Article(id=1319987070886589323, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319987055371858691, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20210753, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1632585600000, receivedDateStr=2021-09-26, revisedDate=1635091200000, revisedDateStr=2021-10-25, acceptedDate=null, acceptedDateStr=null, onlineDate=1792639041872, onlineDateStr=2026-10-22, pubDate=1645286400000, pubDateStr=2022-02-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792639041872, onlineIssueDateStr=2026-10-22, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792639041872, creator=13701087609, updateTime=1792639041872, updator=13701087609, issue=Issue{id=1319987055371858691, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='2', pageStart='277', pageEnd='554', issueExtLink='null', onlineDate='null', pubDate='1645286400000', pubDateStr='2022-02-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792639038174, creator='13701087609', updateTime=1792639254308, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319987961958089069, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319987055371858691, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319987961958089070, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319987055371858691, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=364, endPage=371, ext={EN=ArticleExt(id=1319987072119714700, articleId=1319987070886589323, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Preparation and Electrochemical Properties of Li₄Ti₅O₁₂@Porous-C Composite as Anode of Lithium Ion Battery, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

A composite of porous carbon coated Li₄Ti₅O₁₂ was prepared by a hydrothermal synthesis and high-temperature activation method. The microstructure and electrochemical properties of the composite were investigated. The results show that Li₄Ti₅O₁₂ is completely coated on the porous carbon layer. Meanwhile, the surface pores of Li₄Ti₅O₁₂@porous C composite are evenly distributed, and the carbon layer thickness is approximately (8.5±3.6) nm. The discharge capacity at first cycle is 363 mAh/g, which is approximately twice greater than that of pure Li₄Ti₅O₁₂. The AC impedance value of Li₄Ti₅O₁₂@porous C composite decreases, which is only the half of that of pure Li₄Ti₅O₁₂. The discharge specific capacity of Li₄Ti₅O₁₂@porous-C composite is 251 mAh/g and the retention rate is 97.7 % after 200 cycles (i.e., the specific capacity of pure Li₄Ti₅O₁₂ is 143 mAh/g and the retention rate is 94.7%), the discharge specific capacity is nearly doubled, especially when the rate test is carried out at different discharge rates. The reversible capacity is twice greater than that of Li₄Ti₅O₁₂. The porous carbon coated modification of Li₄Ti₅O₁₂ can increase the specific surface area and the electron transfer rate for the higher electrochemical properties.

, authors=Ming WANG, Pengfei FANG, Liang DU, Pengtao QI, Ding SHEN, authorsList=Ming WANG, Pengfei FANG, Liang DU, Pengtao QI, Ding SHEN, authorCompany=null, correspAuthors=null, authorNote=, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319987072354595725, articleId=1319987070886589323, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=锂离子电池负极用多孔碳包覆Li₄Ti₅O₁₂复合材料的制备及电化学性能, columnId=1263922770220560512, journalTitle=硅酸盐学报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=

利用水热合成和高温活化处理对Li₄Ti₅O₁₂进行多孔碳包覆复合改性实验，制备了Li₄Ti₅O₁₂@porous-C复合材料，研究了复合材料微观结构和电化学性能。结果表明：Li₄Ti₅O₁₂完全被包覆在多孔碳层中，同时，Li₄Ti₅O₁₂@porous-C复合材料表面碳层孔洞分布均匀，碳层厚度约为（8.5±3.6） nm。其首次放电比容量为363 mAh/g，约为纯Li₄Ti₅O₁₂放电比容量的2倍；交流阻抗值降低，仅为纯Li₄Ti₅O₁₂的阻抗值的一半；Li₄Ti₅O₁₂@porous-C复合材料在循环200周后的放电比容量为251 mAh/g，容量保持率为97.7%（纯LTO的比容量为143 mAh/g，保持率为94.7%），放电比容量提高了近1倍，而且特别是在不同放电速率下进行倍率测试时，其可逆容量比Li₄Ti₅O₁₂提高超1.5倍。对Li₄Ti₅O₁₂表面进行多孔碳包覆改性，可以同时提高其比表面积和电子传输速率，这也是其电化学性能也显著提高的主要原因。

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WANG Ming (1982-), male, Ph.D., Associate Professor. E-mail: mwang_neu@126.com

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王鸣（1982—），男，博士，副教授。

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王鸣（1982—），男，博士，副教授。

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