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Article(id=1319987014380933185, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986924727677753, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20210995, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1636646400000, receivedDateStr=2021-11-12, revisedDate=1640188800000, revisedDateStr=2021-12-23, acceptedDate=null, acceptedDateStr=null, onlineDate=1792639028401, onlineDateStr=2026-10-22, pubDate=1650384000000, pubDateStr=2022-04-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792639028401, onlineIssueDateStr=2026-10-22, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792639028401, creator=13701087609, updateTime=1792639028401, updator=13701087609, issue=Issue{id=1319986924727677753, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='4', pageStart='877', pageEnd='1200', issueExtLink='null', onlineDate='null', pubDate='1650384000000', pubDateStr='2022-04-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792639007026, creator='13701087609', updateTime=1792639269665, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319988026600702366, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986924727677753, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319988026600702367, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986924727677753, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1100, endPage=1108, ext={EN=ArticleExt(id=1319987014586454082, articleId=1319987014380933185, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Progress on Rare-Earth Ions Doped Midinfrared Chalcogenide Optical Fibers and Their Sensing Application, columnId=1321891933815943235, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Issue on United Nations International Year of Glass—Review, runingTitle=null, highlight=null, articleAbstract=

Mid-infrared light sources have some important applications in military and national economy, such as national defense safety, food safety, spectral analysis and so on. Recent research work on rare-earth element ions doped chalcogenide glasses and optical fibers mainly focuses on improving the solubility of rare-earth element ions, reducing the local phonon energy of rare-earth element ions and co-doping of sensitized ions. The mid-infrared fluorescence of rare-earth element ions such as Dy3+, Pr3+, Dy3+, Tb3+, and Sm3+ can be obtained in glass and optical fiber. This broadband mid-infrared fluorescence is applied in the sensing field to realize the sensing of gases such as CO2 and CH4. This review represented recent research progress on rare-earth element ions doped mid-infrared chalcogenide glasses and optical fibers. Various factors affecting the mid-infrared luminescence of chalcogenide glass fibers were discussed, i.e., the solubility of rare-earth element ions, phonon energy around rare-earth element ions, energy transfer between sensitized ions and impurity loss. The research progress of broadband mid-infrared fluorescence in the field of gas sensing was summarized. There are five deficiencies in the research of rare-earth element ions doped sulfur fiber gas sensor. Obtaining the mid-infrared laser in rare-earth element ions doped glass fiber is still a challenge. In addition to seeking the solutions from the perspective of active fiber preparation (i.e., matrix selection, rare-earth ions co-doping, local structure regulation, preform glass purification, etc.), some aspects of optical fiber grating writing technology, pump laser power and wavelength tuning were also concerned. Rare-earth element ions doped mid-infrared chalcogenide fiber as a promising optical material has a great application potential due to its advantages of compactness, compactness and economy.

, authors=Quan LIU1, Zijian LI1, Xudong ZHAO1, Yinsheng XU1, 2, Xianghua ZHANG1, authorsList=Quan LIU, Zijian LI, Xudong ZHAO, Yinsheng XU, Xianghua ZHANG, authorCompany=null, correspAuthors=Yinsheng XU, authorNote=

LIU Quan (1997-), male, Master candidate. E-mail:

