Article(id=1319987012023726504, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986978137944236, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20210789, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1631116800000, receivedDateStr=2021-09-09, revisedDate=1636300800000, revisedDateStr=2021-11-08, acceptedDate=null, acceptedDateStr=null, onlineDate=1792639027839, onlineDateStr=2026-10-22, pubDate=1647705600000, pubDateStr=2022-03-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792639027839, onlineIssueDateStr=2026-10-22, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792639027839, creator=13701087609, updateTime=1792639027839, updator=13701087609, issue=Issue{id=1319986978137944236, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='3', pageStart='555', pageEnd='876', issueExtLink='null', onlineDate='null', pubDate='1647705600000', pubDateStr='2022-03-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792639019760, creator='13701087609', updateTime=1792639223744, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319987833767575858, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986978137944236, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319987833767575859, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986978137944236, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=642, endPage=660, ext={EN=ArticleExt(id=1319987012648677801, articleId=1319987012023726504, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Electrocaloric Effect of Ferroelectric Ceramic and Its Application, columnId=1321898055960474021, journalTitle=Journal of the Chinese Ceramic Society, columnName=Advanced Ferroelectric and Piezoelectric Ceramics—Review, runingTitle=null, highlight=null, articleAbstract=

Electrocaloric effect, i.e., the entropy and temperature changes arising from phase transition and dipole orientation induced in electric fields, can realize heat transport and refrigeration. The electrocaloric cooling eliminates the use of environmentally harmful coolants, possesses high cooling efficiency, small size and low weight as a promising environmental-friendly and high-efficiency cooling. One key point for electrocaloric cooling toward practical cooling is to enhance the performance of the electrocaloric effect of ferroelectrics. Ferroelectric ceramics have attracted much attention due to their high polarization, rich phase structures and variety of regulation methods. In this review, we introduced the electrocaloric effect of ferroelectric ceramic thin films, bulks and multilayer thick films with various compositions, and discussed the internal relations among electrocaloric effect, compositions, phase transition behaviors and microstructures. Furthermore, we concluded the modulation approaches of the electrocaloric effect of ferroelectric ceramics, and gave the future development of electrocaloric materials.

, authors=Chao ZHANG, Fangjie CEN, Wenrong XIAO, Quanpei DU, Kailun ZOU, Shenglin JIANG, Guangzu ZHANG, authorsList=Chao ZHANG, Fangjie CEN, Wenrong XIAO, Quanpei DU, Kailun ZOU, Shenglin JIANG, Guangzu ZHANG, authorCompany=null, correspAuthors=Shenglin JIANG, Guangzu ZHANG, authorNote=

ZHANG Chao(1994-), male, Doctoral candidate. E-mail:

, correspAuthorsNote=
JIANG Shenglin (1967-), male, Ph. D., Professor. E-mail: (JIANG Shenglin)
ZHANG Guangzu (1984-), male, Ph. D., Professor. (ZHANG Guangzu)
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319987014150238634, articleId=1319987012023726504, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=铁电陶瓷的电卡效应及其应用, columnId=1321898056165994918, journalTitle=硅酸盐学报, columnName=先进铁电压电陶瓷材料专题—综合评述, runingTitle=null, highlight=null, articleAbstract=

电卡效应通过电场诱导极性材料的相变和偶极子取向,进而引起材料的熵变和温变、控制材料的吸、放热过程,可用于热搬运和制冷。电卡制冷无须危害环境的制冷剂,且具有效率高、体积小和重量轻的特点,可为节能环保制冷技术的实现提供新的解决方案。铁电材料电卡效应的增强是电卡制冷走向实用的关键。铁电陶瓷极化率高、相结构丰富且调控方法多样,在电卡效应研究中备受关注。本工作介绍了基于不同材料体系的铁电陶瓷薄膜、块体和多层厚膜的电卡效应,讨论了电卡性能与材料配方、相变行为和微结构间的内在联系,归纳了材料电卡效应的调控方法。最后,对铁电陶瓷的未来研究进行了展望。

, authors=张超, 岑方杰, 肖文荣, 杜全沛, 邹凯伦, 姜胜林, 张光祖, authorsList=张超, 岑方杰, 肖文荣, 杜全沛, 邹凯伦, 姜胜林, 张光祖, authorCompany=null, correspAuthors=姜胜林, 张光祖, authorNote=

张超(1994—),男,博士研究生。

, correspAuthorsNote=
姜胜林(1967—),男,博士,教授。
张光祖(1984—),男,博士,教授。
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张超(1994—),男,博士研究生。

