Article(id=1319986559076643237, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986532933555119, articleNumber=null, orderNo=null, doi=10.14062/j.issn.0454-5648.20210850, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1632931200000, receivedDateStr=2021-09-30, revisedDate=1635091200000, revisedDateStr=2021-10-25, acceptedDate=null, acceptedDateStr=null, onlineDate=1792638919847, onlineDateStr=2026-10-22, pubDate=1655654400000, pubDateStr=2022-06-20, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1792638919847, onlineIssueDateStr=2026-10-22, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1792638919847, creator=13701087609, updateTime=1792638919847, updator=13701087609, issue=Issue{id=1319986532933555119, tenantId=1146029695717560320, journalId=1263187385517883426, year='2022', volume='50', issue='6', pageStart='1455', pageEnd='1774', issueExtLink='null', onlineDate='null', pubDate='1655654400000', pubDateStr='2022-06-20', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=0, createTime=1792638913615, creator='13701087609', updateTime=1792639299444, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1319988151507075566, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986532933555119, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1319988151507075567, tenantId=1146029695717560320, journalId=1263187385517883426, issueId=1319986532933555119, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=1533, endPage=1541, ext={EN=ArticleExt(id=1319986559483490726, articleId=1319986559076643237, tenantId=1146029695717560320, journalId=1263187385517883426, language=EN, title=Effects of Structure Evolution and Quenching on Structure and Electrical Properties of BiFeO3-BaTiO3 Piezoelectric Ceramics Near Phase Boundary, columnId=1263922769897599102, journalTitle=Journal of the Chinese Ceramic Society, columnName=Research Articles, runingTitle=null, highlight=null, articleAbstract=

(1-x)BiFeO3-xBaTiO3(BF-xBT, x=0.28, 0.29, 0.30,0.31) piezoelectric ceramics were prepared by a conventional sintering technology. The relationship between the phase structure and dielectric, ferroelectric and piezoelectric properties of the ceramics near the phase boundary was investigated. Based on the results by X-ray diffraction, all the samples present a pure perovskite phase structure without any impurity phase, and all the ceramics are located around the rhombohedral-pseudocubic phase boundary. The phase structure gradually transforms from rhombohedral to pseudocubic phase as x increases, and the content of R and pC phase tends to be equal when x=0.30, showing the optimum electrical properties (i.e., piezoelectric coefficient (d33) =165 pC/N, remanent polarization (Pr) = 26.80 μC/cm2, and the Curie temperature (TC) = 465 ℃). In addition, the changes of Raman vibration mode and diffuseness factor of the samples after quenching indicate that the quenching process can effectively improve the long range order degree and the temperature stability of ferroelectric phase of the samples, resulting in a further increase in the Curie temperature of BF-xBT ceramics. For a ceramic BF-0.30BT, the enhanced dielectric and ferroelectric properties are obtained due to its more proper R/pC phase ratio and quenching process. Also, the relationship between the phase structure evolution and piezoelectric properties of BF-xBT ceramics was revealed, and the electrical properties of BF-xBT ceramics were further optimized by quenching process, so as to provide a reference for broadening the application temperature range of the BF-BT system materials.

, authors=Li YANG, Chao CHEN, Xiangping JIANG, Xiaokun HUANG, Xin NIE, Hanwen RAO, authorsList=Li YANG, Chao CHEN, Xiangping JIANG, Xiaokun HUANG, Xin NIE, Hanwen RAO, authorCompany=null, correspAuthors=Chao CHEN, Xiangping JIANG, authorNote=

YANG Li (1995-), female, Master candidate. E-mail:

, correspAuthorsNote=
CHEN Chao (1983-), male, Ph.D., Professor; E-mail:
JIANG Xiangping (1964-), male, Ph.D., Professor.
, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1319986559919698343, articleId=1319986559076643237, tenantId=1146029695717560320, journalId=1263187385517883426, language=CN, title=相界附近结构演化及淬火对BiFeO3-BaTiO3压电陶瓷结构与电学性能的影响, columnId=1263922770220560512, journalTitle=硅酸盐学报, columnName=研究论文, runingTitle=null, highlight=null, articleAbstract=

