Article(id=1319986600352797133, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986532933555119, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20210946, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1636041600000, receivedDateStr=2021-11-05, revisedDate=1640188800000, revisedDateStr=2021-12-23, acceptedDate=null, acceptedDateStr=null, onlineDate=1792638929688, onlineDateStr=2026-10-22, pubDate=1655654400000, pubDateStr=2022-06-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792638929688, onlineIssueDateStr=2026-10-22, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792638929688, creator=13701087609, updateTime=1792638929688, updator=13701087609, issue=Issue{id=1319986532933555119, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='6', pageStart='1455', pageEnd='1774', issueExtLink='null', onlineDate='null', pubDate='1655654400000', pubDateStr='2022-06-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792638913615, creator='13701087609', updateTime=1792639299444, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319988151507075566, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986532933555119, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319988151507075567, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986532933555119, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1661, endPage=1668, ext={EN=ArticleExt(id=1319986600814170574, articleId=1319986600352797133, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=High-Performance Anode-Supported Solid Oxide Fuel Cells Prepared by Tape Casting Technique, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

The development of high-performance anode-supported solid oxide fuel cells (SOFCs) contributes to reducing the working temperature of SOFCs, and the preparation process and structural parameters of cells have a significant impact on the performance. Tape casting is a cheap and mass-produced cell fabrication method. In this paper, anode-supported SOFCs were prepared by a tape casting technique. The effects of pore-former type in anode support, the thickness and porosity of the anode functional layer and the thickness of the electrolyte on the SOFC performances were investigated. An anode functional layer with the thickness of about 12 μm was prepared when PMMA was used as a pore-former of the anode support, thus obtaining a preferred anode structure. Reducing the thickness of the electrolyte can reduce the ohmic resistance, but a too thin electrolyte can lead to the insufficient strength of electrolyte, affecting the stable operation of SOFCs. An anode-supported SOFC with the optimized anode and an electrolyte thickness of 8 μm has a peak power density of 1.2 W·cm-2 at 800 ℃.

, authors=Kai TAN1, Xiaoming YAN1, Fengyuan TIAN1, 2, Meirong XIA1, Mingyang ZHOU1, Jiang LIU1, authorsList=Kai TAN, Xiaoming YAN, Fengyuan TIAN, Meirong XIA, Mingyang ZHOU, Jiang LIU, authorCompany=null, correspAuthors=Jiang LIU, authorNote=

TAN Kai (1997-), male, Master candidate. E-mail:

, correspAuthorsNote=
LIU Jiang (1963-), Female, Ph.D., Professor. E-mail:
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开发高性能的阳极支撑固体氧化物燃料电池(SOFC)有助于实现其低温化,而电池的制备工艺及结构参数对电池的性能影响显著。流延成型法是一种廉价且可以实现批量生产的电池制备方法。采用流延成型法制备阳极支撑SOFC,并研究阳极支撑体造孔剂种类、阳极功能层的厚度及孔隙度、电解质厚度等因素对电池性能的影响。当使用PMMA作为阳极支撑体造孔剂、阳极功能层厚度约12 μm且功能层内不添加造孔剂时,阳极结构最好;减少电解质厚度能显著地降低Ohmic阻抗,但电解质过薄也会导致电解质的强度不够,影响电池的稳定运行。采用优选的阳极结构、电解质厚度为8 μm的阳极支撑SOFC在800 ℃的最大功率密度达到1.2 W·cm-2。

, authors=谭楷1, 颜晓敏1, 田丰源1, 2, 夏美荣1, 周明扬1, 刘江1, authorsList=谭楷, 颜晓敏, 田丰源, 夏美荣, 周明扬, 刘江, authorCompany=null, correspAuthors=刘江, authorNote=

谭楷(1997—),男,硕士研究生。

, correspAuthorsNote=
刘江(1963—),女,博士,教授。
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流延成型法制备高性能阳极支撑固体氧化物燃料电池
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谭楷 1 , 颜晓敏 1 , 田丰源 1, 2 , 夏美荣 1 , 周明扬 1 , 刘江 1
硅酸盐学报 | 研究论文 2022,50(6): 1661-1668
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硅酸盐学报 |研究论文 2022 , 50 (6) : 1661 -1668
流延成型法制备高性能阳极支撑固体氧化物燃料电池
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谭楷1 , 颜晓敏1, 田丰源1, 2, 夏美荣1, 周明扬1, 刘江1
作者信息
  • 1.华南理工大学环境与能源学院,广州 510006
  • 2.西南技术工程研究所,重庆 400039
通讯作者:
刘江(1963—),女,博士,教授。
作者简介:

谭楷(1997—),男,硕士研究生。

High-Performance Anode-Supported Solid Oxide Fuel Cells Prepared by Tape Casting Technique
Kai TAN1 , Xiaoming YAN1, Fengyuan TIAN1, 2, Meirong XIA1, Mingyang ZHOU1, Jiang LIU1
Affiliations
  • 1.School of Environment and Energy, South China University of Technology, Guangzhou 510006, China
  • 2.Southwest Technology and Engineering Research Institute, Chongqing 400039, China
  • Corresponding Author:
    LIU Jiang (1963-), Female, Ph.D., Professor. E-mail:

    TAN Kai (1997-), male, Master candidate. E-mail:

出版时间: 2022-06-20 doi: 10.14062/j.issn.0454-5648.20210946
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开发高性能的阳极支撑固体氧化物燃料电池(SOFC)有助于实现其低温化,而电池的制备工艺及结构参数对电池的性能影响显著。流延成型法是一种廉价且可以实现批量生产的电池制备方法。采用流延成型法制备阳极支撑SOFC,并研究阳极支撑体造孔剂种类、阳极功能层的厚度及孔隙度、电解质厚度等因素对电池性能的影响。当使用PMMA作为阳极支撑体造孔剂、阳极功能层厚度约12 μm且功能层内不添加造孔剂时,阳极结构最好;减少电解质厚度能显著地降低Ohmic阻抗,但电解质过薄也会导致电解质的强度不够,影响电池的稳定运行。采用优选的阳极结构、电解质厚度为8 μm的阳极支撑SOFC在800 ℃的最大功率密度达到1.2 W·cm-2。

固体氧化物燃料电池  /  流延成型  /  阳极支撑  /  造孔剂  /  阳极功能层

The development of high-performance anode-supported solid oxide fuel cells (SOFCs) contributes to reducing the working temperature of SOFCs, and the preparation process and structural parameters of cells have a significant impact on the performance. Tape casting is a cheap and mass-produced cell fabrication method. In this paper, anode-supported SOFCs were prepared by a tape casting technique. The effects of pore-former type in anode support, the thickness and porosity of the anode functional layer and the thickness of the electrolyte on the SOFC performances were investigated. An anode functional layer with the thickness of about 12 μm was prepared when PMMA was used as a pore-former of the anode support, thus obtaining a preferred anode structure. Reducing the thickness of the electrolyte can reduce the ohmic resistance, but a too thin electrolyte can lead to the insufficient strength of electrolyte, affecting the stable operation of SOFCs. An anode-supported SOFC with the optimized anode and an electrolyte thickness of 8 μm has a peak power density of 1.2 W·cm-2 at 800 ℃.

solid oxide fuel cell  /  tape casting  /  anode-supported  /  pore-former  /  anode functional layer
谭楷, 颜晓敏, 田丰源, 夏美荣, 周明扬, 刘江. 流延成型法制备高性能阳极支撑固体氧化物燃料电池. 硅酸盐学报, 2022 , 50 (6) : 1661 -1668 . DOI: 10.14062/j.issn.0454-5648.20210946
Kai TAN, Xiaoming YAN, Fengyuan TIAN, Meirong XIA, Mingyang ZHOU, Jiang LIU. High-Performance Anode-Supported Solid Oxide Fuel Cells Prepared by Tape Casting Technique[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (6) : 1661 -1668 . DOI: 10.14062/j.issn.0454-5648.20210946
  • 国家科学自然基金(91745203; U1601207)
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2022年第50卷第6期
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doi: 10.14062/j.issn.0454-5648.20210946
  • 接收时间:2021-11-05
  • 首发时间:2026-10-22
  • 出版时间:2022-06-20
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  • 收稿日期:2021-11-05
  • 修回日期:2021-12-23
基金
国家科学自然基金(91745203; U1601207)
作者信息
    1.华南理工大学环境与能源学院,广州 510006
    2.西南技术工程研究所,重庆 400039

通讯作者:

刘江(1963—),女,博士,教授。
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鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
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