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铁电陶瓷的电卡效应及其应用
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张超 , 岑方杰 , 肖文荣 , 杜全沛 , 邹凯伦 , 姜胜林 , 张光祖
硅酸盐学报 | 先进铁电压电陶瓷材料专题—综合评述 2022,50(3): 642-660
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硅酸盐学报 |先进铁电压电陶瓷材料专题—综合评述 2022 , 50 (3) : 642 -660
铁电陶瓷的电卡效应及其应用
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张超 , 岑方杰, 肖文荣, 杜全沛, 邹凯伦, 姜胜林 , 张光祖
作者信息
  • 华中科技大学光学与电子信息学院,武汉 430074
通讯作者:
姜胜林(1967—),男,博士,教授。
张光祖(1984—),男,博士,教授。
作者简介:

张超(1994—),男,博士研究生。

Electrocaloric Effect of Ferroelectric Ceramic and Its Application
Chao ZHANG , Fangjie CEN, Wenrong XIAO, Quanpei DU, Kailun ZOU, Shenglin JIANG , Guangzu ZHANG
Affiliations
  • School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan, 430074, China
  • Corresponding Author:
    JIANG Shenglin (1967-), male, Ph. D., Professor. E-mail: (JIANG Shenglin)
    ZHANG Guangzu (1984-), male, Ph. D., Professor. (ZHANG Guangzu)

    ZHANG Chao(1994-), male, Doctoral candidate. E-mail:

出版时间: 2022-03-20 doi: 10.14062/j.issn.0454-5648.20210789
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电卡效应通过电场诱导极性材料的相变和偶极子取向,进而引起材料的熵变和温变、控制材料的吸、放热过程,可用于热搬运和制冷。电卡制冷无须危害环境的制冷剂,且具有效率高、体积小和重量轻的特点,可为节能环保制冷技术的实现提供新的解决方案。铁电材料电卡效应的增强是电卡制冷走向实用的关键。铁电陶瓷极化率高、相结构丰富且调控方法多样,在电卡效应研究中备受关注。本工作介绍了基于不同材料体系的铁电陶瓷薄膜、块体和多层厚膜的电卡效应,讨论了电卡性能与材料配方、相变行为和微结构间的内在联系,归纳了材料电卡效应的调控方法。最后,对铁电陶瓷的未来研究进行了展望。

固态制冷  /  电卡效应  /  铁电陶瓷  /  相结构  /  熵变  /  温变

Electrocaloric effect, i.e., the entropy and temperature changes arising from phase transition and dipole orientation induced in electric fields, can realize heat transport and refrigeration. The electrocaloric cooling eliminates the use of environmentally harmful coolants, possesses high cooling efficiency, small size and low weight as a promising environmental-friendly and high-efficiency cooling. One key point for electrocaloric cooling toward practical cooling is to enhance the performance of the electrocaloric effect of ferroelectrics. Ferroelectric ceramics have attracted much attention due to their high polarization, rich phase structures and variety of regulation methods. In this review, we introduced the electrocaloric effect of ferroelectric ceramic thin films, bulks and multilayer thick films with various compositions, and discussed the internal relations among electrocaloric effect, compositions, phase transition behaviors and microstructures. Furthermore, we concluded the modulation approaches of the electrocaloric effect of ferroelectric ceramics, and gave the future development of electrocaloric materials.

solid-state cooling  /  electrocaloric effect  /  ferroelectric ceramic  /  phase structure  /  entropy change  /  temperature change
张超, 岑方杰, 肖文荣, 杜全沛, 邹凯伦, 姜胜林, 张光祖. 铁电陶瓷的电卡效应及其应用. 硅酸盐学报, 2022 , 50 (3) : 642 -660 . DOI: 10.14062/j.issn.0454-5648.20210789
Chao ZHANG, Fangjie CEN, Wenrong XIAO, Quanpei DU, Kailun ZOU, Shenglin JIANG, Guangzu ZHANG. Electrocaloric Effect of Ferroelectric Ceramic and Its Application[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (3) : 642 -660 . DOI: 10.14062/j.issn.0454-5648.20210789
  • 国家自然科学基金(51772108; 51972125; 51972126)
  • 湖北省重点研发计划项目(2020BAB067)
  • 湖北省创新群体项目(2019CFA004)
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2022年第50卷第3期
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doi: 10.14062/j.issn.0454-5648.20210789
  • 接收时间:2021-09-09
  • 首发时间:2026-10-22
  • 出版时间:2022-03-20
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  • 收稿日期:2021-09-09
  • 修回日期:2021-11-08
基金
国家自然科学基金(51772108; 51972125; 51972126)
湖北省重点研发计划项目(2020BAB067)
湖北省创新群体项目(2019CFA004)
作者信息
    华中科技大学光学与电子信息学院,武汉 430074

通讯作者:

姜胜林(1967—),男,博士,教授。
张光祖(1984—),男,博士,教授。
参考文献
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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