采用传统固相法制备了(1-x)BiFeO3-xBaTiO3(BF-xBT,x=0.28,0.29,0.30,0.31)压电陶瓷,研究了其在相界附近的相结构演化与介电、铁电性能和压电性能的变化关系。结果表明,所有样品均呈现出钙钛矿相结构且无任何杂相,且均位于三方-赝立方相相界附近,表现出三方、赝立方两相共存状态。随着x的增加,相结构中赝立方相相含量逐渐增加,而三方相相含量逐渐减少,当x=0.30时,样品的三方相与赝立方相含量趋于相近,表现出最佳的电性能:压电系数d33=165 pC/N,剩余极化强度Pr=26.80 μC/cm2,Curie温度TC=465 ℃。另外,淬火后样品的Raman振动模与弥散指数的显著变化表明淬火工艺能有效提高样品的长程有序度和铁电相的温度稳定性,致使BF-xBT体系陶瓷的Curie温度得到进一步提升。特别是对于BF-0.30BT陶瓷样品,由于更合适的三方-赝立方相相比例和淬火工艺,介电和铁电性能均得到增强。本工作揭示了BF-xBT陶瓷样品相结构演化与压电性能的关系,并通过淬火工艺进一步优化BF-xBT陶瓷的电性能,从而为拓宽BF-BT体系材料的应用温度范围提供参考依据。

, authors=杨利, 陈超, 江向平, 黄枭坤, 聂鑫, 饶汉文, authorsList=杨利, 陈超, 江向平, 黄枭坤, 聂鑫, 饶汉文, authorCompany=null, correspAuthors=陈超, 江向平, authorNote=

杨利(1995—),女,硕士研究生。

, correspAuthorsNote=
陈超(1983—),男,博士,教授;
江向平(1964—),男,博士,教授。
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相界附近结构演化及淬火对BiFeO3-BaTiO3压电陶瓷结构与电学性能的影响
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杨利 , 陈超 , 江向平 , 黄枭坤 , 聂鑫 , 饶汉文
硅酸盐学报 | 研究论文 2022,50(6): 1533-1541
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硅酸盐学报 |研究论文 2022 , 50 (6) : 1533 -1541
相界附近结构演化及淬火对BiFeO3-BaTiO3压电陶瓷结构与电学性能的影响
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杨利 , 陈超 , 江向平 , 黄枭坤, 聂鑫, 饶汉文
作者信息
  • 景德镇陶瓷大学材料科学与工程学院,江西省先进陶瓷材料重点实验室,江西 景德镇 333000
通讯作者:
陈超(1983—),男,博士,教授;
江向平(1964—),男,博士,教授。
作者简介:

杨利(1995—),女,硕士研究生。

Effects of Structure Evolution and Quenching on Structure and Electrical Properties of BiFeO3-BaTiO3 Piezoelectric Ceramics Near Phase Boundary
Li YANG , Chao CHEN , Xiangping JIANG , Xiaokun HUANG, Xin NIE, Hanwen RAO
Affiliations
  • Jiangxi Key Laboratory of Advanced Ceramic Materials, School of Material Science and Engineering, Jingdezhen Ceramic Institute, Jingdezhen 333000, Jiangxi, China
  • Corresponding Author:
    CHEN Chao (1983-), male, Ph.D., Professor; E-mail:
    JIANG Xiangping (1964-), male, Ph.D., Professor.

    YANG Li (1995-), female, Master candidate. E-mail:

出版时间: 2022-06-20 doi: 10.14062/j.issn.0454-5648.20210850
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采用传统固相法制备了(1-x)BiFeO3-xBaTiO3(BF-xBT,x=0.28,0.29,0.30,0.31)压电陶瓷,研究了其在相界附近的相结构演化与介电、铁电性能和压电性能的变化关系。结果表明,所有样品均呈现出钙钛矿相结构且无任何杂相,且均位于三方-赝立方相相界附近,表现出三方、赝立方两相共存状态。随着x的增加,相结构中赝立方相相含量逐渐增加,而三方相相含量逐渐减少,当x=0.30时,样品的三方相与赝立方相含量趋于相近,表现出最佳的电性能:压电系数d33=165 pC/N,剩余极化强度Pr=26.80 μC/cm2,Curie温度TC=465 ℃。另外,淬火后样品的Raman振动模与弥散指数的显著变化表明淬火工艺能有效提高样品的长程有序度和铁电相的温度稳定性,致使BF-xBT体系陶瓷的Curie温度得到进一步提升。特别是对于BF-0.30BT陶瓷样品,由于更合适的三方-赝立方相相比例和淬火工艺,介电和铁电性能均得到增强。本工作揭示了BF-xBT陶瓷样品相结构演化与压电性能的关系,并通过淬火工艺进一步优化BF-xBT陶瓷的电性能,从而为拓宽BF-BT体系材料的应用温度范围提供参考依据。

