Article(id=1319987091719696497, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319987091220574321, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20210566, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1626019200000, receivedDateStr=2021-07-12, revisedDate=1629388800000, revisedDateStr=2021-08-20, acceptedDate=null, acceptedDateStr=null, onlineDate=1792639046839, onlineDateStr=2026-10-22, pubDate=1642608000000, pubDateStr=2022-01-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792639046839, onlineIssueDateStr=2026-10-22, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792639046839, creator=13701087609, updateTime=1792639046839, updator=13701087609, issue=Issue{id=1319987091220574321, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='1', pageStart='1', pageEnd='276', issueExtLink='null', onlineDate='null', pubDate='1642608000000', pubDateStr='2022-01-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792639046721, creator='13701087609', updateTime=1792639238958, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319987897588105574, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319987091220574321, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319987897588105575, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319987091220574321, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=55, endPage=61, ext={EN=ArticleExt(id=1319987092046852210, articleId=1319987091719696497, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=High-Temperature Quenching Synthesis and Electrochemical Properties of Na11Sn2PS12 Solid Electrolytes, columnId=1321891465115062324, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Issue on Electrochemical Energy Storage Materials—Research Articles, runingTitle=null, highlight=null, articleAbstract=

Na11Sn2PS12 solid electrolytes were synthesized by a high-temperature quenching method, and the structures as well as electrochemical performance were investigated. A Na11Sn2PS12 phase with a certain amount of impurity can be obtained in quenching process. The content of impurity phase in the quenching precursors annealed at 430 ℃ decreases and the room-temperature ionic conductivity enhances from 0.34×10-4 S/cm to 6.26×10-4 S/cm. In addition, a prepared Na11Sn2PS12 possesses a low activation energy of 0.27 eV and an electronic conductivity of 2.25×10-8 S/cm, and an electrochemistry stability window between 0.8 V and 2.8 V. Also, Na11Sn2PS12 is used in all-solid-state sodium batteries, showing good electrochemical performances.

, authors=Wei WENG1, 2, Hongli WAN1, Gaozhan LIU1, Lin SHEN1, 2, Xiayin YAO1, 2, authorsList=Wei WENG, Hongli WAN, Gaozhan LIU, Lin SHEN, Xiayin YAO, authorCompany=null, correspAuthors=Xiayin YAO, authorNote=

WENG Wei (1994-), male, Doctoral candidate. E-mail:

, correspAuthorsNote=
YAO Xiayin (1982-), male, Ph.D., Professor. E-mail:
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319987092315287667, articleId=1319987091719696497, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=高温淬火制备Na11Sn2PS12固体电解质及其电化学性能, columnId=1321891465291223093, journalTitle=硅酸盐学报, columnName=电化学储能材料专题—研究论文, runingTitle=null, highlight=null, articleAbstract=

采用高温淬火法成功制备了Na11Sn2PS12固体电解质,并对其结构、离子/电子电导率、激活能以及电化学稳定性进行了表征分析,最后研究了Na11Sn2PS12固体电解质在全固态钠电池中的应用。结果表明:高温淬火得到的目标物相含有杂相,通过430 ℃退火可以显著减少杂相,进而将钠离子电导率从0.34×10-4 S/cm提高至6.26×10-4 S/cm;退火后的Na11Sn2PS12固体电解质具有较低的激活能(0.27 eV)和电子电导率(2.25×10-8 S/cm),且在0.8~2.8 V具有稳定的电化学窗口。将Na11Sn2PS12应用于全固态钠电池,电池表现出良好的充放电性能。

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翁伟(1994—),男,博士研究生。

, correspAuthorsNote=
姚霞银(1982—),男,博士,研究员。
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高温淬火制备Na11Sn2PS12固体电解质及其电化学性能
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翁伟 1, 2 , 万红利 1 , 刘高瞻 1 , 沈麟 1, 2 , 姚霞银 1, 2
硅酸盐学报 | 电化学储能材料专题—研究论文 2022,50(1): 55-61
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硅酸盐学报 |电化学储能材料专题—研究论文 2022 , 50 (1) : 55 -61
高温淬火制备Na11Sn2PS12固体电解质及其电化学性能
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翁伟1, 2 , 万红利1, 刘高瞻1, 沈麟1, 2, 姚霞银1, 2
作者信息
  • 1.中国科学院宁波材料技术与工程研究所,浙江 宁波 315201
  • 2.中国科学院大学,北京 100049
通讯作者:
姚霞银(1982—),男,博士,研究员。
作者简介:

翁伟(1994—),男,博士研究生。

High-Temperature Quenching Synthesis and Electrochemical Properties of Na11Sn2PS12 Solid Electrolytes
Wei WENG1, 2 , Hongli WAN1, Gaozhan LIU1, Lin SHEN1, 2, Xiayin YAO1, 2
Affiliations
  • 1.Ningbo Institute of Materials Technology and Engineering, Chinese Academy of Sciences, Ningbo 315201, Zhejiang, China
  • 2.Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China
  • Corresponding Author:
    YAO Xiayin (1982-), male, Ph.D., Professor. E-mail:

    WENG Wei (1994-), male, Doctoral candidate. E-mail:

出版时间: 2022-01-20 doi: 10.14062/j.issn.0454-5648.20210566
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采用高温淬火法成功制备了Na11Sn2PS12固体电解质,并对其结构、离子/电子电导率、激活能以及电化学稳定性进行了表征分析,最后研究了Na11Sn2PS12固体电解质在全固态钠电池中的应用。结果表明:高温淬火得到的目标物相含有杂相,通过430 ℃退火可以显著减少杂相,进而将钠离子电导率从0.34×10-4 S/cm提高至6.26×10-4 S/cm;退火后的Na11Sn2PS12固体电解质具有较低的激活能(0.27 eV)和电子电导率(2.25×10-8 S/cm),且在0.8~2.8 V具有稳定的电化学窗口。将Na11Sn2PS12应用于全固态钠电池,电池表现出良好的充放电性能。

硫化物固体电解质  /  四元钠离子导体  /  高温淬火法  /  全固态钠电池

Na11Sn2PS12 solid electrolytes were synthesized by a high-temperature quenching method, and the structures as well as electrochemical performance were investigated. A Na11Sn2PS12 phase with a certain amount of impurity can be obtained in quenching process. The content of impurity phase in the quenching precursors annealed at 430 ℃ decreases and the room-temperature ionic conductivity enhances from 0.34×10-4 S/cm to 6.26×10-4 S/cm. In addition, a prepared Na11Sn2PS12 possesses a low activation energy of 0.27 eV and an electronic conductivity of 2.25×10-8 S/cm, and an electrochemistry stability window between 0.8 V and 2.8 V. Also, Na11Sn2PS12 is used in all-solid-state sodium batteries, showing good electrochemical performances.

sulfide solid electrolytes  /  quaternary sodium ionic conductor  /  high temperature quenching synthesis  /  all-solid-state sodium batteries
翁伟, 万红利, 刘高瞻, 沈麟, 姚霞银. 高温淬火制备Na11Sn2PS12固体电解质及其电化学性能. 硅酸盐学报, 2022 , 50 (1) : 55 -61 . DOI: 10.14062/j.issn.0454-5648.20210566
Wei WENG, Hongli WAN, Gaozhan LIU, Lin SHEN, Xiayin YAO. High-Temperature Quenching Synthesis and Electrochemical Properties of Na11Sn2PS12 Solid Electrolytes[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (1) : 55 -61 . DOI: 10.14062/j.issn.0454-5648.20210566
  • 国家自然科学基金(51872303; U1964205)
  • 浙江省自然科学基金(LD18E020004)
  • 中国科学院青年创新促进会(2017342)
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doi: 10.14062/j.issn.0454-5648.20210566
  • 接收时间:2021-07-12
  • 首发时间:2026-10-22
  • 出版时间:2022-01-20
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  • 收稿日期:2021-07-12
  • 修回日期:2021-08-20
基金
国家自然科学基金(51872303; U1964205)
浙江省自然科学基金(LD18E020004)
中国科学院青年创新促进会(2017342)
作者信息
    1.中国科学院宁波材料技术与工程研究所,浙江 宁波 315201
    2.中国科学院大学,北京 100049

通讯作者:

姚霞银(1982—),男,博士,研究员。
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2种不同金属材料的力学参数
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genus
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species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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