Article(id=1319986609584456069, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986532933555119, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20210843, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1632758400000, receivedDateStr=2021-09-28, revisedDate=1637683200000, revisedDateStr=2021-11-24, acceptedDate=null, acceptedDateStr=null, onlineDate=1792638931890, onlineDateStr=2026-10-22, pubDate=1655654400000, pubDateStr=2022-06-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792638931890, onlineIssueDateStr=2026-10-22, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792638931890, creator=13701087609, updateTime=1792638931890, updator=13701087609, issue=Issue{id=1319986532933555119, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='6', pageStart='1455', pageEnd='1774', issueExtLink='null', onlineDate='null', pubDate='1655654400000', pubDateStr='2022-06-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792638913615, creator='13701087609', updateTime=1792639299444, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319988151507075566, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986532933555119, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319988151507075567, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986532933555119, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1677, endPage=1684, ext={EN=ArticleExt(id=1319986610192630150, articleId=1319986609584456069, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Heat Treatment Process Optimization of Microcrystalline Cast Stone from Silico-manganese Slag by One-Step Preparation, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

Silico-manganese slag is a main solid waste produced from production of silicon-manganese alloy, which affects the environment. It is thus necessary to explore the corresponding disposal methods since the exsiting processing technology restricts the absorbing capacity. A microcrystalline cast stone was fabricated by the Petrurgic firing method with silico-manganese slag as a raw material. The bulk density, microhardness, flexural and compressive strength of the samples were determined. The influences of crystallization temperature and time on the phase structure and properties of the finished product were invesigated. The results show that a hot molten slag is cooled to 950 ℃ for 60 min and then annealed at 760 ℃, obtaing a microcrystalline cast stone with the superior properties. The microcrystalline cast stone has a compact structure, and the precipitated crystal phases are mainly clinopyroxene, diopside and aluminum diopside, as well as anorthite and wollastonite. The bulk density of the cast stone can reach 3.11×103 kg·m-3, the microhardness is 8.77×103 MPa, and the flexural strength and the compressive strength are 86 MPa and 222.9 MPa, respectively.

, authors=Xin XIN, Zexin TAN, Junxue ZHAO, Ailin HU, Ze WANG, Yi KANG, He WANG, Zhenkai ZHANG, authorsList=Xin XIN, Zexin TAN, Junxue ZHAO, Ailin HU, Ze WANG, Yi KANG, He WANG, Zhenkai ZHANG, authorCompany=null, correspAuthors=Junxue ZHAO, authorNote=

XIN Xin (1997-), female, Master candidate. E-mail:

, correspAuthorsNote=
ZHAO Junxue (1962-), male, Ph.D., Professor. E-mail:
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硅锰渣是硅锰合金生产中产生的主要固废,对环境产生巨大威胁,现行处理工艺消纳能力有限,亟需探索新的处置方法。以硅锰渣为原料、不外加成核剂,采用Petrurgic烧成法制备硅锰渣微晶铸石,讨论了晶化温度、晶化时间对成品物相组成及性能的影响规律,从而得到最佳热处理制度。结果表明:将热熔渣冷却至950 ℃保温60 min和760 ℃退火处理,能够制备出性能优良的微晶铸石。所得微晶铸石结构致密,析出的晶相主要为辉石族矿物,包括透辉石和铝透辉石,其次是钙长石和硅灰石,具有较好的综合性能,其体积密度可达3.11×103 kg·m-3,显微硬度达8.77×103 MPa,抗折强度和抗压强度分别为86 MPa和222.9 MPa。

, authors=辛鑫, 谭泽馨, 赵俊学, 胡爱琳, 王泽, 康毅, 王贺, 张桢凯, authorsList=辛鑫, 谭泽馨, 赵俊学, 胡爱琳, 王泽, 康毅, 王贺, 张桢凯, authorCompany=null, correspAuthors=赵俊学, authorNote=

辛鑫(1997—),女,硕士研究生。

, correspAuthorsNote=
赵俊学(1962—),男,博士,教授。
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辛鑫(1997—),女,硕士研究生。

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硅锰渣一步法制备微晶铸石的热处理工艺及性能
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辛鑫 , 谭泽馨 , 赵俊学 , 胡爱琳 , 王泽 , 康毅 , 王贺 , 张桢凯
硅酸盐学报 | 研究论文 2022,50(6): 1677-1684
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硅酸盐学报 |研究论文 2022 , 50 (6) : 1677 -1684
硅锰渣一步法制备微晶铸石的热处理工艺及性能
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辛鑫 , 谭泽馨, 赵俊学 , 胡爱琳, 王泽, 康毅, 王贺, 张桢凯
作者信息
  • 西安建筑科技大学冶金工程学院,西安 710055
通讯作者:
赵俊学(1962—),男,博士,教授。
作者简介:

辛鑫(1997—),女,硕士研究生。

Heat Treatment Process Optimization of Microcrystalline Cast Stone from Silico-manganese Slag by One-Step Preparation
Xin XIN , Zexin TAN, Junxue ZHAO , Ailin HU, Ze WANG, Yi KANG, He WANG, Zhenkai ZHANG
Affiliations
  • School of Metallurgical Engineering, Xi'an University of Architecture and Technology, Xi'an 710055, China
  • Corresponding Author:
    ZHAO Junxue (1962-), male, Ph.D., Professor. E-mail:

    XIN Xin (1997-), female, Master candidate. E-mail:

出版时间: 2022-06-20 doi: 10.14062/j.issn.0454-5648.20210843
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硅锰渣是硅锰合金生产中产生的主要固废,对环境产生巨大威胁,现行处理工艺消纳能力有限,亟需探索新的处置方法。以硅锰渣为原料、不外加成核剂,采用Petrurgic烧成法制备硅锰渣微晶铸石,讨论了晶化温度、晶化时间对成品物相组成及性能的影响规律,从而得到最佳热处理制度。结果表明:将热熔渣冷却至950 ℃保温60 min和760 ℃退火处理,能够制备出性能优良的微晶铸石。所得微晶铸石结构致密,析出的晶相主要为辉石族矿物,包括透辉石和铝透辉石,其次是钙长石和硅灰石,具有较好的综合性能,其体积密度可达3.11×103 kg·m-3,显微硬度达8.77×103 MPa,抗折强度和抗压强度分别为86 MPa和222.9 MPa。

硅锰渣  /  微晶铸石  /  热处理工艺优化  /  力学性能

Silico-manganese slag is a main solid waste produced from production of silicon-manganese alloy, which affects the environment. It is thus necessary to explore the corresponding disposal methods since the exsiting processing technology restricts the absorbing capacity. A microcrystalline cast stone was fabricated by the Petrurgic firing method with silico-manganese slag as a raw material. The bulk density, microhardness, flexural and compressive strength of the samples were determined. The influences of crystallization temperature and time on the phase structure and properties of the finished product were invesigated. The results show that a hot molten slag is cooled to 950 ℃ for 60 min and then annealed at 760 ℃, obtaing a microcrystalline cast stone with the superior properties. The microcrystalline cast stone has a compact structure, and the precipitated crystal phases are mainly clinopyroxene, diopside and aluminum diopside, as well as anorthite and wollastonite. The bulk density of the cast stone can reach 3.11×103 kg·m-3, the microhardness is 8.77×103 MPa, and the flexural strength and the compressive strength are 86 MPa and 222.9 MPa, respectively.

silico-manganese slag  /  microcrystalline cast stone  /  heat treatment process optimization  /  mechanical properties
辛鑫, 谭泽馨, 赵俊学, 胡爱琳, 王泽, 康毅, 王贺, 张桢凯. 硅锰渣一步法制备微晶铸石的热处理工艺及性能. 硅酸盐学报, 2022 , 50 (6) : 1677 -1684 . DOI: 10.14062/j.issn.0454-5648.20210843
Xin XIN, Zexin TAN, Junxue ZHAO, Ailin HU, Ze WANG, Yi KANG, He WANG, Zhenkai ZHANG. Heat Treatment Process Optimization of Microcrystalline Cast Stone from Silico-manganese Slag by One-Step Preparation[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (6) : 1677 -1684 . DOI: 10.14062/j.issn.0454-5648.20210843
  • 国家自然科学基金(51674185; 51674186)
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2022年第50卷第6期
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文章信息
doi: 10.14062/j.issn.0454-5648.20210843
  • 接收时间:2021-09-28
  • 首发时间:2026-10-22
  • 出版时间:2022-06-20
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  • 收稿日期:2021-09-28
  • 修回日期:2021-11-24
基金
国家自然科学基金(51674185; 51674186)
作者信息
    西安建筑科技大学冶金工程学院,西安 710055

通讯作者:

赵俊学(1962—),男,博士,教授。
参考文献
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2种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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