Article(id=1319986967350203135, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986924727677753, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20211055, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1638720000000, receivedDateStr=2021-12-06, revisedDate=1640620800000, revisedDateStr=2021-12-28, acceptedDate=null, acceptedDateStr=null, onlineDate=1792639017187, onlineDateStr=2026-10-22, pubDate=1650384000000, pubDateStr=2022-04-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792639017187, onlineIssueDateStr=2026-10-22, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792639017187, creator=13701087609, updateTime=1792639017187, updator=13701087609, issue=Issue{id=1319986924727677753, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='4', pageStart='877', pageEnd='1200', issueExtLink='null', onlineDate='null', pubDate='1650384000000', pubDateStr='2022-04-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792639007026, creator='13701087609', updateTime=1792639269665, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319988026600702366, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986924727677753, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319988026600702367, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986924727677753, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=937, endPage=942, ext={EN=ArticleExt(id=1319986969275388672, articleId=1319986967350203135, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Effects of Acid Leaching and Heat Treatment on Structure of SiO2-Na2O Glass Fibers, columnId=1321891873954837352, journalTitle=Journal of the Chinese Ceramic Society, columnName=Special Issue on United Nations International Year of Glass—Research Articles, runingTitle=null, highlight=null, articleAbstract=

High silica glass fiber is widely used and has the superior properties. Acid leaching is the main existing method to prepare high silica special glass fiber. In this paper, high silica glass fiber was prepared via acid leaching and heat treatment. The structure of SiO2-Na2O binary glass fiber during acid leaching and heat treatment was investigated by Raman spectroscopy. The results show that the bending vibration peak and asymmetric stretching vibration peak shift to a lower wavenumber, and the peak intensity becomes weaker during acid leaching process, mainly because SiO2 content in the fiber increases and the internal structure of the fiber changes to a chain structure. After heat treatment, the asymmetric stretching vibration peaks disappear, and the defect lines D1 and D2 appear, and the density of fibers changes at different heat treatment temperatures, mainly due to the condensation reaction of fiber during heat treatment.

, authors=Zhengwei LIU1, 2, Shuaiming ZHANG1, 2, Lida LUO1, 2, Qingwei WANG1, 2, 3, Weizhong JIANG1, 2, Xiang ZHAO3, authorsList=Zhengwei LIU, Shuaiming ZHANG, Lida LUO, Qingwei WANG, Weizhong JIANG, Xiang ZHAO, authorCompany=null, correspAuthors=Qingwei WANG, authorNote=

LIU Zhengwei (1997-), male, Master candidate. E-mail:

, correspAuthorsNote=
WANG Qingwei (1978-), male, Ph.D., Professor. E-mail:
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319986969548018433, articleId=1319986967350203135, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=酸沥滤和热处理对SiO2-Na2O系统高硅氧玻璃纤维结构的影响, columnId=1321891874147775337, journalTitle=硅酸盐学报, columnName=“联合国国际玻璃年”特刊—研究论文, runingTitle=null, highlight=null, articleAbstract=

高硅氧玻璃纤维应用广泛、性能优异。目前制备高硅氧特种玻璃纤维的主要方法是酸沥滤。酸沥滤法是将玻璃纤维原纱通过酸沥滤,热处理等工艺制备得到高硅氧玻璃纤维。采用Raman光谱研究SiO2-Na2O二元系玻纤在酸沥滤、热处理工艺制备高硅氧玻璃纤维过程中的纤维结构变化。结果表明:酸沥滤过程使硅氧四面体的弯曲振动峰和不对称伸缩振动峰向低波数偏移,且峰强变弱,主要由于酸沥滤过程提高了纤维的SiO2含量并改变了内部结构。热处理后,纤维Raman光谱的不对称伸缩振动峰消失,出现缺陷谱线D1和D2,且不同热处理温度后纤维的致密度不同,主要是由于热处理过程中纤维发生的缩合反应导致的。

, authors=刘郑威1, 2, 张帅明1, 2, 罗理达1, 2, 汪庆卫1, 2, 3, 蒋伟忠1, 2, 赵祥3, authorsList=刘郑威, 张帅明, 罗理达, 汪庆卫, 蒋伟忠, 赵祥, authorCompany=null, correspAuthors=汪庆卫, authorNote=

刘郑威(1997—),男,硕士研究生。

, correspAuthorsNote=
汪庆卫(1978—),男,博士,教授。
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酸沥滤和热处理对SiO2-Na2O系统高硅氧玻璃纤维结构的影响
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刘郑威 1, 2 , 张帅明 1, 2 , 罗理达 1, 2 , 汪庆卫 1, 2, 3 , 蒋伟忠 1, 2 , 赵祥 3
硅酸盐学报 | “联合国国际玻璃年”特刊—研究论文 2022,50(4): 937-942
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硅酸盐学报 |“联合国国际玻璃年”特刊—研究论文 2022 , 50 (4) : 937 -942
酸沥滤和热处理对SiO2-Na2O系统高硅氧玻璃纤维结构的影响
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刘郑威1, 2 , 张帅明1, 2, 罗理达1, 2, 汪庆卫1, 2, 3 , 蒋伟忠1, 2, 赵祥3
作者信息
  • 1.东华大学纤维材料改性国家重点实验室,上海 201620
  • 2.先进玻璃制造技术教育部工程研究中心,上海 201620
  • 3.临沂昊泉硅业科技有限公司,山东 临沂 276003
通讯作者:
汪庆卫(1978—),男,博士,教授。
作者简介:

