Article(id=1319987102184489734, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319987055371858691, articleNumber=null, orderNo=null, doi=null, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1633276800000, receivedDateStr=2021-10-04, revisedDate=1635609600000, revisedDateStr=2021-10-31, acceptedDate=null, acceptedDateStr=null, onlineDate=1792639049335, onlineDateStr=2026-10-22, pubDate=1645286400000, pubDateStr=2022-02-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792639049335, onlineIssueDateStr=2026-10-22, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792639049335, creator=13701087609, updateTime=1792639049335, updator=13701087609, issue=Issue{id=1319987055371858691, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='2', pageStart='277', pageEnd='554', issueExtLink='null', onlineDate='null', pubDate='1645286400000', pubDateStr='2022-02-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792639038174, creator='13701087609', updateTime=1792639254308, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319987961958089069, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319987055371858691, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319987961958089070, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319987055371858691, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=285, endPage=289, ext={EN=ArticleExt(id=1319987102394204935, articleId=1319987102184489734, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=High-Frequency Electromagnetic Properties of Layered Sulfur Doped Black Phosphorus Crystals, columnId=1321891764701615020, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Issue on Inerim Achievements of Key Program of National Natural Science Foundation of China—Research Articles, runingTitle=null, highlight=null, articleAbstract=

Microwave absorbing materials are widely used in military and civil fields. The current research focusses on novel microwave absorbing materials with intense absorption, wide bandwidth, light weight and thin thickness. Black phosphorus (BP) and sulfur-doped black phosphorus (BP-S) crystals were prepared at a high temperature and a high pressure, and then BP and BP-S nanosheets were obtained via liquid-phase exfoliation. Compared with BP, the complex permittivity and εr″/εr′ of BP-S are enhanced at 1.0-16.5 GHz. The minimum reflection loss (RL) reaches -41.4 dB at 9.6 GHz, and the RL exceeding -10 dB in a frequency range of 7.0 to 16.1 GHz is obtained for the absorber thickness of 1.0-2.0 mm. The minimum RL frequency dependence of the absorber thickness for BP-S comply with a λ/4 matching model. BP-S has broad application prospects as a high-performance microwave absorbing material.

, authors=Bochong WANG1, 2, Chunxue HAO1, Yukai CHANG1, Congpu MOU1, 2, Fusheng WEN1, Zhongyuan LIU1, authorsList=Bochong WANG, Chunxue HAO, Yukai CHANG, Congpu MOU, Fusheng WEN, Zhongyuan LIU, authorCompany=null, correspAuthors=Zhongyuan LIU, authorNote=

WANG Bochong (1985-), male, Ph.D., Associate Professor. E-mail:

, correspAuthorsNote=
LIU Zhongyuan (1965-), male, Ph.D., Professor. E-mail:
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电子设备的增多使得吸波材料在军事和民用领域具有广泛的应用。当前研究的重点在于制备吸收强、频带宽、质量轻、厚度薄的新型吸波材料。利用高温高压成功合成黑磷(BP)和硫掺杂黑磷(BP-S)晶体,并使用液相剥离的方法制备BP和BP-S纳米片。高频电磁参数测量发现相较于BP,硫元素的掺杂使得BP-S复数介电常数和介电损耗正切值在频率1.0~16.5 GHz情况下明显提高。BP-S在9.6 GHz处最小反射损耗可达到-41.1 dB;当厚度在1.0~2.0 mm范围内变化时,小于-10 dB的反射损耗频率范围为7.0~16.1 GHz。BP-S的最小反射损耗频率点与材料厚度符合λ/4阻抗匹配模型。综上,层状硫掺杂黑磷作为高性能介电损耗吸波材料具有广阔的应用前景。

, authors=王博翀1, 2, 郝春雪1, 常玉凯1, 牟从普1, 2, 温福昇1, 柳忠元1, authorsList=王博翀, 郝春雪, 常玉凯, 牟从普, 温福昇, 柳忠元, authorCompany=null, correspAuthors=柳忠元, authorNote=

王博翀(1985—),男,博士,副教授。

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柳忠元(1965—),男,博士,教授。
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层状硫掺杂黑磷晶体的高频电磁性能
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王博翀 1, 2 , 郝春雪 1 , 常玉凯 1 , 牟从普 1, 2 , 温福昇 1 , 柳忠元 1
硅酸盐学报 | 国家自然科学基金重点项目中期成果专题—研究论文 2022,50(2): 285-289
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硅酸盐学报 |国家自然科学基金重点项目中期成果专题—研究论文 2022 , 50 (2) : 285 -289
层状硫掺杂黑磷晶体的高频电磁性能
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王博翀1, 2 , 郝春雪1, 常玉凯1, 牟从普1, 2, 温福昇1, 柳忠元1
作者信息
  • 1.高压科学研究中心,亚稳材料制备技术与科学国家重点实验室,燕山大学,河北 秦皇岛 066004
  • 2.河北省微结构材料物理重点实验室,燕山大学理学院,河北 秦皇岛 066004
通讯作者:
柳忠元(1965—),男,博士,教授。
作者简介:

王博翀(1985—),男,博士,副教授。

High-Frequency Electromagnetic Properties of Layered Sulfur Doped Black Phosphorus Crystals
Bochong WANG1, 2 , Chunxue HAO1, Yukai CHANG1, Congpu MOU1, 2, Fusheng WEN1, Zhongyuan LIU1
Affiliations
  • 1.Center for High Pressure Science, State Key Laboratory of Metastable Materials Science & Technology, Yanshan University, Qinhuangdao 066004, China
  • 2.Hebei Key Laboratory of Microstructure Materials Physics, School of Science, Yanshan University, Qinhuangdao 066004, China
  • Corresponding Author:
    LIU Zhongyuan (1965-), male, Ph.D., Professor. E-mail:

    WANG Bochong (1985-), male, Ph.D., Associate Professor. E-mail:

出版时间: 2022-02-20
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电子设备的增多使得吸波材料在军事和民用领域具有广泛的应用。当前研究的重点在于制备吸收强、频带宽、质量轻、厚度薄的新型吸波材料。利用高温高压成功合成黑磷(BP)和硫掺杂黑磷(BP-S)晶体,并使用液相剥离的方法制备BP和BP-S纳米片。高频电磁参数测量发现相较于BP,硫元素的掺杂使得BP-S复数介电常数和介电损耗正切值在频率1.0~16.5 GHz情况下明显提高。BP-S在9.6 GHz处最小反射损耗可达到-41.1 dB;当厚度在1.0~2.0 mm范围内变化时,小于-10 dB的反射损耗频率范围为7.0~16.1 GHz。BP-S的最小反射损耗频率点与材料厚度符合λ/4阻抗匹配模型。综上,层状硫掺杂黑磷作为高性能介电损耗吸波材料具有广阔的应用前景。

黑磷  /  吸波材料  /  高温  /  高压  /  硫掺杂  /  高频  /  电磁性能

Microwave absorbing materials are widely used in military and civil fields. The current research focusses on novel microwave absorbing materials with intense absorption, wide bandwidth, light weight and thin thickness. Black phosphorus (BP) and sulfur-doped black phosphorus (BP-S) crystals were prepared at a high temperature and a high pressure, and then BP and BP-S nanosheets were obtained via liquid-phase exfoliation. Compared with BP, the complex permittivity and εr″/εr′ of BP-S are enhanced at 1.0-16.5 GHz. The minimum reflection loss (RL) reaches -41.4 dB at 9.6 GHz, and the RL exceeding -10 dB in a frequency range of 7.0 to 16.1 GHz is obtained for the absorber thickness of 1.0-2.0 mm. The minimum RL frequency dependence of the absorber thickness for BP-S comply with a λ/4 matching model. BP-S has broad application prospects as a high-performance microwave absorbing material.

black phosphorus  /  microwave absorbing material  /  high temperature  /  high pressure  /  sulfur doped  /  high frequency  /  electromagnetic property
王博翀, 郝春雪, 常玉凯, 牟从普, 温福昇, 柳忠元. 层状硫掺杂黑磷晶体的高频电磁性能. 硅酸盐学报, 2022 , 50 (2) : 285 -289 .
Bochong WANG, Chunxue HAO, Yukai CHANG, Congpu MOU, Fusheng WEN, Zhongyuan LIU. High-Frequency Electromagnetic Properties of Layered Sulfur Doped Black Phosphorus Crystals[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (2) : 285 -289 .
  • 国家自然科学基金项目(51732010; 52071280; 51801175)
  • 河北省自然科学基金项目(E2020203151; E2019203233)
  • 河北省高等学校科学技术研究项目重点项目(ZD2020121)
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2022年第50卷第2期
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  • 接收时间:2021-10-04
  • 首发时间:2026-10-22
  • 出版时间:2022-02-20
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  • 收稿日期:2021-10-04
  • 修回日期:2021-10-31
基金
国家自然科学基金项目(51732010; 52071280; 51801175)
河北省自然科学基金项目(E2020203151; E2019203233)
河北省高等学校科学技术研究项目重点项目(ZD2020121)
作者信息
    1.高压科学研究中心,亚稳材料制备技术与科学国家重点实验室,燕山大学,河北 秦皇岛 066004
    2.河北省微结构材料物理重点实验室,燕山大学理学院,河北 秦皇岛 066004

通讯作者:

柳忠元(1965—),男,博士,教授。
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属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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