Article(id=1319987095070945441, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319987091220574321, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20210646, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1628092800000, receivedDateStr=2021-08-05, revisedDate=1632326400000, revisedDateStr=2021-09-23, acceptedDate=null, acceptedDateStr=null, onlineDate=1792639047639, onlineDateStr=2026-10-22, pubDate=1642608000000, pubDateStr=2022-01-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792639047639, onlineIssueDateStr=2026-10-22, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792639047639, creator=13701087609, updateTime=1792639047639, updator=13701087609, issue=Issue{id=1319987091220574321, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='1', pageStart='1', pageEnd='276', issueExtLink='null', onlineDate='null', pubDate='1642608000000', pubDateStr='2022-01-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792639046721, creator='13701087609', updateTime=1792639238958, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319987897588105574, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319987091220574321, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319987897588105575, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319987091220574321, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=134, endPage=147, ext={EN=ArticleExt(id=1319987095268077730, articleId=1319987095070945441, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Structural Design of Organic Sulfides for Lithium Sulfur Batteries and Its Relative Scientific Issues, columnId=1321891336266035533, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Issue on Electrochemical Energy Storage Materials—Review, runingTitle=null, highlight=null, articleAbstract=

Organic sulfides are recognized as the most promising cathode materials for lithium-sulfur batteries due to their high capacities, abundant resources and adjustable structures. Organic sulfides have a variety of superior features with respect to the diversity of structural designs, superior lithium storage properties and reaction mechanisms. In this review, recent development on organic sulfides in lithium sulfur batteries was represented, the latest progress of researches on small molecule polysulfides, polysulfides and vulcanized polymers was described, and their structure characteristics and electrochemical mechanisms were illustrated. In addition, the relationship between electrochemical performance of organic sulfides and their structure design as well as functional groups was also summarized. The future prospect of organic sulfides was given for next generation energy storage systems.

, authors=Lei WANG, Xiang CUI, Hanghang DONG, Qianqian PENG, Shuo QI, Qijie YU, Xuan YU, Weiwei SUN, Liping LYU, Yong WANG, Shuangqiang CHEN, authorsList=Lei WANG, Xiang CUI, Hanghang DONG, Qianqian PENG, Shuo QI, Qijie YU, Xuan YU, Weiwei SUN, Liping LYU, Yong WANG, Shuangqiang CHEN, authorCompany=null, correspAuthors=Shuangqiang CHEN, authorNote=

WANG Lei (1994-), female, Doctoral candidate. E-mail:

, correspAuthorsNote=
CHEN Shuangqiang (1983-), male, Ph.D., Professor. E-mail:
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目前,有机硫化物因具有容量大、资源丰富和结构可调等优点,已成为锂硫电池中最具发展前景的正极材料,其中,有机硫化物因具有丰富的结构设计、优良的储锂性能和特殊的反应机制而备受关注。基于此,回顾了有机硫化物在锂硫电池中的发展历程,综述了小分子多硫化物、聚多硫化物和硫化聚合物的最新研究进展。同时阐明了它们的结构特性和电化学机理,总结了有机硫化物的电池性能与其结构设计和官能团调节的相互关系与优化策略,并对有机硫化物的发展前景进行了探讨。

, authors=王磊, 崔香, 董行行, 彭倩倩, 齐硕, 余期捷, 余璇, 孙炜伟, 吕丽萍, 王勇, 陈双强, authorsList=王磊, 崔香, 董行行, 彭倩倩, 齐硕, 余期捷, 余璇, 孙炜伟, 吕丽萍, 王勇, 陈双强, authorCompany=null, correspAuthors=陈双强, authorNote=