刘郑威(1997—),男,硕士研究生。

Effects of Acid Leaching and Heat Treatment on Structure of SiO2-Na2O Glass Fibers
Zhengwei LIU1, 2 , Shuaiming ZHANG1, 2, Lida LUO1, 2, Qingwei WANG1, 2, 3 , Weizhong JIANG1, 2, Xiang ZHAO3
Affiliations
  • 1.State Key Laboratory for Modification of chemical Fibers and Polymer Materials, Donghua University, Shanghai 201620, China
  • 2.Engineering Center of Advanced Glass Manufacturing Technology, Ministry of Edu0cation; Donghua University, Shanghai 201620, China
  • 3.Linyi Haoquan Silicon Industry Technology Co.Ltd, Linyi 276003, Shandong, China
  • Corresponding Author:
    WANG Qingwei (1978-), male, Ph.D., Professor. E-mail:

    LIU Zhengwei (1997-), male, Master candidate. E-mail:

出版时间: 2022-04-20 doi: 10.14062/j.issn.0454-5648.20211055
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高硅氧玻璃纤维应用广泛、性能优异。目前制备高硅氧特种玻璃纤维的主要方法是酸沥滤。酸沥滤法是将玻璃纤维原纱通过酸沥滤,热处理等工艺制备得到高硅氧玻璃纤维。采用Raman光谱研究SiO2-Na2O二元系玻纤在酸沥滤、热处理工艺制备高硅氧玻璃纤维过程中的纤维结构变化。结果表明:酸沥滤过程使硅氧四面体的弯曲振动峰和不对称伸缩振动峰向低波数偏移,且峰强变弱,主要由于酸沥滤过程提高了纤维的SiO2含量并改变了内部结构。热处理后,纤维Raman光谱的不对称伸缩振动峰消失,出现缺陷谱线D1和D2,且不同热处理温度后纤维的致密度不同,主要是由于热处理过程中纤维发生的缩合反应导致的。

Raman光谱  /  高硅氧玻璃纤维  /  酸沥滤  /  热处理

High silica glass fiber is widely used and has the superior properties. Acid leaching is the main existing method to prepare high silica special glass fiber. In this paper, high silica glass fiber was prepared via acid leaching and heat treatment. The structure of SiO2-Na2O binary glass fiber during acid leaching and heat treatment was investigated by Raman spectroscopy. The results show that the bending vibration peak and asymmetric stretching vibration peak shift to a lower wavenumber, and the peak intensity becomes weaker during acid leaching process, mainly because SiO2 content in the fiber increases and the internal structure of the fiber changes to a chain structure. After heat treatment, the asymmetric stretching vibration peaks disappear, and the defect lines D1 and D2 appear, and the density of fibers changes at different heat treatment temperatures, mainly due to the condensation reaction of fiber during heat treatment.

Raman spectroscopy  /  high silica glass fiber  /  acid leaching  /  heat treatment
刘郑威, 张帅明, 罗理达, 汪庆卫, 蒋伟忠, 赵祥. 酸沥滤和热处理对SiO2-Na2O系统高硅氧玻璃纤维结构的影响. 硅酸盐学报, 2022 , 50 (4) : 937 -942 . DOI: 10.14062/j.issn.0454-5648.20211055
Zhengwei LIU, Shuaiming ZHANG, Lida LUO, Qingwei WANG, Weizhong JIANG, Xiang ZHAO. Effects of Acid Leaching and Heat Treatment on Structure of SiO2-Na2O Glass Fibers[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (4) : 937 -942 . DOI: 10.14062/j.issn.0454-5648.20211055
  • 国家自然科学基金面上项目(51873032)
  • 山东省重点研发计划(2019JZZY010308)
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2022年第50卷第4期
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doi: 10.14062/j.issn.0454-5648.20211055
  • 接收时间:2021-12-06
  • 首发时间:2026-10-22
  • 出版时间:2022-04-20
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  • 收稿日期:2021-12-06
  • 修回日期:2021-12-28
基金
国家自然科学基金面上项目(51873032)
山东省重点研发计划(2019JZZY010308)
作者信息
    1.东华大学纤维材料改性国家重点实验室,上海 201620
    2.先进玻璃制造技术教育部工程研究中心,上海 201620
    3.临沂昊泉硅业科技有限公司,山东 临沂 276003

通讯作者:

汪庆卫(1978—),男,博士,教授。
参考文献
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2种不同金属材料的力学参数
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属数
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genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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