, correspAuthorsNote=
XU Yinsheng (1984-), male, Ph.D., Professor. E-mail:
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中红外光源在国防安全、食品安全、光谱分析等军事或国民经济的重要行业有着重要的应用。近年来，稀土离子掺杂硫系玻璃和光纤的研究主要集中在提高稀土离子溶解度、降低稀土离子局域声子能量和敏化离子共掺等方面。在玻璃和光纤中获得了Dy3+、Pr3+、Dy3+、Tb3+、Sm3+等稀土离子的中红外荧光，这种宽带中红外荧光在传感领域得到了应用，实现了CO2、CH4等气体的传感。本文综合评述了稀土掺杂中红外硫系玻璃和光纤的研究进展，讨论了影响硫系玻璃光纤中红外发光的各种因素，包括稀土离子溶解度、稀土离子周围声子能量、敏化离子间能量传递和杂质损耗等，重点总结了宽带中红外荧光在气体传感领域的研究进展，指出对于稀土离子掺杂硫系光纤气体传感器的研究有5个方面存在不足。如何在稀土掺杂玻璃光纤中获得中红外激光仍是一个急需研究的方向，除了从有源光纤制备（基质选择、稀土离子共掺、局域结构调控、预制棒玻璃提纯等）的角度来寻求解决方案，还需要从光纤光栅刻写技术、泵浦激光器功率和波长调谐方面进行研究。稀土掺杂中红外硫系光纤凭借其小巧、紧凑以及经济性等优点展现出巨大的应用潜力，未来在多个领域的物质检测方面将实现广泛应用，具有巨大的应用前景。

, authors=刘权1, 李子坚1, 赵旭东1, 许银生1, 2, 章向华1, authorsList=刘权, 李子坚, 赵旭东, 许银生, 章向华, authorCompany=null, correspAuthors=许银生, authorNote=

刘权（1997—），男，硕士研究生。

, correspAuthorsNote=
许银生（1984—），男，博士，研究员。
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LIU Quan (1997-), male, Master candidate. E-mail:

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刘权（1997—），男，硕士研究生。

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稀土掺杂中红外硫系光纤及其传感应用研究进展
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刘权 1 , 李子坚 1 , 赵旭东 1 , 许银生 1, 2 , 章向华 1
硅酸盐学报 | “联合国国际玻璃年”特刊—综合评述 2022,50(4): 1100-1108
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硅酸盐学报 |“联合国国际玻璃年”特刊—综合评述 2022 , 50 (4) : 1100 -1108
稀土掺杂中红外硫系光纤及其传感应用研究进展
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刘权1 , 李子坚1, 赵旭东1, 许银生1, 2 , 章向华1
作者信息
  • 1．武汉理工大学硅酸盐建筑材料国家重点实验室，武汉 430070
  • 2．华南理工大学发光材料与器件国家重点实验室，广州 510640
通讯作者:
许银生（1984—），男，博士，研究员。
作者简介:

刘权（1997—），男，硕士研究生。

Progress on Rare-Earth Ions Doped Midinfrared Chalcogenide Optical Fibers and Their Sensing Application
Quan LIU1 , Zijian LI1, Xudong ZHAO1, Yinsheng XU1, 2 , Xianghua ZHANG1
Affiliations
  • 1.State Key Laboratory of Silicate Materials for Architecture, Wuhan University of Technology, Wuhan 430070, China
  • 2.State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou 510640, China
    • Corresponding Author:
    XU Yinsheng (1984-), male, Ph.D., Professor. E-mail:

    LIU Quan (1997-), male, Master candidate. E-mail:

出版时间: 2022-04-20 doi: 10.14062/j.issn.0454-5648.20210995
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中红外光源在国防安全、食品安全、光谱分析等军事或国民经济的重要行业有着重要的应用。近年来，稀土离子掺杂硫系玻璃和光纤的研究主要集中在提高稀土离子溶解度、降低稀土离子局域声子能量和敏化离子共掺等方面。在玻璃和光纤中获得了Dy3+、Pr3+、Dy3+、Tb3+、Sm3+等稀土离子的中红外荧光，这种宽带中红外荧光在传感领域得到了应用，实现了CO2、CH4等气体的传感。本文综合评述了稀土掺杂中红外硫系玻璃和光纤的研究进展，讨论了影响硫系玻璃光纤中红外发光的各种因素，包括稀土离子溶解度、稀土离子周围声子能量、敏化离子间能量传递和杂质损耗等，重点总结了宽带中红外荧光在气体传感领域的研究进展，指出对于稀土离子掺杂硫系光纤气体传感器的研究有5个方面存在不足。如何在稀土掺杂玻璃光纤中获得中红外激光仍是一个急需研究的方向，除了从有源光纤制备（基质选择、稀土离子共掺、局域结构调控、预制棒玻璃提纯等）的角度来寻求解决方案，还需要从光纤光栅刻写技术、泵浦激光器功率和波长调谐方面进行研究。稀土掺杂中红外硫系光纤凭借其小巧、紧凑以及经济性等优点展现出巨大的应用潜力，未来在多个领域的物质检测方面将实现广泛应用，具有巨大的应用前景。

