Article(id=1319986591993544977, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986532933555119, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20211153, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1640620800000, receivedDateStr=2021-12-28, revisedDate=1642176000000, revisedDateStr=2022-01-15, acceptedDate=null, acceptedDateStr=null, onlineDate=1792638927696, onlineDateStr=2026-10-22, pubDate=1655654400000, pubDateStr=2022-06-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792638927696, onlineIssueDateStr=2026-10-22, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792638927696, creator=13701087609, updateTime=1792638927696, updator=13701087609, issue=Issue{id=1319986532933555119, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='6', pageStart='1455', pageEnd='1774', issueExtLink='null', onlineDate='null', pubDate='1655654400000', pubDateStr='2022-06-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792638913615, creator='13701087609', updateTime=1792639299444, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319988151507075566, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986532933555119, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319988151507075567, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986532933555119, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1642, endPage=1651, ext={EN=ArticleExt(id=1319986593834844434, articleId=1319986591993544977, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Preparation and Thermal Performance of Nano- Graphene Oxide/Mirabilite Composite Phase Change Materials, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=
To solve the problem of the shortened cycle life of phase-change latent heat storage due to the large subcooling degree and serious phase stratification of mirabilite phase-change materials, a graphene oxide/mirabilite composite phase-change material (GO-MCPCM) was prepared with Na2SO4·10H2O-Na2CO3·10H2O-NaCl phase-change composite as a matrix and graphene oxide (GO) as additives. The microstructure and properties of GO and GO-MCPCMs were characterized by scanning electron microscopy, transmission electron microscopy Raman spectroscopy, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and thermogravimetry-Differential scanning calorimetry, respectively. The results show that the O/C ratio in oxidized graphene oxide is increased by 65.75%, the structural defect level is increased from 0.224 to 1.088, indicating that the oxidation-treated graphene has no agglomeration phenomenon and has good hydrophilicity and compatibility. The crystalline phase transition temperature of GO-MCPCMs is 23 ℃, the degree of subcooling reduces to 0 ℃, only sodium sulfate decahydrate releases heat, and the crystalline hydrate is Na2SO4·10H2O with a grain length of approximately 2 cm. The maximum latent heat of GO-MCPCMs crystallization at a mass fraction of 0.075% is 156.7 J/g, and the attenuation rate of the latent heat of GO-MCPCMs crystallization at a mass fraction of 0.075% is 4.3% after 500 solid-liquid cycles. Therefore, the addition of GO can improve the thermal stability of the mirabilite composite phase-change material, and graphene oxide/mirabilite composite phase-change material prepared has a good thermal cycle stability and a long service life.
, authors=Fenglan CHEN
1, Xin LIU
1, Shengnian TIE
1, Chang'an WANG
1, 2, authorsList=Fenglan CHEN, Xin LIU, Shengnian TIE, Chang'an WANG, authorCompany=null, correspAuthors=Shengnian TIE, authorNote=
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针对芒硝相变材料因过冷度大、相分层严重导致相变潜热存储循环寿命缩短的问题,以Na2SO4·10H2O-Na2CO3·10H2O-NaCl相变材料体系为基体、改进的Hummers法结合冷冻干燥和球磨工艺改性制备的亲水性纳米氧化石墨烯(Nano-GO)为添加剂,制得纳米氧化石墨烯/芒硝基复合相变材料(GO-MCPCMs)。结果表明:氧化处理过的纳米氧化石墨烯中O/C比例增加了65.75%,结构缺陷水平由0.224增至1.088,无团聚现象;纳米氧化石墨烯/芒硝基复合相变材料的结晶相变温度增至约23 ℃、过冷度减小至0 ℃、相分层消除,该复合相变体系中Na2SO4结晶体全部结晶为晶粒长度尺寸近于2 cm的Na2SO4·10H2O;500次固-液循环前后含氧化石墨烯质量分数为0.075%的GO-MCPCMs结晶潜热值分别为156.7 J/g和149.9 J/g,衰减率为4.3%,Nano-GO的加入明显改善了芒硝基复合相变体系的热稳定性。纳米氧化石墨烯/芒硝基复合相变材料具有良好的热循环稳定性和较长的使用寿命。
, authors=陈凤兰
1, 柳馨
1, 铁生年
1, 汪长安
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铁生年(1965—),男,教授。
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