶华超, 杨学林, authorsList=李静, 陶华超, 杨学林, authorCompany=null, correspAuthors=陶华超, 杨学林, authorNote=

李静(1995—),女,硕士研究生。

, correspAuthorsNote=
陶华超(1984—),男,博士,副教授;
杨学林(1973—),男,博士,教授。
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高性能钠离子电池负极材料FexMo1-xS2
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李静 , 陶华超 , 杨学林
硅酸盐学报 | 研究论文 2022,50(1): 204-211
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硅酸盐学报 |研究论文 2022 , 50 (1) : 204 -211
高性能钠离子电池负极材料FexMo1-xS2
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李静 , 陶华超 , 杨学林
作者信息
  • 三峡大学电气与新能源学院,湖北省微电网创新协同中心,湖北 宜昌 443002
通讯作者:
陶华超(1984—),男,博士,副教授;
杨学林(1973—),男,博士,教授。
作者简介:

李静(1995—),女,硕士研究生。

FexMo1-xS2 as Anode for High-Performance Sodium Ion Batteries
Jing LI , Huachao TAO , Xuelin YANG
Affiliations
  • College of Electrical Engineering and New Energy, Hubei Provincial Collaborative Innovation Center for New Energy Microgrid, China Three Gorges University, Yichang 443002, Hubei, China
  • Corresponding Author:
    TAO Huachao (1984-), male, Ph.D., Associate Professor; E-mail: (TAO Huachao)
    YANG Xuelin (1973-), male, Ph.D., Professor. (YANG Xuelin)

    LI Jing (1995-), female, Master candidate. E-mail:

出版时间: 2022-01-20 doi: 10.14062/j.issn.0454-5648.20210375
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通过一步溶剂热法制备了层间距0.75 nm的三元FexMo1-xS2,扩大的层间距改善了Na+首次循环过程中扩散速率。FexMo1-xS2作为钠离子电池负极在0.1 A/g电流密度循环100圈后可逆容量为285 mA·h/g,同时显示出较好倍率性能(5 A/g电流密度下容量为178 mA·h/g)。通过X射线光电子能谱仪和透射电子显微镜对循环前后电极材料进行了表征,分析FexMo1-xS2在循环过程中的电化学反应机理。结果表明:FexMo1-xS2与Na+发生不可逆转换反应,多次循环后生成Fe-Mo合金和S。

钠离子电池  /  负极  /  二硫化钼  /  反应机理  /  不可逆反应

FexMo1-xS2 with an expanded interlayer spacing of 0.75 nm was prepared via a simple solvothermal method. The larger interlayer spacing enhances the rate of Na+ diffusion during initial cycle. FexMo1-xS2 as an anode for sodium ion batteries exhibits a high capacity of 285 mA·h/g at 0.1 A/g after 100 cycles and an excellent rate capability of 178 mA·h/g at 5 A/g. The fresh and cycled electrodes were characterized by in-situ X-ray photoelectric spectroscopy and transmission electronic microscopy to investigate electrochemical reaction mechanism of FexMo1-xS2 during cycling. The results indicate that the irreversible conversion reaction of FexMo1-xS2 with Na+ results in the formation of main products of Fe-Mo alloy and S.

sodium ion battery  /  anode  /  molybdenum sulfide  /  reaction mechanism  /  irreversible reaction
李静, 陶华超, 杨学林. 高性能钠离子电池负极材料FexMo1-xS2. 硅酸盐学报, 2022 , 50 (1) : 204 -211 . DOI: 10.14062/j.issn.0454-5648.20210375
Jing LI, Huachao TAO, Xuelin YANG. FexMo1-xS2 as Anode for High-Performance Sodium Ion Batteries[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (1) : 204 -211 . DOI: 10.14062/j.issn.0454-5648.20210375
  • 国家自然科学基金(22179071; 51772169)
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doi: 10.14062/j.issn.0454-5648.20210375
  • 接收时间:2021-05-12
  • 首发时间:2026-10-22
  • 出版时间:2022-01-20
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  • 收稿日期:2021-05-12
  • 修回日期:2021-07-01
基金
国家自然科学基金(22179071; 51772169)
作者信息
    三峡大学电气与新能源学院,湖北省微电网创新协同中心,湖北 宜昌 443002

通讯作者:

陶华超(1984—),男,博士,副教授;
杨学林(1973—),男,博士,教授。
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2种不同金属材料的力学参数
科
Family
属数
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genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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