稀土离子掺杂  /  气体传感  /  硫系玻璃光纤  /  中红外发光

Mid-infrared light sources have some important applications in military and national economy, such as national defense safety, food safety, spectral analysis and so on. Recent research work on rare-earth element ions doped chalcogenide glasses and optical fibers mainly focuses on improving the solubility of rare-earth element ions, reducing the local phonon energy of rare-earth element ions and co-doping of sensitized ions. The mid-infrared fluorescence of rare-earth element ions such as Dy3+, Pr3+, Dy3+, Tb3+, and Sm3+ can be obtained in glass and optical fiber. This broadband mid-infrared fluorescence is applied in the sensing field to realize the sensing of gases such as CO2 and CH4. This review represented recent research progress on rare-earth element ions doped mid-infrared chalcogenide glasses and optical fibers. Various factors affecting the mid-infrared luminescence of chalcogenide glass fibers were discussed, i.e., the solubility of rare-earth element ions, phonon energy around rare-earth element ions, energy transfer between sensitized ions and impurity loss. The research progress of broadband mid-infrared fluorescence in the field of gas sensing was summarized. There are five deficiencies in the research of rare-earth element ions doped sulfur fiber gas sensor. Obtaining the mid-infrared laser in rare-earth element ions doped glass fiber is still a challenge. In addition to seeking the solutions from the perspective of active fiber preparation (i.e., matrix selection, rare-earth ions co-doping, local structure regulation, preform glass purification, etc.), some aspects of optical fiber grating writing technology, pump laser power and wavelength tuning were also concerned. Rare-earth element ions doped mid-infrared chalcogenide fiber as a promising optical material has a great application potential due to its advantages of compactness, compactness and economy.

rare earth ion doped  /  gas sensing  /  chalcogenide glass fiber  /  mid infrared luminescence
刘权, 李子坚, 赵旭东, 许银生, 章向华. 稀土掺杂中红外硫系光纤及其传感应用研究进展. 硅酸盐学报, 2022 , 50 (4) : 1100 -1108 . DOI: 10.14062/j.issn.0454-5648.20210995
Quan LIU, Zijian LI, Xudong ZHAO, Yinsheng XU, Xianghua ZHANG. Progress on Rare-Earth Ions Doped Midinfrared Chalcogenide Optical Fibers and Their Sensing Application[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (4) : 1100 -1108 . DOI: 10.14062/j.issn.0454-5648.20210995
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  • 国家自然科学基金项目(61975156)
  • 发光材料与器件国家重点实验室开放基金资助(2020-skllmd-09)
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doi: 10.14062/j.issn.0454-5648.20210995
  • 接收时间：2021-11-12
  • 首发时间：2026-10-22
  • 出版时间：2022-04-20
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  • 收稿日期：2021-11-12
  • 修回日期：2021-12-23
基金
国家自然科学基金项目(61975156)
发光材料与器件国家重点实验室开放基金资助(2020-skllmd-09)
作者信息
    1．武汉理工大学硅酸盐建筑材料国家重点实验室，武汉 430070
    2．华南理工大学发光材料与器件国家重点实验室，广州 510640

通讯作者:

许银生（1984—），男，博士，研究员。
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2种不同金属材料的力学参数
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total species (%)		 属
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鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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