王磊(1994—),女,博士研究生。

, correspAuthorsNote=
陈双强(1983—),男,博士,教授。
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锂硫电池中有机硫化物的结构设计及最新进展
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王磊 , 崔香 , 董行行 , 彭倩倩 , 齐硕 , 余期捷 , 余璇 , 孙炜伟 , 吕丽萍 , 王勇 , 陈双强
硅酸盐学报 | 电化学储能材料专题—综合评述 2022,50(1): 134-147
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硅酸盐学报 |电化学储能材料专题—综合评述 2022 , 50 (1) : 134 -147
锂硫电池中有机硫化物的结构设计及最新进展
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王磊 , 崔香, 董行行, 彭倩倩, 齐硕, 余期捷, 余璇, 孙炜伟, 吕丽萍, 王勇, 陈双强
作者信息
  • 上海大学环境与化学工程学院,上海 200444
通讯作者:
陈双强(1983—),男,博士,教授。
作者简介:

王磊(1994—),女,博士研究生。

Structural Design of Organic Sulfides for Lithium Sulfur Batteries and Its Relative Scientific Issues
Lei WANG , Xiang CUI, Hanghang DONG, Qianqian PENG, Shuo QI, Qijie YU, Xuan YU, Weiwei SUN, Liping LYU, Yong WANG, Shuangqiang CHEN
Affiliations
  • School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China
  • Corresponding Author:
    CHEN Shuangqiang (1983-), male, Ph.D., Professor. E-mail:

    WANG Lei (1994-), female, Doctoral candidate. E-mail:

出版时间: 2022-01-20 doi: 10.14062/j.issn.0454-5648.20210646
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目前,有机硫化物因具有容量大、资源丰富和结构可调等优点,已成为锂硫电池中最具发展前景的正极材料,其中,有机硫化物因具有丰富的结构设计、优良的储锂性能和特殊的反应机制而备受关注。基于此,回顾了有机硫化物在锂硫电池中的发展历程,综述了小分子多硫化物、聚多硫化物和硫化聚合物的最新研究进展。同时阐明了它们的结构特性和电化学机理,总结了有机硫化物的电池性能与其结构设计和官能团调节的相互关系与优化策略,并对有机硫化物的发展前景进行了探讨。

锂硫电池  /  有机硫化物  /  储锂机制  /  柔性电极  /  结构设计

Organic sulfides are recognized as the most promising cathode materials for lithium-sulfur batteries due to their high capacities, abundant resources and adjustable structures. Organic sulfides have a variety of superior features with respect to the diversity of structural designs, superior lithium storage properties and reaction mechanisms. In this review, recent development on organic sulfides in lithium sulfur batteries was represented, the latest progress of researches on small molecule polysulfides, polysulfides and vulcanized polymers was described, and their structure characteristics and electrochemical mechanisms were illustrated. In addition, the relationship between electrochemical performance of organic sulfides and their structure design as well as functional groups was also summarized. The future prospect of organic sulfides was given for next generation energy storage systems.

lithium-sulfur battery  /  organic sulfides  /  lithium storage mechanism  /  flexible electrode  /  structural design
王磊, 崔香, 董行行, 彭倩倩, 齐硕, 余期捷, 余璇, 孙炜伟, 吕丽萍, 王勇, 陈双强. 锂硫电池中有机硫化物的结构设计及最新进展. 硅酸盐学报, 2022 , 50 (1) : 134 -147 . DOI: 10.14062/j.issn.0454-5648.20210646
Lei WANG, Xiang CUI, Hanghang DONG, Qianqian PENG, Shuo QI, Qijie YU, Xuan YU, Weiwei SUN, Liping LYU, Yong WANG, Shuangqiang CHEN. Structural Design of Organic Sulfides for Lithium Sulfur Batteries and Its Relative Scientific Issues[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (1) : 134 -147 . DOI: 10.14062/j.issn.0454-5648.20210646
  • 国家自然科学基金面上项目(21975154; 22179078)
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2022年第50卷第1期
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doi: 10.14062/j.issn.0454-5648.20210646
  • 接收时间:2021-08-05
  • 首发时间:2026-10-22
  • 出版时间:2022-01-20
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  • 收稿日期:2021-08-05
  • 修回日期:2021-09-23
基金
国家自然科学基金面上项目(21975154; 22179078)
作者信息
    上海大学环境与化学工程学院,上海 200444

通讯作者:

陈双强(1983—),男,博士,教授。
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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