铁酸铋-钛酸钡  /  相结构  /  淬火工艺  /  压电陶瓷

(1-x)BiFeO3-xBaTiO3(BF-xBT, x=0.28, 0.29, 0.30,0.31) piezoelectric ceramics were prepared by a conventional sintering technology. The relationship between the phase structure and dielectric, ferroelectric and piezoelectric properties of the ceramics near the phase boundary was investigated. Based on the results by X-ray diffraction, all the samples present a pure perovskite phase structure without any impurity phase, and all the ceramics are located around the rhombohedral-pseudocubic phase boundary. The phase structure gradually transforms from rhombohedral to pseudocubic phase as x increases, and the content of R and pC phase tends to be equal when x=0.30, showing the optimum electrical properties (i.e., piezoelectric coefficient (d33) =165 pC/N, remanent polarization (Pr) = 26.80 μC/cm2, and the Curie temperature (TC) = 465 ℃). In addition, the changes of Raman vibration mode and diffuseness factor of the samples after quenching indicate that the quenching process can effectively improve the long range order degree and the temperature stability of ferroelectric phase of the samples, resulting in a further increase in the Curie temperature of BF-xBT ceramics. For a ceramic BF-0.30BT, the enhanced dielectric and ferroelectric properties are obtained due to its more proper R/pC phase ratio and quenching process. Also, the relationship between the phase structure evolution and piezoelectric properties of BF-xBT ceramics was revealed, and the electrical properties of BF-xBT ceramics were further optimized by quenching process, so as to provide a reference for broadening the application temperature range of the BF-BT system materials.

bismuth ferrite-barium titanate  /  phase structure  /  quenching process  /  piezoelectric ceramics
杨利, 陈超, 江向平, 黄枭坤, 聂鑫, 饶汉文. 相界附近结构演化及淬火对BiFeO3-BaTiO3压电陶瓷结构与电学性能的影响. 硅酸盐学报, 2022 , 50 (6) : 1533 -1541 . DOI: 10.14062/j.issn.0454-5648.20210850
Li YANG, Chao CHEN, Xiangping JIANG, Xiaokun HUANG, Xin NIE, Hanwen RAO. Effects of Structure Evolution and Quenching on Structure and Electrical Properties of BiFeO3-BaTiO3 Piezoelectric Ceramics Near Phase Boundary[J]. Journal of the Chinese Ceramic Society, 2022 , 50 (6) : 1533 -1541 . DOI: 10.14062/j.issn.0454-5648.20210850
  • 国家自然科学基金(52162003; 51862016; 52062018; 51762024)
  • 江西省自然科学基金(20212ACB214007; 20192BAB212002; 20192BAB206008)
  • 江西省教育厅科技项目(GJJ190699)
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doi: 10.14062/j.issn.0454-5648.20210850
  • 接收时间:2021-09-30
  • 首发时间:2026-10-22
  • 出版时间:2022-06-20
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  • 收稿日期:2021-09-30
  • 修回日期:2021-10-25
基金
国家自然科学基金(52162003; 51862016; 52062018; 51762024)
江西省自然科学基金(20212ACB214007; 20192BAB212002; 20192BAB206008)
江西省教育厅科技项目(GJJ190699)
作者信息
    景德镇陶瓷大学材料科学与工程学院,江西省先进陶瓷材料重点实验室,江西 景德镇 333000

通讯作者:

陈超(1983—),男,博士,教授;
江向平(1964—),男,博士,教授。
参考文献
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https://castjournals.cast.org.cn/joweb/gsyxb/CN/10.14062/j.issn.0454-5648.20210850
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2种不同金属材料的力学参数
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鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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